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Journal of Materials Science: Materials in Electronics

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04-05-2021

Enhanced energy storage properties at phase boundary in Fe‐doped Ba(Zr_0.04Ti_0.96)O₃ ceramics with a slush polar state

Authors: Yu Fang, Yucong Zhang, Chen Wu, Changyi Liu, Wenwei Ge, Hongwei Zhao, Hongming Yuan

Published in: Journal of Materials Science: Materials in Electronics | Issue 10/2021

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Abstract

The relationship between phase boundary and energy storage properties in x mol% Fe-doped Ba(Zr_0.04Ti_0.96)O₃ (BZT4-xFe) ceramics was studied. The BZT4-xFe (x = 0 ~ 2) ceramics were fabricated via a conventional solid-state reaction method. The average grain size (ξ) is reduced from ~ 1.63 to ~ 1.23 μm with increasing Fe-doping content. X-ray diffraction (XRD) reveals that orthorhombic (O) and tetragonal (T) phases coexist at x = 0 ~ 0.8 and a mixing of O and cubic (C) phases was observed at x = 1 ~ 2. A slush polar state with the coexistence of O and T phases appeared near the O-T transition temperature (T_O−T) in BZT4-xFe (x = 0 ~ 0.8) ceramics. A critical behavior can be observed in the BZT4-xFe ceramics. The O-T phase boundary with the slush polar state can increase the energy storage density W_rec in BZT4-xFe ceramics. The energy storage properties of BZT4-0.4Fe ceramics exhibit a good temperature, frequency, and fatigue stability.

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Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Lead-free piezoceramics. Nature. 432, 81–84 (2004). https://doi.org/10.1038/nature03008CrossRef

T. Zheng, J. Wu, D. Xiao, J. Zhu, Recent development in lead-free perovskite piezoelectric bulk materials. Prog. Mater Sci. 98, 552–624 (2018). https://doi.org/10.1016/j.pmatsci.2018.06.002CrossRef

J. Rödel, W. Jo, K.T.P. Seifert, E.-M. Anton, T. Granzow, D. Damjanovic, Perspective on the development of lead-free piezoceramics. J. Am. Ceram. Soc. 92, 1153–1177 (2009). https://doi.org/10.1111/j.1551-2916.2009.03061.xCrossRef

W. Liu, X. Ren, Large piezoelectric effect in Pb-free ceramics. Phys. Rev. Lett. 103, 257602 (2009). https://doi.org/10.1103/PhysRevLett.103.257602CrossRef

F. Cordero, F. Craciun, M. Dinescu, N. Scarisoreanu, C. Galassi, W. Schranz, V. Soprunyuk, Elastic response of (1-x)Ba(Ti_0.8Zr_0.2)O₃-x(Ba_0.7Ca_0.3)TiO₃ (x = 0.45–0.55) and the role of the intermediate orthorhombic phase in enhancing the piezoelectric coupling. Appl. Phys. Lett. 105, 232904 (2014). https://doi.org/10.1063/1.4903807CrossRef

P. Jaiban, P. Wannasut, R. Yimnirun, A. Watcharapasorn, Influences of acceptor dopants (Cu, Mg, Fe) on electrical and optical properties of Ba_0.7Ca_0.3TiO₃ ceramics. Mater. Res. Bull. 118, 110501 (2019). https://doi.org/10.1016/j.materresbull.2019.110501CrossRef

P. Jaiban, M. Tongtham, P. Wannasut, N. Pisitpipathsin, O. Namsar, N. Chanlek, S. Pojprapai, R. Yimnirun, R. Guo, A.S. Bhalla, A. Watcharapasorn, Phase characteristics, microstructure, and electrical properties of (1-x)BaZr_0.2Ti_0.8O₃-(x)(Ba_0.7Ca_0.3)_0.985La_0.01TiO₃ ceramics. Ceram. Int. 45, 17502–17511 (2019). https://doi.org/10.1016/j.ceramint.2019.05.312CrossRef

P. Jaiban, A. Watcharapasorn, R. Yimnirun, R. Guo, A.S. Bhalla, Dielectric, ferroelectric and piezoelectric properties of (Ba_0.7Ca_0.3)Ti_{1 – x}Cu_xO_3–x ceramics. J. Alloys Compd. 759, 120–127 (2018). https://doi.org/10.1016/j.jallcom.2018.05.093CrossRef

P. Jaiban, A. Watcharapasorn, R. Yimnirun, R. Guo, A.S. Bhalla, Effects of donor and acceptor doping on dielectric and ferroelectric properties of Ba_0.7Ca_0.3TiO₃ lead-free ceramics. J. Alloys Compd. 695, 1329–1335 (2017). https://doi.org/10.1016/j.jallcom.2016.10.274CrossRef

10.

