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Polymer Bulletin
Published in: Polymer Bulletin 2/2024

12-04-2023 | ORIGINAL PAPER

Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core–shell structure and its film properties

Authors: Jiawei Li, Chengyu Hong, Hao Zhang, Ye Han, Xin Li, Ruonan Sun, Chao Zhou

Published in: Polymer Bulletin | Issue 2/2024

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Abstract

Polyvinyl chloride (PVDC) coatings require excellent adhesion to substrates. Herein, a series of self-cross-linking silylated polyvinylidene chloride (PVMBV) emulsions with core–shell structure were prepared by seed emulsion polymerization using vinylidene chloride (VDC), methyl acrylate (MA), butyl acrylate (BA), and acrylic acid (AA) as the raw materials. Vinyltrimethoxysilane (VTMO) as the cross-linker was employed to enhance the adhesive properties. The effects of various VTMO contents on the properties of PVMBV were investigated. The results showed that the adhesion performance and thermal stability of PVMBV films were enhanced significantly with the increasing VTMO content. More interestingly, the introduction of a small quantity of VTMO enhanced the toughness of PVMBV films. The water contact angle increased could prove that the hydrophobicity of PVMBV films was improved. Further, it is important to that barrier properties of PVMBV films were effectively improved when VTMO content was no more than 3 wt%. This work provides potential applications in multifunctional barrier coatings, such as vapor barrier, water barrier, weathering, and corrosion protection.
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Metadata
Title
Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core–shell structure and its film properties
Authors
Jiawei Li
Chengyu Hong
Hao Zhang
Ye Han
Xin Li
Ruonan Sun
Chao Zhou
Publication date
12-04-2023
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 2/2024
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-023-04779-5

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