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Journal of Polymer Research

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01-10-2023 | Original Paper

Enhancement of mechanical properties of epoxy resin matrix adhesives by high-performance fillers

Authors: Hang Xu, Xiaorui Zhang, Yating Yu, Yang Yu, Zhou Yang, Xingsong Zhu, Ling Weng

Published in: Journal of Polymer Research | Issue 10/2023

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Abstract

This study aims to prepare functional fillers using isophorone diisocyanate (IPDI), amine-terminated butadiene acrylonitrile (ATBN), and graphene oxide (GO) to improve the performance of epoxy resin (EP) composite materials by enhancing filler dispersion and toughening. Unexpected results were obtained during the experimental and testing phases, achieving multiple bonding mechanisms. Successful grafting of IPDI and ATBN onto GO was confirmed using TEM, FT-IR, and XPS. The prepared composites underwent T-peel, shear, tensile, and impact testing. Compared to pure EP, the T-peel strength increased by 579%, the shear strength increased by 99%, and Al elements were detected in the T-peel samples. The tensile strength increased by 134%, and the impact strength increased by 65%, with an analysis of the impact morphology to explore the mechanism of IPDI and ATBN enhancement. Additionally, the dynamic mechanical performance of EP and its composites was tested, and various forms of T_g were analyzed. This functional filler can be applied to various resin matrices and effectively improve their performance.

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Kanari K et al (2022) Interlaminar fracture toughness of carbon fibre composites with electrospun nanofibrous interleaves of polystyrene and cellulose nanocrystals. J Mater Sci 57(45):21080CrossRef

Attar A et al (2022) Fabrication, characterization, TD-DFT, optical and electrical properties of poly (aniline-co-para nitroaniline)/ZrO2 composite for solar cell applications. J Ind Eng Chem 109:230CrossRef

Kim TG et al (2021) Dispersibility-tailored conductive epoxy nanocomposites with silica nanoparticle-embedded silver nanowires. Polym Test 96:107111CrossRef

Zhao G et al (2020) The tribological behaviors of core-shell n-octadecane@TiO2/epoxy composites. Polym Compos 41(11):4872CrossRef

Okoroanyanwu U et al (2021) Rapid preparation and electrochemical energy storage applications of silicon carbide and silicon oxycarbide ceramic/carbon nanocomposites derived via flash photothermal pyrolysis of organosilicon preceramic polymers. Chem Mater 33(2):678CrossRef

Armstrong M et al (2020) Composite materials made from glass microballoons and ceramic nanofibers for use as catalysts and catalyst supports. J Mater Sci 55(27):12940CrossRef

Wang B et al (2019) Multi-walled carbon nanotube-reinforced boron carbide matrix composites fabricated via ultra-high-pressure sintering. J Mater Sci 54(16):11084CrossRef

Chanda A et al (2022) Fiber alignment and mode-mixity effects on fracture behavior of CNF/epoxy nanocomposite adhesive joints. Compos Part B Eng 247:110341CrossRef

Cakir MV, Kinay D (2021) MWCNT, nano-silica, and nano-clay additives effects on adhesion performance of dissimilar materials bonded joints. Polym Compos 42(11):5880CrossRef

10.

Sanghvi MR et al (2022) Performance of various fillers in adhesives applications: a review. Polym Bull (Berlin) 79(12):10491CrossRef

11.

Wang Z et al (2018) Graphene nanoplatelets/epoxy composites with excellent shear properties for construction adhesives. Compos Part B Eng 152:311CrossRef

12.

Ge Y et al (2022) Super-flexibility and high-temperature adhesion of epoxy structural adhesives endowed by homogeneous rigid-flexible crosslinking networks. Ind Eng Chem Res 61(30):10990CrossRef

13.

Gonçalves FAMM et al (2022) Influence of fillers on epoxy resins properties: a review. J Mater Sci 57(32):15183CrossRef

14.

Ahmadi Z (2019) Nanostructured epoxy adhesives: A review. Prog Org Coat 135:449CrossRef

15.

Chen Y et al (2022) High-epoxy value bio-based epoxy emulsion reinforced interfacial properties of carbon fiber/epoxy composites. J Appl Polym Sci 139(13):51855CrossRef

16.

Amirbeygi H et al (2019) Reinforcing effects of aminosilane-functionalized graphene on the tribological and mechanical behaviors of epoxy nanocomposites. J Appl Polym Sci 136(18):47410CrossRef

17.

