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Published in: Journal of Materials Science 6/2014

01-03-2014

Enhancement of the power conversion efficiency of polymer solar cells by functionalized single-walled carbon nanotubes decorated with CdSe/ZnS core–shell colloidal quantum dots

Authors: Ting Ni, Jingying Yan, Yurong Jiang, Fan Zou, Li Zhang, Dan Yang, Jinquan Wei, Shengyi Yang, Bingsuo Zou

Published in: Journal of Materials Science | Issue 6/2014

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Abstract

In this paper, we demonstrated an enhanced performance of polymer solar cells by incorporating functionalized single-walled carbon nanotubes (SWCNTs) decorated with CdSe/ZnS core–shell colloidal quantum dots (CQDs) into copolymers of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as active layer. Short-circuit current density and power conversion efficiency of the ITO/PEDOT:PSS/P3HT:PCBM:(CdSe/ZnS-SWCNTs)/Al solar cells can be enhanced by more than 31 and 23 %, respectively, as compared with the control device ITO/PEDOT:PSS/P3HT:PCBM/Al. This enhancement is due to the high electron-transporting ability of SWCNTs and the increased absorption of CdSe/ZnS CQD in visible region. It shows an applicable way to improve the efficiency of polymer solar cells by incorporating suitable quantity of CQDs-decorated SWCNTs with suitable kinds of CQDs and suitable acid treatment to the SWCNTs.

