Skip to main content
Top
Published in: Journal of Materials Science 10/2018

01-02-2018 | Energy materials

Facile synthesis of Ni-doping Bi2WO6 nano-sheets with enhanced adsorptive and visible-light photocatalytic performances

Authors: Lei Xiang, Lei Chen, Ce-Hui Mo, Lian-Ming Zheng, Zhong-Xiong Yu, Yan-Wen Li, Quan-Ying Cai, Hui Li, Wei-Dong Yang, Dong-Mei Zhou, Ming-Hung Wong

Published in: Journal of Materials Science | Issue 10/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Bi2WO6 nano-sheets doped with various amounts of nickel (Ni) were prepared by hydrothermal method, and their microstructure and photocatalytic performance for degrading rhodamine B (RhB) and ciprofloxacin (CIP) under simulated solar light irradiation were investigated. The effective incorporation of Ni atoms in Bi2WO6 was confirmed by energy-dispersive spectroscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy. Ni-doping decreased the crystallite size of Bi2WO6 and improved its specific surface area and surface electrical property. Furthermore, Ni atoms acting as electron traps facilitated the separation of photo electron–hole pairs. Accordingly, both adsorptive and photocatalytic performances of the Ni–Bi2WO6 were improved compared to undoping Bi2WO6. The 0.15-Ni–Bi2WO6 (Ni/W, molar ratio) displayed the best adsorptive and photocatalytic activities among the Bi2WO6 samples doped with various elements. The photogenerated holes were the predominant reactive species responsible for the photodegradation of RhB by 0.15-Ni–Bi2WO6. Solution pH could influence the adsorptive and photocatalytic performances of 0.15-Ni–Bi2WO6 with the best performances under acidic condition.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
1.
go back to reference Fan XY, Yue X, Luo JM, Wang CY (2016) Facile synthesis of carbon-Bi2WO6 with enhanced visible-light photocatalytic activities. J Nanopart Res 18:1–9CrossRef Fan XY, Yue X, Luo JM, Wang CY (2016) Facile synthesis of carbon-Bi2WO6 with enhanced visible-light photocatalytic activities. J Nanopart Res 18:1–9CrossRef
2.
go back to reference Zhang P, Hua X, Teng XX, Liu DS, Qin ZH, Ding SM (2016) CTAB assisted hydrothermal synthesis of lamellar Bi2WO6 with superior photocatalytic activity for rhodamine b degradation. Mater Lett 185:275–277CrossRef Zhang P, Hua X, Teng XX, Liu DS, Qin ZH, Ding SM (2016) CTAB assisted hydrothermal synthesis of lamellar Bi2WO6 with superior photocatalytic activity for rhodamine b degradation. Mater Lett 185:275–277CrossRef
3.
go back to reference Lai LL, Wen W, Wu JM (2016) Ni-doped rutile TiO2 nanoflowers: low-temperature solution synthesis and enhanced photocatalytic efficiency. Rsc Adv 6:25511–25518CrossRef Lai LL, Wen W, Wu JM (2016) Ni-doped rutile TiO2 nanoflowers: low-temperature solution synthesis and enhanced photocatalytic efficiency. Rsc Adv 6:25511–25518CrossRef
4.
go back to reference Song XC, Zheng YF, Ma R, Zhang YY, Yin HY (2011) Photocatalytic activities of Mo-doped Bi2WO6 three-dimensional hierarchical microspheres. J Hazard Mater 192:186–191 Song XC, Zheng YF, Ma R, Zhang YY, Yin HY (2011) Photocatalytic activities of Mo-doped Bi2WO6 three-dimensional hierarchical microspheres. J Hazard Mater 192:186–191
5.
go back to reference Li H, Hao H, Jin S, Guo W, Hu X, Hou H, Zhang G, Yan S, Gao W, Liu G (2017) Synthesis and luminescence properties of Ho3+/Yb3+ co-doped bismuth tungstate nanopowder. Mater Res Bull 89:51–56CrossRef Li H, Hao H, Jin S, Guo W, Hu X, Hou H, Zhang G, Yan S, Gao W, Liu G (2017) Synthesis and luminescence properties of Ho3+/Yb3+ co-doped bismuth tungstate nanopowder. Mater Res Bull 89:51–56CrossRef
6.
