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Topics in Catalysis
Published in: Topics in Catalysis 7-10/2010

01-06-2010 | Original Paper

Further Investigations on the Promoting Effect of Mesoporous Silica on Base-Catalyzed Aldol Reaction

Authors: Y. Kubota, H. Yamaguchi, T. Yamada, S. Inagaki, Y. Sugi, T. Tatsumi

Published in: Topics in Catalysis | Issue 7-10/2010

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Abstract

Addition of an ordered mesoporous silica to a mixture of an aldol reaction, comprising 4-nitrobenzaldehyde with acetone catalyzed by organic amines, caused significant increase in the reaction rate to afford the β-hydroxyketone in high yield. A cooperative effect between the surface silanol and amine was considered to be the likely reason for the rate-enhancement, which was supported by FTIR spectroscopy.
previous article Dehydration of Triol Compounds in High-Temperature Liquid Water Under High-Pressure Carbon Dioxide
next article Highly Efficient Supported Diimine Ni(II) and Iminopyridyl Fe(II) Catalysts for Ethylene Polymerizations

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Metadata
Title
Further Investigations on the Promoting Effect of Mesoporous Silica on Base-Catalyzed Aldol Reaction
Authors
Y. Kubota
H. Yamaguchi
T. Yamada
S. Inagaki
Y. Sugi
T. Tatsumi
Publication date
01-06-2010
Publisher
Springer US
Published in
Topics in Catalysis / Issue 7-10/2010
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-010-9477-9

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