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Glass and Ceramics

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01-07-2013

Functional Glass Ceramic Based on Potassium Niobate

Authors: S. Yu. Stefanovich, V. N. Sigaev, S. V. Lotarev, E. V. Lopatina, A. V. Mosunov, A. G. Segalla, D. P. Chertin

Published in: Glass and Ceramics | Issue 3-4/2013

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Abstract

A new approach to obtaining a functional glass ceramic based on potassium niobate from an amorphous precursor, obtained by rapid cooling of the melt containing small additions of the glass former SiO₂, is examined. The results indicate that there is promise in the glass ceramic technology, which ensures the formation of cubic KNbO₃ crystals of almost ideal habitus whose flat grains surrounded by thin, composition-regulated glass interlayers can stick to one another. The ceramic KNbO₃ obtained by the glass ceramic technology differs beneficially from its conventional analog by low tanä in the entire range of existence of the ferroelectric phase (below 410°C), which determines its advantage for a host of applications.

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Here and below, the molar content unless otherwise stipulated.

I. Saito, H. Takao, T. Tani, et al., “Lead-free piezoceramics,” Nature, 432, 84–87 (2004).CrossRef

2. K. Kakimoto, I. Masuda, and H. Ohsato, “Lead-free KNbO₃ piezoceramics synthesized by pressure-less sintering,” J. Europ. Ceram. Soc., 25, 2719–2722 (2005).CrossRef

3. P. Palei and P. Kumar, “Dielectric, ferroelectric and piezoelectric properties of (1 − x )[K_0.5Na_0.5NbO₃ ] − x [LiSbO₃ ] ceramics,” J. Phys. Chem. Sol., 73(3), 827–833 (2012).CrossRef

4. F. Iona and D. Shirane, Ferroelectric Crystals, Pergamon Press, New York (1962).

5. A. S. Mankevich, Thin-Film Ceramic Materials Based on KNbO ₃ and (La, K)MnO ₃ for Composite Multiferroics: Synthesis and Properties, Author’s Abstract of Candidate’s Thesis [in Russian], Izd. MGU im. M. V. Lomonosova, Moscow (2009).

6. T. Sato, Y. Koike, T. Endo, and M. Shimada, “Preparation and characterization of quenched KNbO₃−Nb₂O₅ glass,” J. Mater. Sci., 26, 510–516 (1991).CrossRef

7. K. Shioya, et al., “Optical properties of transparent glass ceramics in K₂ONb₂O₅−TeO₂ glasses,” J. Non-Cryst. Solids, 189, 16–24 (1995).CrossRef

8. H. Tanaka, et al., “Crystalline phases and second harmonic intensities in potassium niobium silicate glasses,” Opt. Mater., 22, 71–79 (2003).CrossRef

9. M. J. Davis, P. Vollo, I. Mitra, et al., “Ferroelectric and nonferroelectric (polar) piezoelectric glass−ceramics,” J. Am. Ceram. Soc., 91(9), 2878–2885 (2008).CrossRef

10.

P. Mukherjee and K. B. R. Varma, “Crystallization and physical properties of LiTaO₃ in a reactive glass matrix,” Ferroelectrics, 306, 129–143 (2004).CrossRef

11.

V. N. Sigaev, V. S. Ryzhenkov, N. V. Golubev, et al., “Glasses and their crystallization in the (1 − x )KNbO₃ − xSiO₂ system at low glass-forming oxide content, 0 ≤ х ≤ 0.35,” J. Non-Cryst. Sol., 356, 958–965 (2010).CrossRef

12.

P. D. Sarkisov, S. V. Lotarev, V. S. Ryzhenkov, et al., “Obtaining potassium niobate based ceramic from glass,” Dokl. Akad. Nauk, 447(1), 63–65 (2012).

13.

K. Nassau, A. Christine, and M. Grasso, “Quenched metastable glassy and crystalline phases in the system lithium-sodium-potassium metaniobate-tantalate,” J. Am. Ceram. Soc., 62, 503–510 (1979).CrossRef

14.

I. V. Zolotukhin and Yu. V. Barmin, Stability and Relaxation Processes in Metallic Glasses [in Russian], Metallurgiya, Moscow (1991).

15.

S. K. Kurtz and T. T. Perry, “A powder technique for the evaluation of nonlinear optical materials,” J. Appl. Phys., 39, 3798–3813 (l968).CrossRef

16.

S. Yu. Stefanovich and V. N. Sigaev, “Application of the SHG method to studying the crystallization of non-centrosymmetric phases in glasses,” Fiz. Khim. Stekla, 21(4), 3435–358 (1995).

Title: Functional Glass Ceramic Based on Potassium Niobate
Authors: S. Yu. Stefanovich
V. N. Sigaev
S. V. Lotarev
E. V. Lopatina
A. V. Mosunov
A. G. Segalla
D. P. Chertin
Publication date: 01-07-2013
Publisher: Springer US
Published in: Glass and Ceramics / Issue 3-4/2013
Print ISSN: 0361-7610
Electronic ISSN: 1573-8515
DOI: https://doi.org/10.1007/s10717-013-9526-5

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