H. Cao, F. Bai, N. Wang, J. Li, D. Viehland, G. Xu, G. Shirane, Intermediate ferroelectric orthorhombic and monoclinic MB phases in [110] electric-field-cooled Pb(Mg_1/3Nb_2/3)O₃-30 %PbTiO₃ crystals. Phys. Rev. B 72, 064104 (2005). https://doi.org/10.1103/PhysRevB.72.064104CrossRef

11.

I. Levin, E. Cockayne, V. Krayzman, J.C. Woicik, S. Lee, C.A. Randall, Local structure of Ba(Ti, Zr)O₃ perovskite-like solid solutions and its relation to the band-gap behavior. Phys. Rev. B 83, 094122 (2011). https://doi.org/10.1103/PhysRevB.83.094122CrossRef

12.

L. Dong, D.S. Stone, R.S. Lakes, Enhanced dielectric and piezoelectric properties of xBaZrO₃-(1-x)BaTiO₃ ceramics. J. Appl. Phys. 111, 084107 (2012). https://doi.org/10.1063/1.4705467CrossRef

13.

S. Priya, K. Uchino, D. Viehland, Fe-substituted 0.92Pb(Zn_1/3Nb_2/3)O₃-0.08PbTiO₃ single crystals: a “hard” piezocrystal. Appl. Phys. Lett. 81, 2430–2432 (2002). https://doi.org/10.1063/1.1507831CrossRef

14.

M. Gao, W. Ge, X. Li, H. Yuan, C. Liu, H. Zhao, Y. Ma, Y. Chang, Enhanced dielectric and energy storage properties in Fe-doped BCZT ferroelectric ceramics. Phys. Status Solid 217, 2000253 (2020). https://doi.org/10.1002/pssa.202000253CrossRef

15.

L. Shi, B. Zhang, Q. Liao, L. Zhu, L. Zhao, D. Zhang, D. Guo, Piezoelectric properties of Fe₂O₃ doped BiYbO₃-Pb(Zr, Ti)O₃ high Curie temperature ceramics. Ceram. Int. 40, 11485–11491 (2014). https://doi.org/10.1016/j.ceramint.2013.10.043CrossRef

16.

E. Erdem, K. Kiraz, M. Somer, R.-A. Eichel, Size effects in Fe³⁺-doped PbTiO₃ nanocrystals-Formation and orientation of (Fe’_Ti-V_O••)• defect-dipoles. J. Eur. Ceram. Soc. 30, 289–293 (2010). https://doi.org/10.1016/j.jeurceramsoc.2009.04.034CrossRef

17.

V. Porokhonskyy, D. Damjanovic, Separation of piezoelectric grain resonance and domain wall dispersion in Pb(Zr, Ti)O₃ ceramics. Appl. Phys. Lett. 94, 212906 (2009). https://doi.org/10.1063/1.3147166CrossRef

18.

Q. Liao, X. Chen, X. Chu, F. Zeng, D. Guo, Effect of Fe doping on the structure and electric properties of relaxor type BSPT-PZN piezoelectric ceramics near the morphotropic phase boundary. Sens. Actuat. A 201, 222–229 (2013). https://doi.org/10.1016/j.sna.2013.07.024CrossRef

19.

K. Hao, W. Ge, Z. Ren, X. Liu, L. Luo, X. Li, H. Luo, D. Viehland, Combining effects of TiO₆ octahedron rotations and random electric fields on structural and properties in Na_0.5Bi_0.5TiO₃. J. Am. Ceram. Soc. 103, 3349–3360 (2020). https://doi.org/10.1111/jace.16986CrossRef

20.

