1986 | OriginalPaper | Chapter
Electron Transfer Reactions on Oxide-Covered Metal Electrodes
Authors : W. Schmickler, J. W. Schultze
Published in: Modern Aspects of Electrochemistry
Publisher: Springer US
Included in: Professional Book Archive
Activate our intelligent search to find suitable subject content or patents.
Select sections of text to find matching patents with Artificial Intelligence. powered by
Select sections of text to find additional relevant content using AI-assisted search. powered by
At bare metal electrodes the rates of outer-sphere electron transfer reactions show only a small dependence on the nature of the substrate1a the exchange current densities of a particular reaction on various metals differ by no more than about one order of magnitude, and the transfer coefficients are generally close to 0.5. These experimental findings are in line with theoretical considerations.1b,2