go back to reference Huang HW, Cao RR, Yu SX, Xu K, Hao WC, Wang YG, Dong F, Zhang TR, Zhang YH (2017) Single-unit-cell layer established Bi2WO6 3D hierarchical architectures: efficient adsorption, photocatalysis and dye-sensitized photoelectrochemical performance. Appl Catal B Environ 219:526–537CrossRef Huang HW, Cao RR, Yu SX, Xu K, Hao WC, Wang YG, Dong F, Zhang TR, Zhang YH (2017) Single-unit-cell layer established Bi2WO6 3D hierarchical architectures: efficient adsorption, photocatalysis and dye-sensitized photoelectrochemical performance. Appl Catal B Environ 219:526–537CrossRef
7.
go back to reference Huang HW, He Y, Lin ZS, Kang L, Zhang YH (2013) Two novel Bi-based borate photocatalysts: crystal structure, electronic structure, photoelectrochemical properties, and photocatalytic activity under simulated solar light irradiation. J Phys Chem C 117:22986–22994CrossRef Huang HW, He Y, Lin ZS, Kang L, Zhang YH (2013) Two novel Bi-based borate photocatalysts: crystal structure, electronic structure, photoelectrochemical properties, and photocatalytic activity under simulated solar light irradiation. J Phys Chem C 117:22986–22994CrossRef
8.
go back to reference Huang HW, He Y, Li XW, Li M, Zeng C, Dong F, Du X, Zhang TR, Zhang HY (2015) Bi2O2(OH)(NO3) as a desirable [Bi2O2]2+ layered photocatalyst: strong intrinsic polarity, rational band structure and 001 active facets co-beneficial for robust photooxidation capability. J Mater Chem A 3:24547–24556CrossRef Huang HW, He Y, Li XW, Li M, Zeng C, Dong F, Du X, Zhang TR, Zhang HY (2015) Bi2O2(OH)(NO3) as a desirable [Bi2O2]2+ layered photocatalyst: strong intrinsic polarity, rational band structure and 001 active facets co-beneficial for robust photooxidation capability. J Mater Chem A 3:24547–24556CrossRef
9.
go back to reference Zhuo Y, Huang J, Cao L, Ouyang H, Wu J (2013) Photocatalytic activity of snow-like Bi2WO6 microcrystalline for decomposition of Rhodamine B under natural sunlight irradiation. Mater Lett 90:107–110CrossRef Zhuo Y, Huang J, Cao L, Ouyang H, Wu J (2013) Photocatalytic activity of snow-like Bi2WO6 microcrystalline for decomposition of Rhodamine B under natural sunlight irradiation. Mater Lett 90:107–110CrossRef
10.
go back to reference Chen P, Zhu L, Fang S, Wang C, Shan G (2012) Photocatalytic degradation efficiency and mechanism of microcystin-RR by mesoporous Bi2WO6 under near ultraviolet light. Environ Sci Technol 46:2345–2351CrossRef Chen P, Zhu L, Fang S, Wang C, Shan G (2012) Photocatalytic degradation efficiency and mechanism of microcystin-RR by mesoporous Bi2WO6 under near ultraviolet light. Environ Sci Technol 46:2345–2351CrossRef
11.
go back to reference Zhang GQ, Chang N, Han DQ, Zhou AQ, Xu XH (2010) The enhanced visible light photocatalytic activity of nanosheet-like Bi2WO6 obtained by acid treatment for the degradation of rhodamine B. Mater Lett 64:2135–2137CrossRef Zhang GQ, Chang N, Han DQ, Zhou AQ, Xu XH (2010) The enhanced visible light photocatalytic activity of nanosheet-like Bi2WO6 obtained by acid treatment for the degradation of rhodamine B. Mater Lett 64:2135–2137CrossRef
12.
go back to reference Tang P, Chen H, Cao F (2012) One-step preparation of bismuth tungstate nanodisks with visible-light photocatalytic activity. Mater Lett 68:171–173CrossRef Tang P, Chen H, Cao F (2012) One-step preparation of bismuth tungstate nanodisks with visible-light photocatalytic activity. Mater Lett 68:171–173CrossRef
13.
go back to reference Dumrongrojthanath P, Thongtem T, Phuruangrat A, Thongtem S (2013) Hydrothermal synthesis of Bi2WO6 hierarchical flowers with their photonic and photocatalytic properties. Superlattice Microstruct 54:71–77CrossRef Dumrongrojthanath P, Thongtem T, Phuruangrat A, Thongtem S (2013) Hydrothermal synthesis of Bi2WO6 hierarchical flowers with their photonic and photocatalytic properties. Superlattice Microstruct 54:71–77CrossRef
14.
