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Metallurgical and Materials Transactions B

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19-06-2020

Experimental Phase Equilibria Studies in the FeO-Fe₂O₃-CaO-SiO₂ System in Air: Results for the Iron-Rich Region

Authors: Siyu Cheng, Maksym Shevchenko, Peter C. Hayes, Evgueni Jak

Published in: Metallurgical and Materials Transactions B | Issue 4/2020

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Abstract

New experimental data are reported on the liquidus and sub-liquidus phase equilibria in the FeO-Fe₂O₃-CaO-SiO₂ system in air. The study was undertaken using equilibration/quenching and microanalysis techniques enabling the compositions of the liquid and solid phases in equilibrium at temperature to be accurately measured. The limits of stability and associations of the primary phase fields of hematite (Fe₂O₃), dicalcium silicate (Ca₂SiO₄), silico-ferrite of calcium solid solution (SFC), dicalcium ferrite (Ca₂Fe₂O₅), calcium ferrite (CaFe₂O₄), calcium diferrite (CaFe₄O₇) have been characterized in the high iron, high CaO/SiO₂, low melting temperature region of the system. The full extent of the primary phase field of SFC has been determined, as have the conjugate lines joining the SFC and the corresponding liquid phase over the range of SFC compositions at sub-liquidus temperatures.

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T. Hidayat, D. Shishin, S.A. Decterov, P.C. Hayes, and E. Jak: Am. Inst. Phys., Conf., 2017, pp. 040004/1–9.

I.Z. Yildirim and M. Prezzi: Adv. Civ. Eng., 2011, vol. 2011, pp. 463638/1–13.

J. Lee, J. Choi, T. Yuan, Y. Yoon and D. Mitchell, Materials, 2019, vol. 12, p.1371.

P. Teo, A. Seman, P. Basu and N. Sharif, Procedia Chem., 2016, vol. 19, pp. 842-846.

D. Mombelli, C. Mapelli, A. Gruttadauria, C. Baldizzone, F. Magni, P. Levrangi and P. Simone, Steel Res. Int., 2012, vol. 83, pp. 1012-1019.

European Standard EN 15167-1, 2006: Ground granulated blast furnace slag for use in concrete, mortar and grout—Part 1: Definitions, Specifications and Conformity Criteria, European Committee for Standardisation, ICS 91.100.15; 01.040.91.

M. Jain, International Journal of Recent Contributions from Engineering, Science & IT (iJES), 2014, vol. 2, pp. 54-60.

M. Tokyay, Cem. Concr. Res., 1999, vol. 29, pp. 531-535.

X. Wu, H. Zhu, X. Hou and H. Li, Cem. Concr. Res., 1999, vol. 29, pp. 1103-1106.

10.

T. A. Mirza, Int. J. Basic Appl. Sci., 2012, vol. 12, pp. 109-118.

11.

M. Benmohamed, R. Alouani, A. Jmayai, A. B. H. Amara and H. B. Rhaiem, Int. J. Anal. Chem., 2016, vol. 2016, p. 10.

12.

B. Nandy, S. Chandra, D. Bhattacharjee and D. Ghosh, Ironmaking Steelmaking, 2006, vol. 33, pp. 111-119.

13.

T. Takayama, R. Murao and M. Kimura, ISIJ Int., 2018, vol. 58, pp. 1069-1078.

14.

S. Nicol, J. Chen, W. Qi, M. Mao, E. Jak and P. C. Hayes, Minerals, 2019, vol. 9, p. 374.

15.

A. Babich, D. Senk, and H.W. Gudenau: Handbook of Ironmaking, Wissenschaftsverlag Mainz, Aachen, 2008, pp. 72–75.

16.

S. H. Lee, R. Khanna, B. Lindblom, M. Hallin and V. Sahajwalla, Steel Res. Int., 2009, vol. 80, pp. 702-708.

17.

E. Ryösä, J. Wikström, B. Lindblom, E. Rutqvist, A. Benedictus, and A. Butcher, in: Ninth International Congress for Applied Mineralogy: ICAM 2008, pp. 545–55.

18.

P. Dawson, Ironmaking Steelmaking, 1993, vol. 20, pp. 137-143.

19.

J. Chen, E. Jak and P.C. Hayes, Miner. Process. Extr. Metall., 2019, https://doi.org/10.1080/25726641.2019.1684712.CrossRef

20.

