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Journal of Materials Science: Materials in Electronics

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09-11-2019

Enhanced electrochemical performance of Li_1.18Ni_0.15Co_0.15Mn_0.52O₂ cathode modified with aluminosilicate solid acid

Authors: Fang Hu, Dongxu Zhang, Fuhan Cui, Di Xie, Guihong Song

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

Li-rich cathode material Li_1.18Ni_0.15Co_0.15Mn_0.52O₂ is prepared by a sol–gel method and modified with aluminosilicate solid acid (Al₂O₃·SiO₂) via an ultrasonic impregnation process. Compared with the pristine and Al₂O₃/SiO₂-sole-modified counterparts, the Al₂O₃·SiO₂ coating layer with high acid center strength on Li_1.18Ni_0.15Co_0.15Mn_0.52O₂ material exhibits overall improved electrochemical performance. Galvanostatic charge–discharge tests at the current density of 200 mA g⁻¹ displays the highest capacity retention of 72.5% and voltage retention of 95.1% after 200 cycles for Al₂O₃·SiO₂-coated material. Meanwhile, a high rate capability of 99.2 mAh g⁻¹ after 300 cycles is obtained with a good retention of 65.7% at the current density of 1 A g⁻¹. The analysis of dQ/dV plots indicates the strong acid center strength of Al₂O₃·SiO₂ coating layer on Li_1.18Ni_0.15Co_0.15Mn_0.52O₂ cathode material can be favor of suppressing the voltage decay and reducing the side reactions between the electrode and the electrolyte.

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Title: Enhanced electrochemical performance of Li1.18Ni0.15Co0.15Mn0.52O2 cathode modified with aluminosilicate solid acid
Authors: Fang Hu
Dongxu Zhang
Fuhan Cui
Di Xie
Guihong Song
Publication date: 09-11-2019
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-019-02497-1

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