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Journal of Materials Science
Published in: Journal of Materials Science 41/2023

31-10-2023 | Chemical routes to materials

Ethanol reforming with CO2 over MOF-derived CoMOx (M:Ce,Zr,Zn): impact of support on activity/stability

Authors: Yuhao Tian, Ting Li, Weijie Cai

Published in: Journal of Materials Science | Issue 41/2023

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Abstract

Recently, bio-ethanol reforming with CO2 (EDR) has been considered as one of the environment-friendly processes to diminish the emission of greenhouse gas, along with increasing the production of value-added syngas. However, designing high-performance catalysts is still a great challenge. In this work, MOF-derived CoMOx (M:Ce,Zr,Zn) catalysts were applied in EDR reaction for the first time to explore the influence of support types on catalytic performance. Characterization of the investigated catalysts by XPS, XRD, H2-TPR, Raman, TEM and BET depicted the difference in cobalt dispersion, specific surface area as well as Co-support interaction. Indeed, H2-TPR and XPS results revealed stronger Co-Ce interaction and the smaller particle size of Co3O4 in Co-CeO2 catalyst which contributed to higher activity. Indeed, 100% of ethanol conversion was obtained at 550 °C and the formed H2/CO ratio (1.18) was suitable for the downstream Fischer–Tropsch process. Meanwhile, no remarkable decline of ethanol conversion and product distributions occurred after 40 h stability tests. The findings implied that EDR process might be suitable to consume greenhouse gas and reduce carbon footprint. Characterization results of the used catalysts indicated that Co-CeO2 catalyst presented an outstanding anti-aggregation and anti-coking property. Herein, the effect of support type in this work might provide guidance for the design of high-performance catalysts for other heterogeneous reactions operated at high temperature.

Graphical abstract

previous article Facile fabrication of amorphous NiFeP nanosheets to promote urea oxidation reaction for energy-saving hydrogen production
next article Conversion of polycarbosilane to silicon carbide: effect of an active filler and pyrolysis conditions

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Metadata
Title
Ethanol reforming with CO2 over MOF-derived CoMOx (M:Ce,Zr,Zn): impact of support on activity/stability
Authors
Yuhao Tian
Ting Li
Weijie Cai
Publication date
31-10-2023
Publisher
Springer US
Published in
Journal of Materials Science / Issue 41/2023
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-023-09050-w

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