go back to reference Fu Y, Chang C, Chen P, Chu X, Zhu L (2013) Enhanced photocatalytic performance of boron doped Bi2WO6 nanosheets under simulated solar light irradiation. J Hazard Mater 254:185–192CrossRef Fu Y, Chang C, Chen P, Chu X, Zhu L (2013) Enhanced photocatalytic performance of boron doped Bi2WO6 nanosheets under simulated solar light irradiation. J Hazard Mater 254:185–192CrossRef
15.
go back to reference Huang H, Liu K, Chen K, Zhang Y, Wang S (2014) Ce and F comodification on the crystal structure and enhanced photocatalytic activity of Bi2WO6 photocatalyst under visible light irradiation. J Phys Chem C 118:14379–14387CrossRef Huang H, Liu K, Chen K, Zhang Y, Wang S (2014) Ce and F comodification on the crystal structure and enhanced photocatalytic activity of Bi2WO6 photocatalyst under visible light irradiation. J Phys Chem C 118:14379–14387CrossRef
16.
go back to reference Ren J, Wang WZ, Sun SM, Zhang L, Chang J (2009) Enhanced photocatalytic activity of Bi2WO6 loaded with Ag nanoparticles under visible light irradiation. Appl Catal B 92:50–55CrossRef Ren J, Wang WZ, Sun SM, Zhang L, Chang J (2009) Enhanced photocatalytic activity of Bi2WO6 loaded with Ag nanoparticles under visible light irradiation. Appl Catal B 92:50–55CrossRef
17.
go back to reference Tian Y, Chang B, Lu J, Fu J, Xi F, Dong X (2013) Hydrothermal synthesis of graphitic carbon nitride-Bi2WO6 heterojunctions with enhanced visible light photocatalytic activities. Acs Appl Mater Inter 5:7079–7085CrossRef Tian Y, Chang B, Lu J, Fu J, Xi F, Dong X (2013) Hydrothermal synthesis of graphitic carbon nitride-Bi2WO6 heterojunctions with enhanced visible light photocatalytic activities. Acs Appl Mater Inter 5:7079–7085CrossRef
18.
go back to reference Ge M, Li Y, Liu L, Zhou Z, Chen W (2011) Bi2O3–Bi2WO6 composite microspheres: hydrothermal synthesis and photocatalytic performances. J Phys Chem C 115:5220–5225CrossRef Ge M, Li Y, Liu L, Zhou Z, Chen W (2011) Bi2O3–Bi2WO6 composite microspheres: hydrothermal synthesis and photocatalytic performances. J Phys Chem C 115:5220–5225CrossRef
19.
go back to reference Liu YJ, Cai R, Fang T, Wu JG, Wei A (2015) Low temperature synthesis of Bi2WO6 and its photocatalytic activities. Mater Res Bull 66:96–100CrossRef Liu YJ, Cai R, Fang T, Wu JG, Wei A (2015) Low temperature synthesis of Bi2WO6 and its photocatalytic activities. Mater Res Bull 66:96–100CrossRef
20.
go back to reference Kulsi C, Ghosh A, Mondal A, Kargupta K, Ganguly S, Banerjee D (2017) Remarkable photo-catalytic degradation of malachite green by nickel doped bismuth selenide under visible light irradiation. Appl Surf Sci 392:540–548CrossRef Kulsi C, Ghosh A, Mondal A, Kargupta K, Ganguly S, Banerjee D (2017) Remarkable photo-catalytic degradation of malachite green by nickel doped bismuth selenide under visible light irradiation. Appl Surf Sci 392:540–548CrossRef
21.
go back to reference Gurunathan K (2004) Photocatalytic hydrogen production using transition metal ions-doped gamma-Bi2O3 semiconductor particles. Int J Hydrogen Energ 29:933–940CrossRef Gurunathan K (2004) Photocatalytic hydrogen production using transition metal ions-doped gamma-Bi2O3 semiconductor particles. Int J Hydrogen Energ 29:933–940CrossRef
22.
go back to reference Zhou JL, Wei YX, Zhe JM, Xu CY (2016) Electrochromic properties of vertically aligned Ni-doped WO3 nanostructure films and their application in complementary electrochromic devices. J Mater Chem C 4:1613–1622CrossRef Zhou JL, Wei YX, Zhe JM, Xu CY (2016) Electrochromic properties of vertically aligned Ni-doped WO3 nanostructure films and their application in complementary electrochromic devices. J Mater Chem C 4:1613–1622CrossRef
24.
