Top

Polymer Bulletin

Published in:

01-12-2012 | Original Paper

Electrospun composite fibers of polyvinylpyrrolidone with embedded poly(methyl methacrylate)–polyethyleneimine core–shell particles

Authors: Thammasit Vongsetskul, Phornpimon Kongjumnean, Panya Sunintaboon, Ratthapol Rangkupan, Pramuan Tangboriboonrat

Published in: Polymer Bulletin | Issue 9/2012

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Composite fibers consisting of poly(methyl methacrylate)–polyethyleneimine (PMMA–PEI) core–shell particles embedded in polyvinylpyrrolidone (PVP) were successfully fabricated by the electrospinning method. The electrospun fibers were produced using 18 % w/v aqueous PVP solution blended with 2 % w/v PMMA–PEI particles at various pH (1, 2, 3, and 4) with a fiber collection distance set at 10 cm. The applied electrical voltages (10, 12, 14, and 16 kV) significantly affected the morphology and diameter of the prepared composite fibers (141–353 nm). The smallest composite fibers were obtained from the spinning mixture at pH 2 and a voltage of 14 kV. The composite fibers would potentially be applied as drug and bioactive compound carriers.

previous article Electron beam irradiation of low-density polyethylene filled with metal hydroxides for wire and cable applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Ramakrishna S, Fujihara K, Teo W, Lim T, Ma Z (2005) An introduction to electrospinning and nanofibers. World Scientific Publishing, SingaporeCrossRef

Kontogiannopoulos KN, Assimopoulou AN, Tsivintzelis I, Panayiotou C, Papageorgiou VP (2011) Electrospun fiber mats containing shikonin and derivatives with potential biomedical applications. Int J Pharm 409(1–2):216–228. doi:10.1016/j.ijpharm.2011.02.004 CrossRef

Fletcher BL, McKnight TE, Fowlkes JD, Allison DP, Simpson ML, Doktycz MJ (2007) Controlling the dimensions of carbon nanofiber structures through the electropolymerization of pyrrole. Synth Met 157(6–7):282–289. doi:10.1016/j.synthmet.2007.03.004 CrossRef

Bai J, Li Y, Li M, Wang S, Zhang C, Yang Q (2008) Electrospinning method for the preparation of silver chloride nanoparticles in PVP nanofiber. Appl Surf Sci 254:4520–4523. doi:10.1016/j.apsusc.2008.01.051 CrossRef

Bai J, Li Y, Zhang C, Liang X, Yang Q (2008) Preparing AgBr nanoparticles in poly(vinyl pyrrolidone) (PVP) nanofibers. Colloids Surf A 329:165–168. doi:10.1016/j.colsurfa.2008.07.010 CrossRef

Woo H, Jung W, Ihm D, Kim J (2010) Synthesis and dispersion of polypyrrole nanoparticles in polyvinylpyrrolidone emulsion. Synth Met 160:588–591. doi:10.1016/j.synthmet.2009.12.010 CrossRef

Zhu JH, Wei SY, Chen XL, Karki AB, Rutman D, Young DP, Guo ZH (2010) Electrospun polyimide nanocomposite fibers reinforced with core-shell Fe-FeO nanoparticles. J Phys Chem C 114:8844–8850. doi:10.1021/jp1020033 CrossRef

Herrmann C, Turshatov A, Crespy D (2012) Fabrication of polymer ellipsoids by the electrospinning of swollen nanoparticles. ACS Macro Lett 1:907–909. doi:10.1021/mz300245b CrossRef

Pimpha N, Chaleawlert-umpon S, Sunintaboon P (2012) Core/shell polymethyl methacrylate/polyethyleneimine particles incorporating large amounts of iron oxide nanoparticles prepared by emulsifier-free emulsion polymerization. Polymer 53(10):2015–2022. doi:10.1016/j.polymer.2012.03.019 CrossRef

10.

Inphonlek S, Pimpha N, Sunintaboon P (2010) Synthesis of poly(methyl methacrylate) core/chitosan-mixed-polyethyleneimine shell nanoparticles and their antibacterial property. Colloids Surf B 77(2):219–226. doi:10.1016/j.colsurfb.2010.01.029 CrossRef

11.

Fischer F, Bauer S (2009) Polyvinylpyrrolidon. Ein Tausendsassa. Chem Unserer Zeit 43(6):376–383. doi:10.1002/ciuz.200900492 CrossRef

12.

Demir MM, Yilgor I, Yilgor E, Eman B (2002) Electrospinning of polyurethane fibers. Polymer 43:3303–3309. doi:10.1016/S0032-3861(02)00136-2 CrossRef

Title: Electrospun composite fibers of polyvinylpyrrolidone with embedded poly(methyl methacrylate)–polyethyleneimine core–shell particles
Authors: Thammasit Vongsetskul
Phornpimon Kongjumnean
Panya Sunintaboon
Ratthapol Rangkupan
Pramuan Tangboriboonrat
Publication date: 01-12-2012
Publisher: Springer-Verlag
Published in: Polymer Bulletin / Issue 9/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-012-0870-3

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 9/2012

Determination of crystallization parameters and occurrence of trans-reaction in a ternary polymer blend system

Temperature-induced thickening of sodium carboxymethylcellulose and poly(N-isopropylacrylamide) physical blends in aqueous solution

Optically active thermosensitive amphiphilic polymer brushes based on helical polyacetylene: preparation through “click” onto grafting method and self-assembly

Soap-free emulsion polymerization of n-butyl acrylate in aqueous solution in the presence of α- and methylated β-cyclodextrin

Electron beam irradiation of low-density polyethylene filled with metal hydroxides for wire and cable applications

Removal of arsenate from ionic mixture by anion exchanger water-soluble polymers combined with ultrafiltration membranes

Premium Partners