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Journal of Materials Science

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05-06-2017 | Composites

Enhanced mechanical, dielectric, electrical and thermal conductive properties of HXNBR/HNBR blends filled with ionic liquid-modified multiwalled carbon nanotubes

Authors: Qing Yin, Yanwei Wen, Hongbing Jia, Liu Hong, Qingmin Ji, Zhaodong Xu

Published in: Journal of Materials Science | Issue 18/2017

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Abstract

1-Butyl 3-methylimidazolium bis(trifluoromethylsulfonyl) imide (BMI)-modified multiwalled carbon nanotubes (MWCNTs) were used as nanofillers for the hydrogenated carboxylated nitrile–butadiene rubber/hydrogenated nitrile–butadiene rubber (HXNBR/HNBR) blends. The multifunctional properties of rubber nanocomposites with various filler loadings were investigated. It was found that in the presence of BMI-MWCNTs, the mechanical strength, dielectric properties, electrical and thermal conductivities of HXNBR/HNBR were significantly improved due to the better dispersibility as well as the intrinsic reinforcement effect of MWCNTs. Particularly, in comparison with unfilled rubber blend, the electrical conductivity of BMI-MWCNTs-filled HXNBR/HNBR composites exhibited three orders of magnitude enhancement with a lower electrical percolation threshold. The tensile strength and thermal conductivity of composites filled with 5 phr (parts per hundred rubber) BMI-MWCNTs increased by 52 and 23%, respectively. In addition, the polarizability of composites was also intensified under the applied electric field, which resulted in remarkable dielectric relaxation compared to neat rubber. Our experimental data have indicated that BMI-MWCNTs can be used as a promising candidate for fabricating multifunctional HXNBR/HNBR nanocomposites.

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Psarras GC, Sofos GA, Vradis A, Anastassopoulos DL, Georga SN, Krontiras CA, Karger-Kocsis J (2014) HNBR and its MWCNT reinforced nanocomposites: crystalline morphology and electrical response. Eur Polym J 54:190–199CrossRef

Pan L, Tan J, Han X, Li P, Zhang W (2016) Effects of elevated temperature and crude oil on the properties of a hydrogenated nitrile butadiene rubber elastomer. J Appl Polym Sci 133:44012

Han Y, Mao L, Meng H, Zhang L, Yue D (2014) Novel self-crosslinking film from hydrogenated carboxylated nitrile rubber latex. J Appl Polym Sci 131:39865

Perraud S, Vallat MF, David MO, Kuczynski J (2010) Network characteristics of hydrogenated nitrile butadiene rubber networks obtained by radiation crosslinking by electron beam. Polym Degrad Stab 95:1495–1501CrossRef

Pan L, Tan J (2015) Numerical investigation of contact stress between rotor and stator in a two-lead progressing cavity pump. J Pet Sci Eng 134:176–185CrossRef

Cao Y, Zhang J, Feng J, Wu P (2011) Compatibilization of immiscible polymer blends using graphene oxide sheets. ACS Nano 5:5920–5927CrossRef

Guo B, Tang Z, Zhang L (2016) Transport performance in novel elastomer nanocomposites: mechanism, design and control. Prog Polym Sci 61:29–66CrossRef

Deng F, Ito M, Noguchi T, Wang L, Ueki H, Niihara K, Kim YA, Endo M, Zheng QS (2011) Elucidation of the reinforcing mechanism in carbon nanotube/rubber nanocomposites. ACS Nano 5:3858–3866CrossRef

Gogotsi Y (2010) High-temperature rubber made from carbon nanotubes. Science 330:1332–1333CrossRef

10.

Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205CrossRef

11.

Bokobza L (2007) Multiwall carbon nanotube elastomeric composites: a review. Polymer 48:4907–4920CrossRef

12.

Lu L, Zhai Y, Zhang Y, Ong C, Guo S (2008) Reinforcement of hydrogenated carboxylated nitrile-butadiene rubber by multi-walled carbon nanotubes. Appl Surf Sci 255:2162–2166CrossRef

13.

George N, Chandra J, Mathiazhagan A, Joseph R (2015) High performance natural rubber composites with conductive segregated network of multiwalled carbon nanotubes. Compos Sci Technol 116:33–40CrossRef

14.