go back to reference Ahmed B, Ojha AK, Kumar S (2017) One-pot synthesis of Ni doped CdS nanosheets for near infrared emission and excellent photocatalytic materials for degradation of MB dye under UV and sunlight irradiation. Spectrochim Acta A 179:144–154CrossRef Ahmed B, Ojha AK, Kumar S (2017) One-pot synthesis of Ni doped CdS nanosheets for near infrared emission and excellent photocatalytic materials for degradation of MB dye under UV and sunlight irradiation. Spectrochim Acta A 179:144–154CrossRef
25.
go back to reference Huang HW, Li XW, Wang JJ, Li M, Dong F, Chu PK, Zhang TR, Zhang HY (2015) Anionic group self-doping as a promising strategy: band-gap engineering and multi-functional applications of high-performance CO3 2−-doped Bi2O2CO3. ACS Catal 5:4094–4103CrossRef Huang HW, Li XW, Wang JJ, Li M, Dong F, Chu PK, Zhang TR, Zhang HY (2015) Anionic group self-doping as a promising strategy: band-gap engineering and multi-functional applications of high-performance CO3 2−-doped Bi2O2CO3. ACS Catal 5:4094–4103CrossRef
26.
go back to reference Zhou D, Shi F, Xie D, Wang DH, Xia XH, Wang XL, Gu CD, Tu JP (2016) Bi-functional Mo-doped WO3 nanowire array electrochromism-plus electrochemical energy storage. J Colloid Interface Sci 465:112–120CrossRef Zhou D, Shi F, Xie D, Wang DH, Xia XH, Wang XL, Gu CD, Tu JP (2016) Bi-functional Mo-doped WO3 nanowire array electrochromism-plus electrochemical energy storage. J Colloid Interface Sci 465:112–120CrossRef
27.
go back to reference Chen QF, Shi WM, Jiang D, Xu Y, Wu D, Sun YH (2010) Visible-light-activated Ni–Si Co-doped TiO2 with photocatalytic performance. Acta Chim Sin 68:301–308 Chen QF, Shi WM, Jiang D, Xu Y, Wu D, Sun YH (2010) Visible-light-activated Ni–Si Co-doped TiO2 with photocatalytic performance. Acta Chim Sin 68:301–308
28.
go back to reference Xiao YH, Xu CQ, Zhang WD (2017) Facile synthesis of Ni-doped WO3 nanoplate arrays for effective photoelectrochemical water splitting. J Solid State Electrochem 21:3355–3364CrossRef Xiao YH, Xu CQ, Zhang WD (2017) Facile synthesis of Ni-doped WO3 nanoplate arrays for effective photoelectrochemical water splitting. J Solid State Electrochem 21:3355–3364CrossRef
29.
go back to reference Yu JG, Xiong JF, Cheng B, Yu Y, Wang JB (2005) Hydrothermal preparation and visible-light photocatalytic activity of Bi2WO6 powders. J Solid State Chem 178:1968–1972CrossRef Yu JG, Xiong JF, Cheng B, Yu Y, Wang JB (2005) Hydrothermal preparation and visible-light photocatalytic activity of Bi2WO6 powders. J Solid State Chem 178:1968–1972CrossRef
30.
go back to reference Zhang LW, Wang YJ, Cheng HY, Yao WQ, Zhu YF (2009) Synthesis of Porous Bi2WO6 thin films as efficient visible-light-active photocatalysts. Adv Mater 21:1286–1290CrossRef Zhang LW, Wang YJ, Cheng HY, Yao WQ, Zhu YF (2009) Synthesis of Porous Bi2WO6 thin films as efficient visible-light-active photocatalysts. Adv Mater 21:1286–1290CrossRef
31.
go back to reference Ma HW, Shen JF, Shi M, Lu X, Li ZQ, Long Y, Li N, Ye MX (2012) Significant enhanced performance for Rhodamine B, phenol and Cr(VI) removal by Bi2WO6 nancomposites via reduced graphene oxide modification. Appl Catal B Environ 121:198–205CrossRef Ma HW, Shen JF, Shi M, Lu X, Li ZQ, Long Y, Li N, Ye MX (2012) Significant enhanced performance for Rhodamine B, phenol and Cr(VI) removal by Bi2WO6 nancomposites via reduced graphene oxide modification. Appl Catal B Environ 121:198–205CrossRef
32.
