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Published in: Metallurgical and Materials Transactions B 6/2009

01-12-2009

Experimental Techniques for Investigating Calcium Ferrite Slags at Metallic Copper Saturation and Application to the Systems “Cu2O”-“Fe2O3” and “Cu2O”-CaO at Metallic Copper Saturation

Authors: Stanko Nikolic, Peter C. Hayes, Evgueni Jak

Published in: Metallurgical and Materials Transactions B | Issue 6/2009

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Abstract

Phase equilibrium studies have been carried out on the systems “Cu2O”-FeO-Fe2O3 and “Cu2O”-CaO at metallic copper saturation. It has been shown that, using synthetic primary phase materials as substrates to support the liquid slag, equilibration at high temperature is possible without contamination of the samples. Rapid quenching of the liquid has been achieved so that it is retained as an amorphous phase on cooling, even in this silica-free system. Through the use of an improved methodology and electron probe X-ray microanalysis (EPMA), accurate, objective, and repeatable phase equilibrium data can be obtained. Experimental data for the pseudo-binary “Cu2O”-“Fe2O3” and “Cu2O”-CaO systems, at metallic copper saturation, are presented.

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Footnotes
1
ISACONVERT is a trademark of Xstrata Technology Pty Ltd., Brisbane, Australia.
 