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Literature
1.
go back to reference Landi BJ, Castro SL, Ruf HJ, Evans CM, Bailey SG, Raffaelle RP (2005) CdSe quantum dot-single wall carbon nanotube complexes for polymeric solar cells. Sol Energy Mater Sol Cells 87:733–746CrossRef Landi BJ, Castro SL, Ruf HJ, Evans CM, Bailey SG, Raffaelle RP (2005) CdSe quantum dot-single wall carbon nanotube complexes for polymeric solar cells. Sol Energy Mater Sol Cells 87:733–746CrossRef
2.
go back to reference Chang LL, Lademann HWA, Bonekamp JB, Meerholz K, Moulé AJ (2011) Effect of trace solvent on the morphology of P3HT:PCBM bulk heterojunction solar cells. Adv Funct Mater 21:1779–1787CrossRef Chang LL, Lademann HWA, Bonekamp JB, Meerholz K, Moulé AJ (2011) Effect of trace solvent on the morphology of P3HT:PCBM bulk heterojunction solar cells. Adv Funct Mater 21:1779–1787CrossRef
3.
go back to reference Li G, Shrotriya V, Huang J, Yao Y, Moriarty T, Emery K, Yang Y (2005) High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends. Nat Mater 4:864–868CrossRef Li G, Shrotriya V, Huang J, Yao Y, Moriarty T, Emery K, Yang Y (2005) High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends. Nat Mater 4:864–868CrossRef
4.
go back to reference He ZC, Zhong CM, Su SJ, Xu M, Wu HB, Cao Y (2012) Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure. Nat Photonics 6:591–595 He ZC, Zhong CM, Su SJ, Xu M, Wu HB, Cao Y (2012) Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure. Nat Photonics 6:591–595
5.
go back to reference Markov DE, Amsterdam E, Blom PWM, Sieval AB, Hummelen JC (2005) Accurate measurement of the exciton diffusion length in a conjugated polymer using a heterostructure with a side-chain cross-linked fullerene layer. J Phys Chem A 109:5266–5274CrossRef Markov DE, Amsterdam E, Blom PWM, Sieval AB, Hummelen JC (2005) Accurate measurement of the exciton diffusion length in a conjugated polymer using a heterostructure with a side-chain cross-linked fullerene layer. J Phys Chem A 109:5266–5274CrossRef
6.
go back to reference Dixit SK, Madan S, Madhwal D, Kumar J, Singh I, Bhatia CS, Bhatnagar PK, Mathur PC (2012) Bulk heterojunction formation with induced concentration gradient from a bilayer structure of P3HT:CdSe/ZnS quantum dots using inter-diffusion process for developing high efficiency solar cell. Org Electron 13:710–714CrossRef Dixit SK, Madan S, Madhwal D, Kumar J, Singh I, Bhatia CS, Bhatnagar PK, Mathur PC (2012) Bulk heterojunction formation with induced concentration gradient from a bilayer structure of P3HT:CdSe/ZnS quantum dots using inter-diffusion process for developing high efficiency solar cell. Org Electron 13:710–714CrossRef
7.
go back to reference Landsber PT, Nussbaumer H, Willeke G (1993) Band–band impact ionisation and solar cell efficiency. J Appl Phys 74:1451–1452CrossRef Landsber PT, Nussbaumer H, Willeke G (1993) Band–band impact ionisation and solar cell efficiency. J Appl Phys 74:1451–1452CrossRef
8.
go back to reference Wang LD, Zhao DX, Su ZS, Li BH, Zhang ZZ, Shen DZ (2011) Enhanced efficiency of polymer/ZnO nanorods hybrid solar cell sensitized by CdS quantum dots. J Electrochem Soc 158:H804–H807CrossRef Wang LD, Zhao DX, Su ZS, Li BH, Zhang ZZ, Shen DZ (2011) Enhanced efficiency of polymer/ZnO nanorods hybrid solar cell sensitized by CdS quantum dots. J Electrochem Soc 158:H804–H807CrossRef
9.
go back to reference Kolodinski S, Werner JH, Wittchen T, Queisser HJ (1993) Quantum efficiencies exceeding unity due to impact ionization in silicon solar cells. Appl Phys Lett 63:2405–2407CrossRef Kolodinski S, Werner JH, Wittchen T, Queisser HJ (1993) Quantum efficiencies exceeding unity due to impact ionization in silicon solar cells. Appl Phys Lett 63:2405–2407CrossRef
10.
go back to reference Zhou YF, Riehle FS, Yuan Y, Schleiermacher HF, Niggemann M, Gerald AU, Michael K (2010) Improved efficiency of hybrid solar cells based on non-ligand-exchanged CdSe quantum dots and poly(3-hexylthiophene). Appl Phys Lett 96:013304 Zhou YF, Riehle FS, Yuan Y, Schleiermacher HF, Niggemann M, Gerald AU, Michael K (2010) Improved efficiency of hybrid solar cells based on non-ligand-exchanged CdSe quantum dots and poly(3-hexylthiophene). Appl Phys Lett 96:013304
11.
go back to reference Wang DF, Baral JK, Zhao HG, Gonfa BA, Truong VV, Khakani MAE, Izquierdo R, Ma DL (2011) Controlled fabrication of PbS quantum-dot/carbon-nanotube nanoarchitecture and its significant contribution to near-infrared photon-to-current conversion. Adv Funct Mater 21:4010–4018CrossRef Wang DF, Baral JK, Zhao HG, Gonfa BA, Truong VV, Khakani MAE, Izquierdo R, Ma DL (2011) Controlled fabrication of PbS quantum-dot/carbon-nanotube nanoarchitecture and its significant contribution to near-infrared photon-to-current conversion. Adv Funct Mater 21:4010–4018CrossRef
