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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2012

01-02-2012 | Original Paper

Fabrication of a high thermal-stable methacrylate-silicate hybrid nanocomposite: hydrolytic versus non-hydrolytic sol–gel synthesis of methacryl-oligosiloxanes

Authors: Jungho Jin, SeungCheol Yang, Byeong-Soo Bae

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2012

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Abstract

A high thermal-stable methacrylate-silicate hybrid nanocomposite (hybrimer) was fabricated based on UV-induced polymerization of a highly-condensed methacryl-oligosiloxane resin (Hy-MO). The Hy-MO resin was newly synthesized via an acid-catalyzed hydrolytic sol–gel reaction of 3-(methacryloxy) propyl trimethoxysilane (MPTS) and diphenyldimethoxysilane. The basic properties of Hy-MO were compared with a conventional resin prepared by a Ba(OH)2·H2O-catalyzed non-hydrolytic sol–gel reaction of MPTS and diphenylsilanediol (N-MO). It was found that Hy-MO have a higher siloxane condensation degree, larger molecular size and weight than the N-MO due to the highly mobile proton ions that effectively catalyze the overall sol–gel reaction. The resultant Hy-MO hybrimer showed a higher thermal stability than N-MO hybrimer.
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Appendix
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Metadata
Title
Fabrication of a high thermal-stable methacrylate-silicate hybrid nanocomposite: hydrolytic versus non-hydrolytic sol–gel synthesis of methacryl-oligosiloxanes
Authors
Jungho Jin
SeungCheol Yang
Byeong-Soo Bae
Publication date
01-02-2012
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2012
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-011-2630-5

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