Fukushima T, Kosaka A, Ishimura Y, Yamamoto T, Takigawa T, Ishii N, Aida T (2003) Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes. Science 300:2072–2074CrossRef

15.

Subramaniam K, Das A, Steinhauser D, Klüppel M, Heinrich G (2011) Effect of ionic liquid on dielectric, mechanical and dynamic mechanical properties of multi-walled carbon nanotubes/polychloroprene rubber composites. Eur Polym J 47:2234–2243CrossRef

16.

Abraham J, Arif M, Kailas L, Kalarikkal N, George SC, Thomas S (2016) Developing highly conducting and mechanically durable styrene butadiene rubber composites with tailored microstructural properties by a green approach using ionic liquid modified MWCNTs. RSC Adv 6:32493–32504CrossRef

17.

Natarajan B, Li Y, Deng H, Brinson LC, Schadler LS (2013) Effect of interfacial energetics on dispersion and glass transition temperature in polymer nanocomposites. Macromolecules 46:2833–2841CrossRef

18.

Fukushima T, Aida T (2007) Ionic liquids for soft functional materials with carbon nanotubes. Chem Eur J 13:5048–5058CrossRef

19.

Tan P, Zhang SL, Yue KT, Huang F, Shi Z, Zhou X, Gu Z (1997) Comparative study of carbon nanotubes Raman prepared by D.C. Arc discharge and catalytic methods. J Raman Spectrosc 28:369–372CrossRef

20.

Laskowska A, Marzec A, Boiteux G, Zaborski M, Gain O, Serghei A (2013) Effect of imidazolium ionic liquid type on the properties of nitrile rubber composites. Polym Int 62:1575–1582

21.

Bai X, Wan C, Zhang Y, Zhai Y (2011) Reinforcement of hydrogenated carboxylated nitrile-butadiene rubber with exfoliated graphene oxide. Carbon 49:1608–1613CrossRef

22.

Yu MF, Lourie O, Dyer MJ, Moloni K, Kelly TF, Ruoff RS (2000) Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load. Science 287:637–640CrossRef

23.

Tang Z, Wu X, Guo B, Zhang L, Jia D (2012) Preparation of butadiene-styrene-vinyl pyridine rubber-graphene oxide hybrids through co-coagulation process and in situ interface tailoring. J Mater Chem 22:7492–7501CrossRef

24.

Bokobza L (2004) The reinforcement of elastomeric networks by fillers. Macromol Mater Eng 289:607–621CrossRef

25.

Xing W, Wu J, Huang G, Li H, Tang M, Fu X (2014) Enhanced mechanical properties of graphene/natural rubber nanocomposites at low content. Polym Int 63:1674–1681CrossRef

26.

Tang Z, Zhang L, Feng W, Guo B, Liu F, Jia D (2014) Rational design of graphene surface chemistry for high-performance rubber/graphene composites. Macromolecules 47:8663–8673CrossRef

27.

Wang J, Jia H, Tang Y, Ji D, Sun Y, Gong X, Ding L (2013) Enhancements of the mechanical properties and thermal conductivity of carboxylated acrylonitrile butadiene rubber with the addition of graphene oxide. J Mater Sci 48:1571–1577. doi:10.1007/s10853-012-6913-1 CrossRef

28.

Zhang X, Wang J, Jia H, You S, Xiong X, Ding L, Xu Z (2016) Multifunctional nanocomposites between natural rubber and polyvinyl pyrrolidone modified graphene. Compos Part B Eng 84:121–129CrossRef

29.

Liu M, Peng Q, Luo B, Zhou C (2015) The improvement of mechanical performance and water-response of carboxylated SBR by chitin nanocrystals. Eur Polym J 68:190–206CrossRef

30.

Subramaniam K, Das A, Simon F, Heinrich G (2013) Networking of ionic liquid modified CNTs in SSBR. Eur Polym J 49:345–352CrossRef

31.

Scott MP, Brazel CS, Benton MG, Mays JW, Holbrey JD, Rogers RD (2002) Application of ionic liquids as plasticizers for poly(methyl methacrylate). Chem Commun 13:1370–1371CrossRef

32.

