Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 3/2012

01-12-2012 | Original Paper

Evaluation of in vitro bioactivity and MG63 Oesteoblast cell response for TiO2 coated magnesium alloys

Authors: P. Amaravathy, C. Rose, S. Sathiyanarayanan, N. Rajendran

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2012

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The present investigation reports TiO2 coating on magnesium alloy AZ31 by sol–gel method via dip coating technique. TiO2 coated surface was characterized by thin film X-ray diffraction (TF-XRD), Fourier transform infrared red (FT-IR) spectroscopy, scanning electron microscopy (SEM) with energy-dispersive X-ray (EDX) spectroscopy, atomic force microscopy (AFM) and transmission electron microscopy (TEM) techniques. From TF-XRD results, the peaks at 2θ values of 25.14, 32.12, 68.73 and 70.11 confirm the presence of TiO2. The TiO2 is crystalline in nature and the crystallite size is about 32.4 nm. SEM-EDX, TEM and AFM show that the coated surface is uniform and nanoporous. FT-IR analysis shows that the peak in the range of 692 cm−1 is assigned to Ti–O–Ti stretching vibration. Contact angle measurements show that the coating is hydrophilic in nature. Bioactivity of the coating in simulated body fluid (SBF) was also examined, the hydroxyl functionalized surface greatly enhances the hydroxyapatite growth. The potentiodynamic polarization studies prove that the corrosion resistance of the TiO2 coated surface after immersion in SBF for 7 days is improved dramatically. Cell adhesion studies confirm the increased cell attachment on TiO2 coated surface when compared to uncoated alloy, due to less amount of Mg ion release from the substrate in the culture medium.
previous article Morphology and dispersion control of titania–silica monolith with macro–meso pore system
next article Synthesis of bioceramic scaffolds for bone tissue engineering by rapid prototyping technique

