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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2020

01.10.2020 | ORIGINAL PAPER

Study of thermomechanical properties of glycidoxypropyl trimethoxy silane functionalized nanosilica/amine terminated poly (butadiene-co-acrylonitrile) rubber modified novolac epoxy composites for high performance applications

verfasst von: Kavita Chauhan, Rajesh Kumar Tiwari

Erschienen in: Journal of Polymer Research | Ausgabe 10/2020

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Abstract

Present study investigates the effect of functionalized fumed silica (f-silica) on the thermal; mechanical and thermomechanical properties of amine terminated polybutadiene-co-acrylonitrile rubber (ATBN) modified novolac epoxy resin. All the nanocomposites showed higher thermal stability as compared to the neat novolac epoxy. Maximum –55 ˚C increment in the peak degradation temperature was achieved in the nanocomposite containing 0.1 wt. % f-silica and 10 wt. % ATBN. Glass transition temperature of the nanocomposites was reduced as compared to neat novolac epoxy resin due to incorporation of ATBN. Thermomechanical analysis showed that crosslinking density of the ATBN/novolac epoxy composite was increased as compared to neat novolac epoxy, which was further reduced in the nanocomposites due to hardener capping effect of the f-silica. All the nanocomposites showed higher elongation at break as compared to neat novolac epoxy resin. Maximum –87 and 60% increment in tensile and flexural strengths were achieved in the nanocomposite containing 2 wt % f-silica and 10 wt. % ATBN. Impact strength of the nanocomposites was increased with increasing f-silica content. Preferential conglomeration of the f-silica nanoparticles was observed in the rubber phase which acted as the efficient energy absorption point during the impact testing.
Vorheriger Artikel RETRACTED ARTICLE: Synthesis and characterization of a novel locally high dense sulfonated poly (aryl ether ketone sulfone) for DMFCs applications
Nächster Artikel Synthesis of magnetic nanoparticles-decorated halloysite nanotubes/poly([2-(acryloyloxy)ethyl]trimethylammonium chloride) hybrid nanoparticles for removal of Sunset Yellow from water

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Metadaten
Titel
Study of thermomechanical properties of glycidoxypropyl trimethoxy silane functionalized nanosilica/amine terminated poly (butadiene-co-acrylonitrile) rubber modified novolac epoxy composites for high performance applications
verfasst von
Kavita Chauhan
Rajesh Kumar Tiwari
Publikationsdatum
01.10.2020
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02278-z

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