12.
go back to reference Lee JM, Kwon BH, Park HI, Kim H, Kim MG, Park JS, Kim ES, Yoo SH, Jeon DY, Kim SO (2013) Exciton dissociation and charge-transport enhancement in organic solar cells with quantum-dot/N-doped CNT hybrid nanomaterials. Adv Mater 25:2011–2017CrossRef Lee JM, Kwon BH, Park HI, Kim H, Kim MG, Park JS, Kim ES, Yoo SH, Jeon DY, Kim SO (2013) Exciton dissociation and charge-transport enhancement in organic solar cells with quantum-dot/N-doped CNT hybrid nanomaterials. Adv Mater 25:2011–2017CrossRef
13.
go back to reference Ma PC, Siddiqui AN, Maromb G, Kim JK (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A 41:1345–1367CrossRef Ma PC, Siddiqui AN, Maromb G, Kim JK (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A 41:1345–1367CrossRef
14.
go back to reference Pornsunthorntawee O, Chuaybumrung S, Kitiyanan B, Chavadej S (2011) Purification of single-walled carbon nanotubes (SWNTs) by acid leaching, NaOH dissolution, and froth flotation. Sep Sci Technol 46:2056–2065CrossRef Pornsunthorntawee O, Chuaybumrung S, Kitiyanan B, Chavadej S (2011) Purification of single-walled carbon nanotubes (SWNTs) by acid leaching, NaOH dissolution, and froth flotation. Sep Sci Technol 46:2056–2065CrossRef
15.
go back to reference Kuznetsova A, Popova I, Yates JT, Bronikowski MJ, Huffman CB, Liu J, Smalley RE, Hwu HH, Chen JGG (2001) Oxygen-containing functional groups on single-wall carbon nanotubes: NEXAFS and vibrational spectroscopic studies. J Am Chem Soc 123:10699–10704CrossRef Kuznetsova A, Popova I, Yates JT, Bronikowski MJ, Huffman CB, Liu J, Smalley RE, Hwu HH, Chen JGG (2001) Oxygen-containing functional groups on single-wall carbon nanotubes: NEXAFS and vibrational spectroscopic studies. J Am Chem Soc 123:10699–10704CrossRef
16.
go back to reference Cho N, Choudhury KP, Thapa RB, Sahoo Y, Ohulchanskyy T, Cartwright AN, Lee KS, Prasad PN (2007) Efficient photodetection at IR wavelengths by incorporation of PbSe-carbon-nanotube conjugates in a polymeric nanocomposite. Adv Mater 19:232–236CrossRef Cho N, Choudhury KP, Thapa RB, Sahoo Y, Ohulchanskyy T, Cartwright AN, Lee KS, Prasad PN (2007) Efficient photodetection at IR wavelengths by incorporation of PbSe-carbon-nanotube conjugates in a polymeric nanocomposite. Adv Mater 19:232–236CrossRef
17.
go back to reference Klem EJD, Gregory CW, Cunningham GB, Hall S, Temple DS, Lewis JS (2012) Planar PbS quantum dot/C-60 heterojunction photovoltaic devices with 5.2% power conversion efficiency. Appl Phys Lett 100:173109 Klem EJD, Gregory CW, Cunningham GB, Hall S, Temple DS, Lewis JS (2012) Planar PbS quantum dot/C-60 heterojunction photovoltaic devices with 5.2% power conversion efficiency. Appl Phys Lett 100:173109
18.
go back to reference Jeong S, Shim HC, Kim S, Han CS (2010) Efficient electron transfer in functional assemblies of pyridine-modified NQDs on SWNTs. ACS Nano 4:324–330CrossRef Jeong S, Shim HC, Kim S, Han CS (2010) Efficient electron transfer in functional assemblies of pyridine-modified NQDs on SWNTs. ACS Nano 4:324–330CrossRef
19.
go back to reference Johnston KW, Pattantyus-Abraham AG, Clifford JP, Myskog SH, MacNeil DD, Levina L, Sargent EH (2008) Schottky-quantum dot photovoltaics for efficient infrared power conversion. Appl Phys Lett 92:151115 Johnston KW, Pattantyus-Abraham AG, Clifford JP, Myskog SH, MacNeil DD, Levina L, Sargent EH (2008) Schottky-quantum dot photovoltaics for efficient infrared power conversion. Appl Phys Lett 92:151115
20.
go back to reference Law M, Luther JM, Song Q, Perkins CL, Nozik AJ (2008) Structural, optical, and electrical properties of PbSe nanocrystal solids treated thermally or with simple amines. J Am Chem Soc 130:5974–5985CrossRef Law M, Luther JM, Song Q, Perkins CL, Nozik AJ (2008) Structural, optical, and electrical properties of PbSe nanocrystal solids treated thermally or with simple amines. J Am Chem Soc 130:5974–5985CrossRef
21.
go back to reference Zheng SZ, Deng XY, Wong KY (2012) Enhancement of the power conversion efficiency of P3HT:PCBM based solar cells by an interfacial effect between P3HT and PEDOT. Synth Met 162:1490–1495CrossRef Zheng SZ, Deng XY, Wong KY (2012) Enhancement of the power conversion efficiency of P3HT:PCBM based solar cells by an interfacial effect between P3HT and PEDOT. Synth Met 162:1490–1495CrossRef
22.