go back to reference Yu ZX, Xiang L, Zhong FL, Li YW, Mo CH, Cai QY, Huang XP, Wu XL, Zhao HM (2015) Effects of solution pH on photocatalytic degradation of rhodamine B using bismuth tungstate prepared by low-temperature combustion method. J Inorg Mater 30:535–541CrossRef Yu ZX, Xiang L, Zhong FL, Li YW, Mo CH, Cai QY, Huang XP, Wu XL, Zhao HM (2015) Effects of solution pH on photocatalytic degradation of rhodamine B using bismuth tungstate prepared by low-temperature combustion method. J Inorg Mater 30:535–541CrossRef
33.
go back to reference Kasnavia T, Vu D, Sabatini S (1999) Fluorescent dye and media properties affecting sorption and tracer selection. Ground Water 3:376–381CrossRef Kasnavia T, Vu D, Sabatini S (1999) Fluorescent dye and media properties affecting sorption and tracer selection. Ground Water 3:376–381CrossRef
34.
go back to reference Huang HJ, Li DZ, Lin Q, Zhang WJ, Shao Y, Chen YB, Sun M, Fu XZ (2009) Efficient degradation of benzene over LaVO4/TiO2 nanocrystalline heterojunction photocatalyst under visible light irradiation. Environ Sci Technol 43:4164–4168CrossRef Huang HJ, Li DZ, Lin Q, Zhang WJ, Shao Y, Chen YB, Sun M, Fu XZ (2009) Efficient degradation of benzene over LaVO4/TiO2 nanocrystalline heterojunction photocatalyst under visible light irradiation. Environ Sci Technol 43:4164–4168CrossRef
35.
go back to reference Fu H, Zhang S, Xu T, Zhu Y, Chen J (2008) Photocatalytic degradation of RhB by fluorinated Bi2WO6 and distributions of the intermediate products. Environ Sci Technol 42:2085–2091CrossRef Fu H, Zhang S, Xu T, Zhu Y, Chen J (2008) Photocatalytic degradation of RhB by fluorinated Bi2WO6 and distributions of the intermediate products. Environ Sci Technol 42:2085–2091CrossRef
36.
go back to reference Huang HW, Tu SC, Zeng C, Zhang TR, Reshak AH, Zhang YH (2017) Macroscopic polarization enhancement promoting photo- and piezoelectric-induced charge separation and molecular oxygen activation. Angew Chem Int Ed 56:11860–11864CrossRef Huang HW, Tu SC, Zeng C, Zhang TR, Reshak AH, Zhang YH (2017) Macroscopic polarization enhancement promoting photo- and piezoelectric-induced charge separation and molecular oxygen activation. Angew Chem Int Ed 56:11860–11864CrossRef
37.
go back to reference Wu XL, Xiang L, Yan QY, Jiang YN, Li YW, Huang XP, Li H, Cai QY, Mo CH (2014) Distribution and risk assessment of quinolone antibiotics in the soils from organic vegetable farms of a subtropical city, Southern China. Sci Total Environ 487:399–406CrossRef Wu XL, Xiang L, Yan QY, Jiang YN, Li YW, Huang XP, Li H, Cai QY, Mo CH (2014) Distribution and risk assessment of quinolone antibiotics in the soils from organic vegetable farms of a subtropical city, Southern China. Sci Total Environ 487:399–406CrossRef
38.
go back to reference Song JM, Wang H, Li YP, Zhu XM, Li LL, Yang J, Jin BK (2013) Photocatalytic activity enhancement for 3D hierarchical Bi2WO6 microsphere and surface acidity. Sci Chin Chem 43:163–170 Song JM, Wang H, Li YP, Zhu XM, Li LL, Yang J, Jin BK (2013) Photocatalytic activity enhancement for 3D hierarchical Bi2WO6 microsphere and surface acidity. Sci Chin Chem 43:163–170
Metadata
Title
Facile synthesis of Ni-doping Bi2WO6 nano-sheets with enhanced adsorptive and visible-light photocatalytic performances
Authors
Lei Xiang
Lei Chen
Ce-Hui Mo
Lian-Ming Zheng
Zhong-Xiong Yu
Yan-Wen Li
Quan-Ying Cai
Hui Li
Wei-Dong Yang
Dong-Mei Zhou
Ming-Hung Wong
Publication date
01-02-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 10/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2064-3

Other articles of this Issue 10/2018

Journal of Materials Science 10/2018 Go to the issue

Premium Partners