Mostovoy AS et al (2020) Reinforcing effects of aminosilane-functionalized h-BN on the physicochemical and mechanical behaviors of epoxy nanocomposites. Sci Rep 10(1):10676CrossRefPubMedPubMedCentral

18.

Chen Y et al (2021) A simple way to synthesize a nano-scale stable epoxy emulsion for sizing CF/epoxy composites. New J Chem 45(48):22860CrossRef

19.

Luo J et al (2023) Simultaneous optimization of the thermal conductivity and mechanical properties of epoxy resin composites through PES and AgNP functionalized BNs. Compos Part B Eng 248:110373CrossRef

20.

Long J et al (2022) Enhancement of mechanical and bond properties of epoxy adhesives modified by SiO2 nanoparticles with active groups. Polymers 14(10):2052CrossRefPubMedPubMedCentral

21.

Lv C et al (2021) Robust, healable and hydrophobically recoverable polydimethylsiloxane based supramolecular material with dual-activate hard segment. Sci China Technol Sci 64(2):423CrossRef

22.

Chauhan K, Tiwari RK (2020) Study of thermomechanical properties of glycidoxypropyl trimethoxy silane functionalized nanosilica/amine terminated poly (butadiene-co-acrylonitrile) rubber modified novolac epoxy composites for high performance applications. J Polym Res 27(10):319CrossRef

23.

Gironès J et al (2007) Blocked isocyanates as coupling agents for cellulose-based composites. Carbohyd Polym 68(3):537CrossRef

24.

Coutinho FMB, Rocha MCG (1991) Kinetic study of the reactions between hydroxylated polybutadiene and isocyanates in chlorobenzene—IV. Reactions with tolylene diisocyanate, 3-isocyanatomethyl-3, 5, 5-trimethylcyclohexyl isocyanate and hexamethylene diisocyanate. Eur Polym J 27(2):213CrossRef

25.

Hu G et al (2018) Improvement of graphene oxide/epoxy resin adhesive properties through interface modification. High Perform Polym 31(3):341CrossRef

26.

Xu H et al (2020) High thermal conductivity EP adhesive based on the GO/EP interface optimized by TDI. Polym Adv Technol 31(6):1356CrossRef

27.

Bagherzadeh A et al (2020) Investigating mechanical and bonding properties of micro/nano filler containing epoxy adhesives for anchoring steel bar in concrete. Construct Build Mater 240:117979CrossRef

28.

Aliakbari M et al (2019) Multi-nationality epoxy adhesives on trial for future nanocomposite developments. Prog Org Coat 133:376CrossRef

29.

Lin P et al (2015) Simultaneously functionalization and reduction of graphene oxide containing isocyanate groups. Appl Surf Sci 324:784CrossRef

30.

Zhang Y et al (2018) Interlayer polymerization in amine-terminated macromolecular chain-grafted expanded graphite for fabricating highly thermal conductive and physically strong thermoset composites for thermal management applications. Compos Part A Appl Sci Manuf 109:498CrossRef

31.

Basak GC et al (2012) The role of tackifiers on the auto-adhesion behavior of EPDM rubber. J Mater Sci 47(7):3166CrossRef

32.

Weiss H (1995) Adhesion of advanced overlay coatings: mechanisms and quantitative assessment. Surf Coat Technol 71(2):201CrossRef

33.

Khraponichev K et al (2021) Effect of rapid manufacturing on the performance of carbon fibre epoxy polymers. J Mater Sci 56(10):6188CrossRef

34.

Derakhshankhah H et al (2020) Conducting polymer-based electrically conductive adhesive materials: design, fabrication, properties, and applications. J Mater Sci Mater Electron 31(14):10947CrossRef

35.

Ochi M et al (1989) Effect of the introduction of methoxy branches on low-temperature relaxations and fracture toughness of epoxide resins. Polymer 30(6):1079CrossRef

36.

da Silva LFM et al (2006) Effect of adhesive type and thickness on the lap shear strength. J Adhes 82(11):1091CrossRef

37.

Kenyon AS, Nielsen LE (1969) Characterization of network structure of epoxy resins by dynamic mechanical and liquid swelling tests. J Macromol Sci Part A - Chem 3(2):275CrossRef

38.

Tobolsky AV, Callinan TD (1960) Properties and structure of polymers. J Electrochem Soc 107(10):243CCrossRef

Title: Enhancement of mechanical properties of epoxy resin matrix adhesives by high-performance fillers
Authors: Hang Xu
Xiaorui Zhang
Yating Yu
Yang Yu
Zhou Yang
Xingsong Zhu
Ling Weng
Publication date: 01-10-2023
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 10/2023
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03755-x

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