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01-12-2017 | Research Paper

Förster resonance energy transfer in hybrid associates of colloidal Ag₂S quantum dots with thionine molecules

Authors: Oleg V. Ovchinnikov, Mikhail S. Smirnov, Tamara S. Kondratenko, Sergey A. Ambrosevich, Mikhail T. Metlin, Irina G. Grevtseva, Aleksey S. Perepelitsa

Published in: Journal of Nanoparticle Research | Issue 12/2017

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Abstract

Nonradiative resonance energy transfer in hydrophilic hybrid associates of thionine molecules (TH⁺) with colloidal Ag₂S quantum dots (QDs) with average diameter of 3.5 nm was studied. Photoluminescence spectra and its decay shown that for these systems the supplemental photosensitization of recombination luminescence of Ag₂S QDs (1200 nm) from the region of TH⁺ fluorescence (618 nm) is possible. It was found that the average lifetime of TH⁺ molecules luminescence is shortened during their association with Ag₂S QDs. Approximation of luminescence decay by stretched exponent with value of parameter β = 0.5 indicates on the inductive-resonance dipole-dipole (Förster) mechanism of nonradiative energy transfer (FRET). The efficiency of FRET was 0.29–0.41.

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Title: Förster resonance energy transfer in hybrid associates of colloidal Ag2S quantum dots with thionine molecules
Authors: Oleg V. Ovchinnikov
Mikhail S. Smirnov
Tamara S. Kondratenko
Sergey A. Ambrosevich
Mikhail T. Metlin
Irina G. Grevtseva
Aleksey S. Perepelitsa
Publication date: 01-12-2017
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 12/2017
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-017-4093-2

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