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2017 | OriginalPaper | Chapter

8. Electron Spin Resonance of Lanthanide EMFs

Author : Tatsuhisa Kato

Published in: Endohedral Fullerenes: Electron Transfer and Spin

Publisher: Springer International Publishing

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Abstract

The chapter describes electron spin resonance (ESR) spectroscopic studies of lanthanide endohedral metallofullerenes. A summary of recent investigations of La@C₈₂, La₂@C₈₀, and their reduced anion and radical species is presented. Also discussed are ESR studies of lanthanide metallofullerene with high spin state, including Eu@C₇₄, Eu@C₈₂, Gd@C₈₂, and Gd₂@C₇₉N.

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previous chapter Electron Spin Resonance Studies of Metallofullerenes

next chapter Ion Radicals of Endohedral Metallofullerenes Studied by EPR Spectroscopy

Chai Y, Guo T, Lin C, Haufler R, Chibante LPF, Fure J, Wang L, Alford JM, Smalley RJE (1991) Fullerenes with metals inside. J Phys Chem 95:7564–7568CrossRef

Johnson RD, de Vries MS, Salem JR, Bthune DS, Yannoni CS (1992) Electron paramagnetic resonance studies of lanthanum-containing C₈₂. Nature 355:239–240CrossRef

Ohkubo S, Kato T, Inakuma M, Shinohara H (2001) Separation and characterization of ESR-active lanthanum endohedral fullerenes. New Diamond Front Carbon Technol 11(4):285–294

Ohkubo S, Kato T (2002) ESR parameters of series of La@C_n isomers. Appl Magn Reson 23:481–493CrossRef

Akasaka T, Wakahara T, Nagase S, Kobayashi K, Wälchli M, Yamamoto K, Kondo M, Shirakura S, Okubo S, Maeda Y, Kato T, Kako M, Nakadaira Y, Nagahata R, Gao X, Van Caemelbecke E, Kadish KM (2000) La@C₈₂ anion, an unusually stable metallofullerene. J Am Chem Soc 122:9316–9317CrossRef

Akasaka T, Wakahara T, Nagase S, Kobayashi K, Wälchli M, Yamamoto K, Kondo M, Shirakura S, Maeda Y, Kato T, Kako M, Nakadaira Y, Gao X, Van Caemelbecke E, Kadish KM (2001) Structure determination of the La@C₈₂ isomer. J Phys Chem B 105:2971–2974CrossRef

Tsuchiya T, Wakahara T, Maeda Y, Akasaka T, Wälchli M, Kato T, Okubo H, Mizorogi N, Kobayashi K, Nagase S (2005) 2D NMR characterization of the La@C₈₂ anion. Angew Chem Int Ed 44:3282–3285CrossRef

Alvarez MM, Gillan EG, Holezer K, Kaner RB, Min KS, Whetten RL (1991) La₂C₈₀: a soluble dimetallofullerene. J Phys Chem 95:10561–10563CrossRef

Suzuki T, Maruyama Y, Kato T, Kikuchi K, Nakao Y, Ahiba Y, Kobayashi K, Nagase S (1995) Electrochemistry and Ab intio study of the dimetallofullerene La₂@C₈₀. Anew Chem Int Ed 34(10):1094–1096CrossRef

10.

Kobayashi K, Nagase S, Akasaka K (1995) A theoretical study of C₈₀ and La₂@C₈₀. Chem Phys Lett 245:230–236CrossRef

11.

Nishibori E, Takata M, Sakata M, Taninaka A, Shinohara H (2001) Pentagonal-dodecahedral La₂ charge density in [80-I _h] fullerene: La₂@C₈₀. Angew Chem Int Ed 40(16):2998–2999CrossRef

12.

Akasaka T, Nagase S, Kobayashi K, Wälchli M, Yamamoto K, Funasaka H, Kako M, Hoshino T, Erata T (1997) ¹³C and ¹³⁹La NMR studies of La₂@C₈₀: first evidence for circular motion of metal atoms in endohedral dimetallofullerenes. Angew Chem Int Ed 36(15):1643–1645CrossRef

13.

Shimotani H, Ito T, Iwasa Y, Taninaka A, Shinohara H, Nishibori E, Takata M, Sakata M (2004) Quantum Chemical Study on the Configurations of Encapsulated Metal Ions and the Molecular Vibration Modes in Endohedral Dimetallofullerene La₂@C₈₀. J Am Chem Soc 126:364–369CrossRef

14.

Yamada M, Kurihara H, Suzuki M, Saito M, Slanina Z, Uhlik F, Aizawa T, Kato T, Olmstead MM, Balch AL, Maeda Y, Nagase S, Lu X, Akasaka T (2015) Hiding and recovering electrons in a dimetallic endohedral fullerene: air-stable products from radical additions. J Am Chem Soc 137:232–238CrossRef

15.

Matsuoka H, Ozawa N, Kodama T, Nishikawa H, Ikemoto I, Kikuchi K, Furukawa K, Sato K, Shiomi D, Takui T, Kato T (2004) Multifrequency EPR study of metallofullerenes: Eu@C₈₂ and Eu@C₇₄. J Phys Chem B 108:13972–13976CrossRef

16.

Furukawa K, Okubo S, Kato H, Shinohara H, Kato T (2003) High-field/ high-frequency ESR study of Gd@C₈₂-I. J Phys Chem A 107:10933–10937CrossRef

17.

Fu W, Zhang J, Fuhrer T, Champion H, Furukawa K, Kato T, Mahaney EJ, Burke GB, Williams AK, Walker K, Dixon C, Ge J, Shu C, Harich K, Dorn CH (2011) Gd₂@C₇₉N: isolation, charaterization, and monoadduct formation of a very stable heterofullerene with a magnetic spin state of S = 15/2. J Am Chem Soc 133:9741–9750CrossRef

Title: Electron Spin Resonance of Lanthanide EMFs
Author: Tatsuhisa Kato
Publisher: Springer International Publishing
Book: Endohedral Fullerenes: Electron Transfer and Spin
Print ISBN: 978-3-319-47047-4

Electronic ISBN: 978-3-319-47049-8

Copyright Year: 2017
DOI: https://doi.org/10.1007/978-3-319-47049-8_8

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