M.I. Pownceby, J.M.F. Clout, and M.J. Fisher-White: Trans. Inst. Min. Metall., Sect. C, 1998, vol. 107, pp. C1–C9.

21.

M. I. Pownceby and T. R. C. Patrick, Eur. J. MIneral., 2000, vol. 12, pp. 455-468.

22.

M.I. Pownceby and J.M.F. Clout: Trans. Inst. Min. Metall., Sect. C, 2000, vol. 109, pp. C36–C48.

23.

M.I. Pownceby and J.M.F. Clout: in: Proceedings of the Iron Ore 2002, Perth, Australia, 9–11 September 2002, pp. 209–15.

24.

T. R. C. Patrick and M. I. Pownceby, Metall. Mater. Trans. B, 2002, vol. 33B, pp. 79-89.

25.

J. Chen, M. Shevchenko, P.C. Hayes and E. Jak, ISIJ Int., 2019, vol. 59, pp. 795-804.

26.

J. Chen, M. Shevchenko, P. Hayes and E. Jak, ISIJ Int., 2019, vol. 59, pp. 805-809.

27.

S. Nicol, E. Jak and P. C. Hayes, Metall. Mater. Trans. B, 2019, vol. 50, pp. 3027-3038.

28.

S. Nicol, E. Jak and P. C. Hayes, Metall. Mater. Trans. B, 2019, vol. 50, pp. 2706-2722.

29.

S. Nicol, J. Chen, M. I. Pownceby and N. A. S. Webster, ISIJ Int., 2018, vol. 58, pp. 2157-2172.

30.

M. Allibert, H. Gaye, J. Geiseler, D. Janke, B.J. Keene, D. Kirner, M. Kowalski, J. Lehmann, K.C. Mills, D. Neuschutz, R. Parra, C. Saint-Jours, P.J. Spencer, M. Susa, M. Tmar, and E. Woermann: Slag Atlas, 2nd ed., Verlag Stahleisen GmbH, d-Dusseldorf, 1995, p. 127.

31.

B. Phillips and A. Muan, J. Am. Ceram. Soc., 1959, vol. 42, pp. 413-423.

32.

K. Inoue and T. Ikeda, Trans. Iron Steel Inst. Jpn., 1982, vol. 68, pp. 2190-2199.

33.

J.D.G. Hamilton, B.F. Hoskins, W.G. Mumme, W.E. Borbidge, and M.A. Montague: Neues Jahrb. Mineral., Abh. (Neues Jahrbuch fuer Mineralogie, Abhandlungen), 1989, vol. 161, pp. 1–26.

34.

P. Dawson, J. Ostwald and K. Hayes, Trans. Instn. Min. Metall. Sect. C, 1985, vol. 94, pp. C71-C78.

35.

C. W. Bale, P. Chartrand, S. A. Decterov, G. Eriksson, K. Hack, R. B. Mahfoud, J. Melancon, A. D. Pelton and S. Petersen, CALPHAD, 2002, vol. 26, pp. 189-228.

36.

S. A. Decterov, Y. B. Kang and I. H. Jung, J. Phase Equilib. Diffus., 2009, vol. 30, pp. 443-461.

37.

T. Hidayat, D. Shishin, S. A. Decterov and E. Jak, CALPHAD, 2016, vol. 56, pp. 58-71.

38.

R. Murao, T. Harano, M. Kimura and I. H. Jung, ISIJ Int., 2018, vol. 58, pp. 259-266.

39.

C. Chen, L. Lu and K. Jiao, Minerals, 2019, vol. 9, p. 361.

40.

L. Zhang, S. Jahanshahi, S. Sun, C. Chen, B. Bourke, S. Wright and M. Somerville, Jom, 2002, vol. 54, pp. 51-56.

41.

L. Lu, R. J. Holmes and J. R. Manuel, ISIJ Int., 2007, vol. 47, pp. 349-358.

42.

M. M. Hessien, Y. Kashiwaya, K. Ishii, M. I. Nasr and A. A. El-Geassy, Ironmaking Steelmaking, 2008, vol. 35, pp. 191-204.

43.

E. Jak, P.C. Hayes, and H.G. Lee: Met. Mater. (Seoul, Repub. Korea), 1995, vol. 1, pp. 1–8.

44.