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Zhanga S, Li Q, Chen B, Yang X (2010) Preparation and corrosion resistance studies of nanometric sol–gel-based CeO2 film with a chromium-free pretreatment on AZ91D magnesium alloy. Electrochim Acta 55:870–877CrossRef
2.
Gray JE, Luan B (2002) Protective coatings on magnesium and its alloys—a critical review. J Alloy Compd 336:88–113CrossRef
3.
Wang J, Wang L, Guan S, Zhu S, Ren C, Hou S (2010) Microstructure and corrosion properties of as sub-rapid solidification Mg-Zn-Y-Nd alloy in dynamic simulated body fluid for vascular stent application. J Mater Sci Mater Med 21:2001–2008CrossRef
4.
Zhang Y, Zhang G, Wei M (2009) Controlling the biodegradation rate of magnesium using biomimetic apatite coating. J Biomed Mater Res B Appl Biomater 89:408–414
5.
GU XN, Zheng YF (2010) A review on magnesium alloys as biodegradable materials. Front Mater Sci China 4:111–115CrossRef
6.
Xu L, Zhang E, Yin D, Zeng S, Yang K (2008) In vitro corrosion behaviour of Mg alloys in a phosphate buffered solution for bone implant application. J Mater Sci Mater Med 19:1017–1025CrossRef
7.
Pardo A, Casajús P, Mohedano M, Coy AE, Viejo F, Torres B, Matykina E (2009) Corrosion protection of Mg/Al alloys by thermal sprayed aluminium coatings. Appl Surf Sci 255:6968–6977CrossRef
8.
Zhou H, Chen F, Yang YG, Wan HC, Cai S (2008) Study on process of Ion implantation on AZ31 magnesium alloy. Key Eng Mater 373–374:342–345CrossRef
9.
Chang JK, Chen SY, Tsai WT, Deng MJ, Sun IW (2007) Electrodeposition of aluminum on magnesium alloy in aluminum chloride (AlCl3)-1-ethyl-3-methylimidazolium chloride (EMIC) ionic liquid and its corrosion behavior. Electrochem Commun 9:1602–1606CrossRef
10.
Guan SK, Peng L, Wen CL, Luo Q (2008) Electrochemical fabrication and biocompatibility of the hydroxyapatite coating on magnesium alloy for implanted applications. In: Magnesium technology 2008. pp 367–371
11.
Izumi S, Yamasaki M, Otsu M, Kawamura Y (2007) Use of laser irradiation to form anti-corrosive surface oxide layer on Mg. Metal Mater Trans 48:1965–1968
12.
Hoche H, Schmidt J, Grob S, Trobmann T, Berger C (2011) PVD coating and substrate pretreatment concepts for corrosion and wear protection of magnesium alloys. Surf Coat Technol 205:S145–S150CrossRef
13.
Christoglou C, Voudouris N, Angelopoulos GN, Pant M, Dahl W (2004) Deposition of aluminium on magnesium by a CVD process. Surf Coat Technol 184:149–155CrossRef
14.
Leite Edson Roberto (2009) Nanostructured materials for electrochemical energy production and storage. Springer Science, New York, USACrossRef
15.
Li Q, Zhong X, Hu J (2008) Preparation and corrosion resistance studies of zirconia coating on fluorinated AZ91D magnesium alloy. Prog Org Coat 63:222–227CrossRef
16.
Xin Y, Hua K, Hu T, Tans G, Chu PK (2009) Mechanical properties of Al2O3/Al bi-layer coated AZ91 magnesium alloy. Thin Solid Films 517:5357–5360CrossRef
17.
Phani AR, Gammel FJ, Hack T, Haefke H (2005) Enhanced corrosion resistance by sol–gel-based ZrO2-CeO2 coatings on magnesium alloys. Mater Corros 56:77–82CrossRef
18.
Rodrigo P, Campo M, Torres B, Escalera MD, Otero E, Rams J (2009) Microstructure and wear resistance of Al-SiC composites coatings on ZE41 magnesium alloy. Appl Surf Sci 255:9174–9181CrossRef
19.
Hu J, Zhang C, Cui B, Bai K, Guan S, Wang L, Zhu S (2011) In vitro degradation of AZ31 magnesium alloy coated with nano TiO2 film by sol–gel method. Appl Surf Sci 257:8772–8777CrossRef
20.
Sun T, Wang M (2008) Low-temperature biomimetic formation of apatite/TiO2 composite coatings on Ti and NiTi shape memory alloy and their characterization. Appl Surf Sci 255:396–400CrossRef
21.
Milella E, Cosentino F, Liciulli A, Massaro C (2001) Preparation and characterization of titania/hydroxyapatite composite coatings obtained by sol gel process. Biomaterials 22:1425–1431CrossRef
22.
Huo H, Li Y, Wang F (2004) Corrosion of AZ91D magnesium alloy with a chemical conversion coating and electroless nickel layer. Corros Sci 46:1467–1477CrossRef
23.
Kokubo T, Kushitani H, Sakka S, Kitsugi T, Yamamuro T (1990) Solutions able to reproduce in vivo surface-structure changes in bioactive glass-ceramic A-W. J Biomed Mater Res 24:721–734CrossRef
24.