M.-K. Zhu, P.-X. Lu, Y.-D. Hou, X.-M. Song, H. Wang, H. Yan, Analysis of phase coexistence in Fe₂O₃-doped 0.2PZN-0.8PZT ferroelectric ceramics by raman scattering spectra. J. Am. Ceram. Soc. 89, 3739–3744 (2006). https://doi.org/10.1111/j.1551-2916.2006.01281.xCrossRef

21.

G.-P. Du, Z.-J. Hu, Q.-F. Han, X.-M. Qin, W.-Z. Shi, Effects of niobium donor doping on the phase structures and magnetic properties of Fe-doped BaTiO₃ ceramics. J. Alloys Compd. 492, L79–L81 (2010). https://doi.org/10.1016/j.jallcom.2009.12.031CrossRef

22.

X. Qin, D. Shihua, S. Tianxiu, W. Hongni, Diffuse phase transition of Ba_0.92Ca_0.08(Ti_0.82Zr_0.18)O₃ based ceramics. Ferroelectrics. 426, 282–289 (2012). https://doi.org/10.1080/00150193.2012.672042CrossRef

23.

N. Vittayakorn, G. Rujijanagul, X. Tan, M.A. Marquardt, D.P. Cann, The morphotropic phase boundary and dielectric properties of the xPb(Zr_1/2Ti_1/2)O₃-(1-x)Pb(Ni_1/3Nb_2/3)O₃ perovskite solid solution. J. Appl. Phys. 96, 5103–5109 (2004). https://doi.org/10.1063/1.1796511CrossRef

24.

L. Yang, B.A. Tyburski, F. Santos, M.K. D D, Endoh, T. Koga, D. Huang, Y. Wang, L. Zhu, Relaxor ferroelectric behavior from strong physical pinning in a poly(vinylidene fluoride-co-trifluoroethylene-co-chlorotrifluoroethylene) random terpolymer. Macromolecules 47, 8119–8125 (2014). https://doi.org/10.1021/ma501852xCrossRef

25.

H. Takenaka, I. Grinberg, S. Liu, A.M. Rappe, Slush-like polar structures in single-crystal relaxors. Nature. 546, 391–395 (2017). doi:https://doi.org/10.1038/nature22068CrossRef

26.

H. Tao, H. Wu, Y. Liu, Y. Zhang, J. Wu, F. Li, X. Lyu, C. Zhao, D. Xiao, J. Zhu, S.J. Pennycook, Ultrahigh performance in lead-free piezoceramics utilizing a relaxor slush polar state with multiphase coexistence. J. Am. Chem. Soc. 141, 13987–13994 (2019). https://doi.org/10.1021/jacs.9b07188CrossRef

27.

J. Hao, W. Bai, W. Li, J. Zhai, Correlation between the microstructure and electrical properties in high-performance (Ba_0.85Ca_0.15)(Zr_0.1Ti_0.9)O₃ lead-free piezoelectric ceramics. J. Am. Ceram. Soc. 30871, 1–9 (2012). https://doi.org/10.1111/j.1551-2916.2012.05146.xCrossRef

28.

Y. Wang, S. Gao, T. Wang, J. Liu, D. Li, H. Yang, G. Hu, L. Kong, F. Wang, G. Liu, Structure, dielectric properties of novel Ba(Zr, Ti)O₃ based ceramics for energy storage application. Ceram. Int. 46, 12080–12087 (2020). https://doi.org/10.1016/j.ceramint.2020.01.251CrossRef

29.

S. Jiang, L. Zhang, G. Zhang, S. Liu, J. Yi, X. Xiong, Y. Yu, J. He, Y. Zeng, Effect of Zr:Sn ratio in the lead lanthanum zirconate stannate titanate anti-ferroelectric ceramics on energy storage properties. Ceram. Int. 39, 5571–5575 (2013). https://doi.org/10.1016/j.ceramint.2012.12.071CrossRef

30.

D. Zheng, R. Zuo, Enhanced energy storage properties in La(Mg_1/2Ti_1/2)O₃-modified BiFeO₃-BaTiO₃ lead-free relaxor ferroelectric ceramics within a wide temperature range. J. Eur. Ceram. Soc. 37, 413–418 (2017). https://doi.org/10.1016/j.jeurceramsoc.2016.08.021CrossRef

31.