go back to reference Mallajosyula AT, Sundar KIS, Baquer M (2010) Role of single walled carbon nanotubes in improving the efficiency of poly-(3-hexylthiophene) based organic solar cells. J Appl Phys 108:094902–094909CrossRef Mallajosyula AT, Sundar KIS, Baquer M (2010) Role of single walled carbon nanotubes in improving the efficiency of poly-(3-hexylthiophene) based organic solar cells. J Appl Phys 108:094902–094909CrossRef
23.
go back to reference Stylianakis MM, Kymakis E (2012) Efficiency enhancement of organic photovoltaics by addition of carbon nanotubes into both active and hole transport layer. Appl Phys Lett 100:093301–093305CrossRef Stylianakis MM, Kymakis E (2012) Efficiency enhancement of organic photovoltaics by addition of carbon nanotubes into both active and hole transport layer. Appl Phys Lett 100:093301–093305CrossRef
24.
go back to reference Fogden S, Howard CA, Heenan RK, Skipper NT, Shaffer MSP (2012) Scalable method for the reductive dissolution, purification, and separation of single-walled carbon nanotubes. ACS Nano 6:54–62CrossRef Fogden S, Howard CA, Heenan RK, Skipper NT, Shaffer MSP (2012) Scalable method for the reductive dissolution, purification, and separation of single-walled carbon nanotubes. ACS Nano 6:54–62CrossRef
25.
go back to reference Kim HJ, Karim MR, Lee CJ, Doh WH (2012) Synthesis and characterization of a poly[(3-hexylthiophene-co-3-octylthiophene)]-SWNT composite for solar cell applications. J Nanoelectron Optoelectron 7:466–470CrossRef Kim HJ, Karim MR, Lee CJ, Doh WH (2012) Synthesis and characterization of a poly[(3-hexylthiophene-co-3-octylthiophene)]-SWNT composite for solar cell applications. J Nanoelectron Optoelectron 7:466–470CrossRef
26.
go back to reference Filho SAG, Jorio A, Dresselhaus G, Dresselhaus MS, Saito R, Swan AK, Unlu MS, Goldberg BB, Hafner JH, Lieber CM, Pimenta MA (2002) Effect of quantized electronic states on the dispersive Raman features in individual single-wall carbon nanotubes. Phys Rev B 65:0354046 Filho SAG, Jorio A, Dresselhaus G, Dresselhaus MS, Saito R, Swan AK, Unlu MS, Goldberg BB, Hafner JH, Lieber CM, Pimenta MA (2002) Effect of quantized electronic states on the dispersive Raman features in individual single-wall carbon nanotubes. Phys Rev B 65:0354046
27.
go back to reference Gazi HAR, Guchhait B, Daschakraborty S, Biswas R (2011) Fluorescence dynamics in supercooled (acetamide plus calcium nitrate) molten mixtures. Chem Phys Lett 501:358–363CrossRef Gazi HAR, Guchhait B, Daschakraborty S, Biswas R (2011) Fluorescence dynamics in supercooled (acetamide plus calcium nitrate) molten mixtures. Chem Phys Lett 501:358–363CrossRef
28.
go back to reference Guchhait B, Gazi HAR, Kashyap HK, Biswas R (2010) Fluorescence spectroscopic studies of (acetamide plus sodium/potassium thiocyanates) molten mixtures: composition and temperature dependence. J Phys Chem B 114:5066–5081CrossRef Guchhait B, Gazi HAR, Kashyap HK, Biswas R (2010) Fluorescence spectroscopic studies of (acetamide plus sodium/potassium thiocyanates) molten mixtures: composition and temperature dependence. J Phys Chem B 114:5066–5081CrossRef
29.
go back to reference Olek M, Bulsgen T, Hilgendorff M, Giersig M (2006) Quantum dot modified multiwall carbon nanotubes. J Phys Chem B 110:12901–12904CrossRef Olek M, Bulsgen T, Hilgendorff M, Giersig M (2006) Quantum dot modified multiwall carbon nanotubes. J Phys Chem B 110:12901–12904CrossRef
30.
go back to reference Dabbousi BO, Rodriguez-Viejo J, Mikulec FV, Heine JR, Mattoussi H, Ober R, Jensen KF, Bawendi MG (1997) (CdSe)ZnS core–shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites. J Phys Chem B 101:9463–9475CrossRef Dabbousi BO, Rodriguez-Viejo J, Mikulec FV, Heine JR, Mattoussi H, Ober R, Jensen KF, Bawendi MG (1997) (CdSe)ZnS core–shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites. J Phys Chem B 101:9463–9475CrossRef
31.
go back to reference Efros AL, Rosen M (2000) The electronic structure of semiconductor nanocrystals. Annu Rev Mater Sci 30:475–521CrossRef Efros AL, Rosen M (2000) The electronic structure of semiconductor nanocrystals. Annu Rev Mater Sci 30:475–521CrossRef
Metadata
Title
Enhancement of the power conversion efficiency of polymer solar cells by functionalized single-walled carbon nanotubes decorated with CdSe/ZnS core–shell colloidal quantum dots
Authors
Ting Ni
Jingying Yan
Yurong Jiang
Fan Zou
Li Zhang
Dan Yang
Jinquan Wei
Shengyi Yang
Bingsuo Zou
Publication date
01-03-2014
Publisher
Springer US
Published in
Journal of Materials Science / Issue 6/2014
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-013-7953-x

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