Marzec A, Laskowska A, Boiteux G, Zaborski M, Gain O, Serghei A (2014) The impact of imidazolium ionic liquids on the properties of nitrile rubber composites. Eur Polym J 53:139–146CrossRef

33.

Song YS, Youn JR (2005) Influence of dispersion states of carbon nanotubes on physical properties of epoxy nanocomposites. Carbon 43:1378–1385CrossRef

34.

Subramaniam K, Das A, Heinrich G (2011) Development of conducting polychloroprene rubber using imidazolium based ionic liquid modified multi-walled carbon nanotubes. Compos Sci Technol 71:1441–1449CrossRef

35.

Patsidis AC, Kalaitzidou K, Psarras GC (2014) Graphite nanoplatelets/polymer nanocomposites: thermomechanical, dielectric, and functional behavior. J Therm Anal Calorim 116:41–49CrossRef

36.

Tian C, Du Y, Xu P, Qiang R, Wang Y, Ding D, Xue J, Ma J, Zhao H, Han X (2015) Constructing uniform core-shell PPy@PANI composites with tunable shell thickness toward enhancement in microwave absorption. ACS Appl Mater Interfaces 7:20090–20099CrossRef

37.

Karahaliou PK, Kerasidou AP, Georga SN, Psarras GC, Krontiras CA, Karger-Kocsis J (2014) Dielectric relaxations in polyoxymethylene and in related nanocomposites: identification and molecular dynamics. Polymer 55:6819–6826CrossRef

38.

Karahaliou PK, Svarnas P, Georga SN, Xanthopoulos NI, Delaportas D, Krontiras CA, Alexandrou I (2012) Cuo/Ta₂O₅ core/shell nanoparticles synthesized in immersed arc-discharge: production conditions and dielectric response. J Nanopart Res 14:1297CrossRef

39.

Zhang X, Dong X, Huang H, Liu Y, Wang W, Zhu X, Lv B, Lei J, Lee C (2006) Microwave absorption properties of the carbon-coated nickel nanocapsules. Appl Phys Lett 89:053115CrossRef

40.

Han Z, Fina A (2011) Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review. Prog Polym Sci 36:914–944CrossRef

41.

Agari Y, Ueda A, Omura Y, Nagai S (1997) Thermal diffusivity and conductivity of PMMA/PC blends. Polymer 38:801–807CrossRef

42.

Araby S, Meng Q, Zhang L, Kang H, Majewski P, Tang Y, Ma J (2014) Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing. Polymer 55:201–210CrossRef

43.

Zhou S, Xu J, Yang QH, Chiang S, Li B, Du H, Xu C, Kang F (2013) Experiments and modeling of thermal conductivity of flake graphite/polymer composites affected by adding carbon-based nano-fillers. Carbon 57:452–459CrossRef

44.

Im H, Kim J (2012) Thermal conductivity of a graphene oxide-carbon nanotube hybrid/epoxy composite. Carbon 50:5429–5440CrossRef

45.

Burger N, Laachachi A, Ferriol M, Lutz M, Toniazzo V, Ruch D (2016) Review of thermal conductivity in composites: mechanisms, parameters and theory. Prog Polym Sci 61:1–28CrossRef

46.

Pradhan NR, Duan H, Liang J, Iannacchione GS (2009) The specific heat and effective thermal conductivity of composites containing single-wall and multi-wall carbon nanotubes. Nanotechnology 20:245705CrossRef

47.

Giri A, Hopkins PE, Wessel JG, Duda JC (2015) Kapitza resistance and the thermal conductivity of amorphous superlattices. J Appl Phys 118:165303CrossRef

Title: Enhanced mechanical, dielectric, electrical and thermal conductive properties of HXNBR/HNBR blends filled with ionic liquid-modified multiwalled carbon nanotubes
Authors: Qing Yin
Yanwei Wen
Hongbing Jia
Liu Hong
Qingmin Ji
Zhaodong Xu
Publication date: 05-06-2017
Publisher: Springer US
Published in: Journal of Materials Science / Issue 18/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1251-y

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