Devi KB, Singh K, Rajendran N (2011) Synthesis and characterization of nanoporous sodium-substituted hydrophilic titania ceramics coated on 316L SS for biomedical applications. J Coat Technol Res 8:595–604CrossRef
25.
Geetha V, Buvaneswari G (2009) Preparation of nanohydroxyapatite by a sol–gel method using alginic acid as a complexing agent. J Am Ceram Soc 92:2207–2211CrossRef
26.
Lindgren T, Muobora JH, Avendeno E, Johnson J, Hoel A, Granquist CG, Lindquist SE (2003) Photoelectrochemical and optical properties of nitrogen doped titanium dioxide films prepared by reactive DC magnetron sputtering. J Phys Chem B 107:5709–5716CrossRef
27.
Sultana R, Yang J, Hu X (2012) Deposition of micro-porous hydroxyapatite/tri-calcium phosphate coating on zirconia-based substrate. J Am Ceram Soc 95:1212–1215CrossRef
28.
Rajeswari R, Ng CCH, Liao S, Pliszka D, Raghunath M, Ramakrishna S, Chan Casey K (2012) Biomimetic surface modification of titanium surfaces for early cell capture by advanced electrospinning. Biomed Mater 7:015001CrossRef
29.
Nagarajan S, Raman V, Rajendran N (2010) Synthesis and electrochemical characterization of porous niobium oxide coated 316L SS for orthopedic applications. Mater Chem Phys 119:363–366CrossRef
30.
Liang F, Zhou L, Wang K (2003) Enhancement of the bioactivity of alkali-heat treated titanium by pre-calcification. J Mater Sci Lett 22:1665–1667CrossRef
31.
Gomes S, Renaudin G, Jallot E, Nedelec J-M (2009) Structural characterization and biological fluid interaction of sol#gel-derived Mg-substituted biphasic calcium phosphate ceramics. Appl Mater Interfaces 2:505–513CrossRef
32.
Bose S, Roy M, Das K, Bandyopadhyay A (2009) Surface modification of titanium for load-bearing applications. J Mater Sci Mater Med 20:S19–S24CrossRef
33.
Kawakami H, Ilala R, Straka L, Papula S, Romu J, Hanninen H, Mahlberg R, Heikkila M (2008) Photocatalytic activity of atomic layer deposited TiO2 coatings on austenitic stainless steels and copper alloys. J Electrochem Soc 155:C62–C68CrossRef
34.
Sebbowa T, Edirisinghe M, Salih V, Huang J (2011) Effect of deposition parameters and post-deposition annealing on the morphology and cellular response of electrosprayed TiO2 films. Biofabrication 3:045001CrossRef
35.
Silver IA, Deas J, Erecin′ska M (2001) Interactions of bioactive glasses with osteoblasts in vitro: effects of 45S5 bioglass, and 58S and 77S bioactive glasses on metabolism, intracellular ion concentrations and cell viability. Biomaterials 22:175–185CrossRef
36.
Kim HW, Koh YH, Li LH, Lee S, Kim HE (2004) Hydroxyapatite coating on titanium substrate with titania buffer layer processed by sol-gel method. Biomaterials 25:2533–2538CrossRef
37.
Karpagavalli R, Zhou A, Chellamuthu P, Nguyen K (2007) Corrosion behavior and biocompatibility of nanostructured TiO2 film on Ti6Al4 V. J Biomed Mater Res A 83:1087–1095
38.
Ou J, Wang J, Zhang D, Zhang P, Liu S, Yan P, Liu B, Yang S (2010) Fabrication and biocompatibility investigation of TiO2 films on the polymer substrates obtained via a novel and versatile route. Colloids Surf B Biointerfaces 76:123–127CrossRef
Metadata
Title
Evaluation of in vitro bioactivity and MG63 Oesteoblast cell response for TiO2 coated magnesium alloys
Authors
P. Amaravathy
C. Rose
S. Sathiyanarayanan
N. Rajendran
Publication date
01-12-2012
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2012
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-012-2904-6

Other articles of this Issue 3/2012

Journal of Sol-Gel Science and Technology 3/2012 Go to the issue

Original Paper

Water sorption in hybrid silica gels containing colloidal nontronite

Original Paper

Chemical synthesis of nanoscale Aurivillius ceramics, Bi2A2TiM2O12 (A = Ca, Sr, Ba and M = Nb, Ta)

Original Paper

Characterization of individual layers of an optical design based multilayered antireflection coating developed by sol–gel method

Original Paper

Synthesis of bioceramic scaffolds for bone tissue engineering by rapid prototyping technique

Original Paper

Investigation of photocatalytic activity of metal-doped TiO2 nanoparticles prepared by Pechini method

Original Paper

Application of lateral sol–gel type crosslinking to a polyurethane copolymer

Premium Partners

    Image Credits