E. Jak: in 9th Intl. Conf. on Molten Slags, Fluxes and Salts (MOLTEN12), The Chinese Society for Metals, Beijing, China, 2012, p. W077.

45.

P.C. Hayes: in Treatise on Process Metallurgy, S. Seetharaman, ed., Elsevier, Oxford, 2014, pp. 875–89.

46.

G. W. Groves, J. Mater. Sci., 1983, vol. 18, pp. 1615-1624.

47.

A. Fallah-Mehrjardi, T. Hidayat, P. C. Hayes and E. Jak, Metall. Mater. Trans. B, 2017, vol. 48, pp. 3002-3016.

48.

M. Shevchenko, J. Chen, and E. Jak: in: AMAS 2017, 14th Biennial Australian Microbeam Analysis Symposium, QUT, Brisbane, 2017, pp. 94-95.

49.

M. Shevchenko and E. Jak, J. Phase Equilib. Diff., 2019, vol. 40, pp. 319-355.

50.

M. Shevchenko and E. Jak, Metall. Mater. Trans. B., 2019, vol. 50, pp. 2780-2793.

51.

T. Kawasaki and H. Ishizuka, J. Mineral. Petrol. Sci., 2008, vol. 103, pp. 255-265.

52.

X. Llovet, P.T. Pinard, J.J. Donovan, and F. Salvat: J. Phys. D Appl. Phys., 2012, vol. 45, pp. 225301/1–12.

53.

M. Shevchenko and E. Jak, Ceram. Int., 2019, vol. 45, pp. 6795-6803.

54.

T. Hidayat, D. Shishin, S. A. Decterov and E. Jak, Metall. Mater. Trans. B, 2016, vol. 47, pp. 256-281.

55.

E. Schurmann and G. Kraume, Arch. Eisenhüttenwes., 1976, vol. 47, pp. 267-69.

56.

G. Liu: Experimental Phase Equilibria Studies in Oxide Systems for Copper Smelting Slags. MPhil Thesis, University of Queensland, Australia, 2012, p. 85.

57.

B. Phillips and A. Muan, J. Am. Ceram. Soc., 1958, vol. 41, pp. 445-454.

58.

S.A. Decterov, I.H. Jung, E. Jak, Y.B. Kang, P.C. Hayes, and A.D. Pelton: in: SAIMM Symposium Series S36 (VII Int. Conf. on Molten Slags, Fluxes & Salts), C. Pistorius, ed., The South African Institute of Mining and Metallurgy, Johannesburg, Republic of South Africa, 2004, pp. 839–50.

59.

M. Hillert, M. Selleby and B. Sundman, Metall. Mater. Trans. A, 1990, vol. 21, pp. 2759-2776.

60.

S. Cheng, M. Shevchenko, and E. Jak, PYROSEARCH, Private Communication, The University of Queensland, Brisbane, QLD, 2020.

61.

Y. Kashiwaya, Metall. Mater. Trans. B, 2017, vol. 48, pp. 3228-3238.

62.

Y. Kashiwaya and S. Yanai, Metall. Mater. Trans. B, 2019, vol. 50, pp. 2095-2110.

63.

J. Chen, S. Cheng, M. Shevchenko, P.C. Hayes, and E. Jak, PYROSEARCH, Private Communication, The University of Queensland, Brisbane, QLD, 2020.

64.

W.G. Mumme, J.M.F. Clout, and R.W. Gable: Neues Jahrb. Mineral., Abh., 1998, vol. 173, pp. 93–117.

65.

H.I. Saleh: J. Mater. Sci. Technol. (Shenyang, China), 2004, vol. 20, pp. 530–34.

66.

C. A. Schneider, W. S. Rasband and K. W. Eliceiri, Nat. Methods, 2012, vol. 9, pp. 671-675.

Title: Experimental Phase Equilibria Studies in the FeO-Fe2O3-CaO-SiO2 System in Air: Results for the Iron-Rich Region
Authors: Siyu Cheng
Maksym Shevchenko
Peter C. Hayes
Evgueni Jak
Publication date: 19-06-2020
Publisher: Springer US
Published in: Metallurgical and Materials Transactions B / Issue 4/2020
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI: https://doi.org/10.1007/s11663-020-01886-w

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