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Journal of Materials Science
Published in: Journal of Materials Science 12/2018

19-03-2018 | Biomaterials

Enhanced dielectric constant and structural transformation in Fe-doped hydroxyapatite synthesized by wet chemical method

Authors: Brajendra Singh, Aditya Tandon, Anand K. Pandey, Priyanka Singh

Published in: Journal of Materials Science | Issue 12/2018

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Abstract

We report the synthesis of single-phase Fe-doped hydroxyapatite (HAp) [Ca10−xFe x (PO4)6(OH)2 (0.0 ≤ x ≤ 0.3)] and enhanced dielectric constant of HAp with Fe doping. Rietveld analysis shows the change in x-axis-oriented lattice constant a in Fe-doped x = 0.1 and 0.3 compositions in comparison with parent HAp, while z-axis-oriented lattice constant c does not show any considerable change. Analysis of absorbance data shows two new symmetric stretching peaks for Fe-doped x = 0.1 and x = 0.3 compositions, which are not present in parent HAp. Magnetic measurements show paramagnetic behaviour of all Fe-doped samples at 300 K. Fe-doped Ca9.9Fe0.1(PO4)6(OH)2 composition shows increase in impedance in the presence of 500 Oersted (Oe) applied magnetic field in comparison with impedance in the absence of magnetic field. Ca9.9Fe0.1(PO4)6(OH)2 composition shows increase in dielectric constant in comparison with parent HAp in frequency range 5–35 MHz. Fe-doped Ca9.9Fe0.1(PO4)6(OH)2 composition shows ~ 970% colossal magnetoimpedance at 100 Hz and ~ 200% at 20 MHz frequency.
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Metadata
Title
Enhanced dielectric constant and structural transformation in Fe-doped hydroxyapatite synthesized by wet chemical method
Authors
Brajendra Singh
Aditya Tandon
Anand K. Pandey
Priyanka Singh
Publication date
19-03-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 12/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2225-4

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