Z. Wang, J. Wang, X. Chao, L. Wei, B. Yang, D. Wang, Z. Yang, Synthesis, structure, dielectric, piezoelectric, and energy storage performance of (Ba_0.85Ca_0.15)(Ti_0.9Zr_0.1)O₃ ceramics prepared by different methods. J. Mater. Sci. 27, 5047–5058 (2016). https://doi.org/10.1007/s10854-016-4392-xCrossRef

32.

H. Yang, F. Yan, Y. Lin, T. Wang, Novel strontium titanate-based lead-free ceramics for high-energy storage applications. ACS Sustain. Chem. Eng. 5, 10215–10222 (2017). https://doi.org/10.1021/acssuschemeng.7b02203CrossRef

33.

A.K. Kalyani, A. Senyshyn, R. Ranjan, Polymorphic phase boundaries and enhanced piezoelectric response in extended composition range in the lead free ferroelectric BaTi_{1 – x}Zr_xO₃. J. Appl. Phys. 114, 014102 (2013). https://doi.org/10.1063/1.4812472CrossRef

34.

W. Ge, J. Li, D. Viehland, Y. Chang, G.L. Messing, Electric-field-dependent phase volume fractions and enhanced piezoelectricity near the polymorphic phase boundary of (K_0.5Na_0.5)_1–xLi_xNbO₃ textured ceramics. Phys. Rev. B 83, 224110 (2011). https://doi.org/10.1103/PhysRevB.83.224110CrossRef

35.

Z. Zhao, X. Li, H. Ji, Y. Dai, T. Li, Microstructure and electrical properties in Zn-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ piezoelectric ceramics. J. Alloys Compd. 637, 291–296 (2015). https://doi.org/10.1016/j.jallcom.2015.02.093CrossRef

36.

S. Patel, N. Novak, The pyroelectric energy harvesting and storage performance around the ferroelectric/antiferroelectric transition in PNZST. J. Mater. Sci. 56, 1133–1146 (2020). https://doi.org/10.1007/s10853-020-05353-4CrossRef

37.

Z. Sun, L. Li, J. Li, H. Zheng, W. Luo, Influence of Nb₂O₅ addition on dielectric properties and diffuse phase transition behavior of BaZr_0.2Ti_0.8O₃ ceramics. Ceram. Int. 42, 10833–10837 (2016). https://doi.org/10.1016/j.ceramint.2016.03.212CrossRef

38.

C. Kruea-In, G. Rujijanagul, Electrical properties and phase transition of Ba(Zr_0.05Ti_0.95)_1–x(Fe_0.5Ta_0.5)_xO₃ ceramics. Mater. Res. Bull. 69, 36–40 (2015). https://doi.org/10.1016/j.materresbull.2015.01.027CrossRef

39.

J. Fan, B. Yang, L. Wei, Z. Wang, B-cation effect on relaxor behavior and electric properties in Sr₂NaNb_5–xSb_xO₁₅ tungsten bronze ceramics. Ceram. Int. 42, 4054–4062 (2016). https://doi.org/10.1016/j.ceramint.2015.11.077CrossRef

40.

M.-K. Zhu, P.-X. Lu, Y.-D. Hou, H. Wang, H. Yan, Effects of Fe₂O₃ addition on microstructure and piezoelectric properties of 0.2PZN-0.8PZT ceramics. J. Mater. Res. 20, 2670–2675 (2011). https://doi.org/10.1557/jmr.2005.0339CrossRef

41.

S.J. Kuang, X.G. Tang, L.Y. Li, Y.P. Jiang, Q.X. Liu, Influence of Zr dopant on the dielectric properties and Curie temperatures of Ba(Zr_xTi_1–x)O₃ (0 ≤ x ≤ 0.12) ceramics. Scr. Mater. 61, 68–71 (2009). https://doi.org/10.1016/j.scriptamat.2009.03.016CrossRef

Title: Enhanced energy storage properties at phase boundary in Fe‐doped Ba(Zr0.04Ti0.96)O3 ceramics with a slush polar state
Authors: Yu Fang
Yucong Zhang
Chen Wu
Changyi Liu
Wenwei Ge
Hongwei Zhao
Hongming Yuan
Publication date: 04-05-2021
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 10/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-021-05973-9

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