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2024 | OriginalPaper | Chapter

Extraction of Vanadium from High Calcium and High Phosphorus Vanadium Slag by Magnesiation Roasting-Acid Leaching

Authors : Xin-Mian Chen, Hong-Yi Li, Jing Tan, Jie Cheng, Jiang Diao, Bing Xie

Published in: Rare Metal Technology 2024

Publisher: Springer Nature Switzerland

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Abstract

Magnesiation roasting-acid leaching is carried out to extract vanadium from high calcium and high phosphorus vanadium slag (HCPVS). The effects of roasting and leaching conditions on vanadium and phosphorus extraction are studied. In optimal conditions, the extraction efficiency of vanadium reaches 79.7%, and only 35.6% of phosphorus is leached owing to Mg2+ inhibiting the leaching of phosphorus. The roasting mechanism is analyzed by XRD and BSE-EDS systematically, best of the vanadium in V-spinel is converted into vanadate, and a small part of vanadium is dissolved into Ca2SiO4–Ca3(PO4)2 and CaTiO3 phase. This work reveals the influence mechanism of Ca2SiO4–Ca3(PO4)2 and CaTiO3 phase on vanadium extraction, providing new insights for vanadium extraction from HCPVS.

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Metadata
Title
Extraction of Vanadium from High Calcium and High Phosphorus Vanadium Slag by Magnesiation Roasting-Acid Leaching
Authors
Xin-Mian Chen
Hong-Yi Li
Jing Tan
Jie Cheng
Jiang Diao
Bing Xie
Copyright Year
2024
DOI
https://doi.org/10.1007/978-3-031-50236-1_42

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