2001 | OriginalPaper | Chapter
Geometric and Electronic Information from the Spectroscopy of Six-Coordinate Copper(II) Compounds
Author : Mark J. Riley
Published in: Transition Metal and Rare Earth Compounds
Publisher: Springer Berlin Heidelberg
Included in: Professional Book Archive
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The ground and excited state geometry of the six-coordinate copper(II) ion is examined in detail using the CuF64− and Cu(H2O)62+ complexes as examples. A variety of spectroscopic techniques are used to illustrate the relations between the geometric and electronic properties of these complexes through the characterization of their potential energy surfaces.