2
JEOL is a trademark of Japan Electron Optics Ltd., Tokyo.
 
Literature
1.
go back to reference W.G.L. Davenport, M. King, M. Schlesinger, and A.K. Biswas: Extractive Metallurgy of Copper, 4th ed., Pergamon, Oxford, United Kingdom, 2002, pp. 155–71. W.G.L. Davenport, M. King, M. Schlesinger, and A.K. Biswas: Extractive Metallurgy of Copper, 4th ed., Pergamon, Oxford, United Kingdom, 2002, pp. 155–71.
2.
go back to reference J.S. Edwards and S. Jahanshahi: Australian Patents C22B 015/06 and C22B 009/05, 1995. J.S. Edwards and S. Jahanshahi: Australian Patents C22B 015/06 and C22B 009/05, 1995.
3.
go back to reference J.S. Edwards and G.R.F. Alvear: Copper 07, vol. III, Book 2: The Carlos Diaz Symp. on Pyrometallurgy, Toronto, 2007, A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, and A. Warczok, eds., TMS-CIM, Montreal, 2007, pp. 17–28. J.S. Edwards and G.R.F. Alvear: Copper 07, vol. III, Book 2: The Carlos Diaz Symp. on Pyrometallurgy, Toronto, 2007, A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, and A. Warczok, eds., TMS-CIM, Montreal, 2007, pp. 17–28.
4.
go back to reference A. Yazawa, Y. Takeda, and Y. Waseda: Can. Metall. Q., 1981, vol. 20, pp. 129–34. A. Yazawa, Y. Takeda, and Y. Waseda: Can. Metall. Q., 1981, vol. 20, pp. 129–34.
5.
go back to reference A. Yazawa and Y. Takeda: Trans. Jpn. Inst. Met., 1982, vol. 23, pp. 328–33. A. Yazawa and Y. Takeda: Trans. Jpn. Inst. Met., 1982, vol. 23, pp. 328–33.
6.
go back to reference Y. Takeda, S. Nakazawa, and A. Yazawa: Can. Metall. Q., 1980, vol. 19, pp. 297–305. Y. Takeda, S. Nakazawa, and A. Yazawa: Can. Metall. Q., 1980, vol. 19, pp. 297–305.
7.
8.
go back to reference R. Scheel: Arch. Eisenhuttenwes., 1974, vol. 45, pp. 751–56. R. Scheel: Arch. Eisenhuttenwes., 1974, vol. 45, pp. 751–56.
9.
go back to reference E. Schuermann and G. Kraume: Arch. Eisenhuettenwes., 1976, vol. 47, pp. 267–69. E. Schuermann and G. Kraume: Arch. Eisenhuettenwes., 1976, vol. 47, pp. 267–69.
10.
go back to reference W. Oelsen and H. Maetz: Mitt. Kaiser-Wilhelm Inst. Eisenforsch., 1941, vol. 23, pp. 195–245. W. Oelsen and H. Maetz: Mitt. Kaiser-Wilhelm Inst. Eisenforsch., 1941, vol. 23, pp. 195–245.
11.
12.
go back to reference H.L. Bishop, Jr., N.J. Grant, and J. Chipman: Trans. TMS-AIME, 1958, vol. 212, pp. 185–92. H.L. Bishop, Jr., N.J. Grant, and J. Chipman: Trans. TMS-AIME, 1958, vol. 212, pp. 185–92.
13.
go back to reference W.A. Fischer and H.J. Fleischer: Arch. Eisenhuettenwes., 1961, vol. 32, pp. 305–13. W.A. Fischer and H.J. Fleischer: Arch. Eisenhuettenwes., 1961, vol. 32, pp. 305–13.
14.
go back to reference E. Goerl, F. Oeters, and R. Scheel: Arch. Eisenhuettenwes., 1966, vol. 37, pp. 441–51. E. Goerl, F. Oeters, and R. Scheel: Arch. Eisenhuettenwes., 1966, vol. 37, pp. 441–51.
15.
go back to reference K.H. Obst and J. Stradtmann: Arch. Eisenhuettenwes., 1969, vol. 40, pp. 615–17. K.H. Obst and J. Stradtmann: Arch. Eisenhuettenwes., 1969, vol. 40, pp. 615–17.
16.
go back to reference F. Abbattista, A. Burdese, and M. Maja: Rev. Int. Hautes Temp. Refract., 1975, vol. 12 (4), pp. 337–42. F. Abbattista, A. Burdese, and M. Maja: Rev. Int. Hautes Temp. Refract., 1975, vol. 12 (4), pp. 337–42.
17.
go back to reference E. Schuermann and G. Kraume: Arch. Eisenhuettenwes., 1976, vol. 47, pp. 327–31. E. Schuermann and G. Kraume: Arch. Eisenhuettenwes., 1976, vol. 47, pp. 327–31.
18.
go back to reference M. Timucin and A.E. Morris: Metall. Trans., 1970, vol. 1, pp. 3193–201. M. Timucin and A.E. Morris: Metall. Trans., 1970, vol. 1, pp. 3193–201.
19.
go back to reference J. Hino, K. Itagaki, and A. Yazawa: Shigen to Sozai, 1989, vol. 105, pp. 315–20. J. Hino, K. Itagaki, and A. Yazawa: Shigen to Sozai, 1989, vol. 105, pp. 315–20.
20.
go back to reference Y. Takeda: Yazawa Int. Symp., vol. I, Materials Processing Fundamentals and New Technologies, San Diego, CA, 2003, F. Kongoli, K. Itagaki, C. Yamauchi, and H.Y. Sohn, eds., TMS, Warrendale, PA, 2003, pp. 211–25. Y. Takeda: Yazawa Int. Symp., vol. I, Materials Processing Fundamentals and New Technologies, San Diego, CA, 2003, F. Kongoli, K. Itagaki, C. Yamauchi, and H.Y. Sohn, eds., TMS, Warrendale, PA, 2003, pp. 211–25.
21.
go back to reference A. Ilyushechkin, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2004, vol. 35B, pp. 203–15.CrossRef A. Ilyushechkin, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2004, vol. 35B, pp. 203–15.CrossRef
22.
go back to reference E. Jak, P.C. Hayes, and H.G. Lee: Kor. IMM J., 1995, vol. 1, pp. 1–8. E. Jak, P.C. Hayes, and H.G. Lee: Kor. IMM J., 1995, vol. 1, pp. 1–8.
23.
go back to reference E. Jak and P.C. Hayes: VII Int. Conf. Molten Slags Fluxes and Salts, Capetown, 2004, SAIMM, Johannesburg, 2004, pp. 85–104. E. Jak and P.C. Hayes: VII Int. Conf. Molten Slags Fluxes and Salts, Capetown, 2004, SAIMM, Johannesburg, 2004, pp. 85–104.
24.
go back to reference S. Nikolic, P.C. Hayes, and E. Jak: Sohn Int. Symp., vol. I, Thermo and Physiochemical Principles, San Diego, CA, 2006, F. Kongoli and R.G. Reddy, eds., TMS, Warrendale, PA, 2006, vol. 1, pp. 791–804. S. Nikolic, P.C. Hayes, and E. Jak: Sohn Int. Symp., vol. I, Thermo and Physiochemical Principles, San Diego, CA, 2006, F. Kongoli and R.G. Reddy, eds., TMS, Warrendale, PA, 2006, vol. 1, pp. 791–804.
25.
go back to reference S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 179–88.CrossRefADS S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 179–88.CrossRefADS
26.
go back to reference S. Nikolic, H. Henao, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 189–99.CrossRefADS S. Nikolic, H. Henao, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 189–99.CrossRefADS
27.
go back to reference S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 200–09.CrossRefADS S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 200–09.CrossRefADS
28.
go back to reference S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 210–17.CrossRefADS S. Nikolic, P.C. Hayes, and E. Jak: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 210–17.CrossRefADS
Metadata
Title
Experimental Techniques for Investigating Calcium Ferrite Slags at Metallic Copper Saturation and Application to the Systems “Cu2O”-“Fe2O3” and “Cu2O”-CaO at Metallic Copper Saturation
Authors
Stanko Nikolic
Peter C. Hayes
Evgueni Jak
Publication date
01-12-2009
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 6/2009
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-009-9259-6

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