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Colloid and Polymer Science
Published in: Colloid and Polymer Science 8/2015

01-08-2015 | Original Contribution

Electrospinning preparation, thermal, and luminescence properties of Eu2(BTP)3(Phen)2 complex doped in PMMA

Authors: Huiquan Gu, Yanjun Hou, Feng Xu, Shuhong Wang

Published in: Colloid and Polymer Science | Issue 8/2015

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Abstract

Different concentrations of bis-β-diketonate complex Eu2(BTP)3(Phen)2 (BTP = 1,3-bis(4,4,4-trifluoro-1,3-dioxobutyl)-phenyl and Phen = 1,10-phenanthroline) were doped into the poly(methylmethacrylate) (PMMA), forming a series of red Eu/PMMA luminescent nanofibers, via electrospinning technology. Various characterization techniques were employed to reveal the effect of Eu2(BTP)3(Phen)2 on the morphology, thermal stability, and luminescence of composite nanofibers. FT-IR spectra show the Eu2(BTP)3(Phen)2 complex was successfully doped into PMMA. The luminescent spectra of the composite nanofibers show strong characteristic emission of Eu3+ ions. Simultaneously, in comparison with the precursor complex Eu2(BTP)3(Phen)2, the Eu/PMMA nanofibers has a great improvement in thermal stability. Furthermore, the Judd-Ofelt theory and simulative constructions of the complex are employed to explain the effect of the dispersion of Eu2(BTP)3(Phen)2 and the interactions between the Eu2(BTP)3(Phen)2 complex and neighboring chain segments of PMMA.
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Appendix
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Metadata
Title
Electrospinning preparation, thermal, and luminescence properties of Eu2(BTP)3(Phen)2 complex doped in PMMA
Authors
Huiquan Gu
Yanjun Hou
Feng Xu
Shuhong Wang
Publication date
01-08-2015
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 8/2015
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3614-8

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