Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 5/2017

11-10-2016 | Original Paper

Graft copolymerization of itaconic acid onto guar gum using ceric ammonium sulfate as an initiator and its characterizations

Authors: Anita G. Sullad, Ashok V. Gaddi, Rahul B. Nemagouda, Mallikarjun Buradiyavar, Vijay P. Gaonkar, Praveen N. Naik

Published in: Polymer Bulletin | Issue 5/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This study focuses on synthesis of pH-sensitive graft copolymer and its characterizations which can be effectively used for various applications, viz. controlled drug delivery, heavy metal adsorption, etc. Itaconic acid-grafted-guar gum (IA-g-GG) copolymer was prepared by free radical mechanism using ceric ammonium sulfate (CAS) as an initiator. Influence of concentration of CAS, IA, reaction temperature and reaction time on grafting efficiency was investigated. Plausible mechanism for grafting reaction was suggested. The graft copolymer formed was characterized by Fourier transform infrared (FTIR), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). Swelling studies of the graft hydrogel was carried out in both acidic (pH 1.2) and basic (pH 7.4) media.
previous article Main characteristic of N-bromo poly(styrene-co-divinylbenzene) sulphonamide acid: a cation exchanger and redox polymer
next article Efficient modification of nanosilica particles in preparation of anti-scratch transparent polyacrylic films through miniemulsion polymerization

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Pietro M, Chiara DM, Tommasina C, Wim EH, Franco A (2013) Interpenetrating polymer networks polysaccharide hydrogels for drug delivery and tissue engineering. Adv Drug Del Rev 65:1172–1187CrossRef
2.
Rajangam V, Rajangam P, Dharmalingam S (2011) Separation of heavy metals from water samples using anion exchange polymers by adsorption process. Desalination 267(2):267–276
3.
Susheelkumar GA, Lata SM, Santoshkumar DB, Tejraj MA (2008) Aluminum-rich zeolite beta incorporated sodium alginate mixed matrix membranes for pervaporation dehydration and esterification of ethanol and acetic acid. J Memb Sci 318:233–246CrossRef
4.
Irene T, Zoya Z, Jean-François L, Maria-Magdalena T (2009) PEGylated chromatography: efficient bioseparation on silica monoliths grafted with smart biocompatible polymers. Appl Mater Interfaces 1:1869–1872
5.
Rudy C, Catherine L, Jacques D, Emmanuelle M, Alain D (2013) Hydrophobic modification of dextran with 1,2-epoxyalkanes in aqueous micellar medium: competition between interfacial and bulk reactions and consequences on polymer properties. Colloids Surf A, Physicochem Eng Asp 436:744–750CrossRef
6.
García NL, Lamanna M, D’Accorso N, Dufresne A, Aranguren M, Goyanes S (2012) Biodegradable materials from grafting of modified PLA onto starch nanocrystals. Polym Degrad Stab 97:2021–2026CrossRef
7.
Anita GS, Lata SM, Tejraj MA (2011) Microspheres of carboxymethyl guar gum for in vitro release of abacavir sulfate: Preparation and characterization. J Appl Polym Sci 122:452–460CrossRef
8.
Tatiana D, Daria ZZ, Michail Y, Alla G, Tatiana A, Elena M, Alexander Z (2012) DC discharge plasma modification of chitosan/gelatin/PLLA films: surface properties, chemical structure and cell affinity. Surf Coat Technol 207:508–516CrossRef
9.
Tetsuya Y, Kan K (2016) Relationship between surface potential and particle size in soap-free emulsion copolymerization of styrene and methyl methacrylate using a water- or oil-soluble initiator. Colloid and Polymer Sci 294:281–284CrossRef
10.
Mahbub H, Kakarla RR, Enamul H, Shaikh NF, Samira G, Andrew IM, Vincent GG (2014) Hierarchical assembly of graphene/polyaniline nanostructures to synthesize free-standing supercapacitor electrode. Compos Sci Technol 98:1–8CrossRef
11.
Kakarla RR, Wonjung P, Byung CS, Jaegeun N, Youngil L (2009) Synthesis of electrically conductive and superparamagnetic monodispersed iron oxide-conjugated polymer composite nanoparticles by in situ chemical oxidative polymerization. Colloid and Interface Sci 335:34–39CrossRef
12.
Kakarla RR, Anjanapura VR, Han MJ (2008) Synthesis and characterization of novel polyurethanes based on 4,4′-{1,4-phenylenebis[methylylidenenitrilo]}diphenol. Polymer Bull 60:609–616CrossRef
13.
Sang HC, Dong HK, Anjanapura VR, Kakarla RR, Hyung-Il L, Koo SY, Han MJ, Byung KK (2012) Properties of graphene/waterborne polyurethane nanocomposites cast from colloidal dispersion mixtures. J Macromol Sci Part B: Phys 51:197–207CrossRef
14.
Kakarla RR, Mahbub H, Vincent GG (2015) Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis. Appl Catal A 489:1–16CrossRef
15.
Yu PZ, Se HL, Kakarla RR, Anantha IG, Kwang PL (2007) Synthesis and characterization of core-shell SiO2nanoparticles/poly(3-aminophenylboronic acid) composites. J Appl Polymer Sci 104:2743–2750CrossRef
16.
Kakarla RR, Kwang-Pill L, Anantha IG (2007) Self-assembly directed synthesis of poly (ortho-toluidine)-metal (gold and palladium) composite nanospheres. J Nanosci Nanotechnol 7:3117–3125CrossRef
17.
Kakarla RR, Kwang-P L, Anantha IG (2007) Novel electrically conductive and ferromagnetic composites of poly(aniline-co-aminonaphthalenesulfonic acid) with iron oxide nanoparticles: synthesis and characterization. J Appl Polymer Sci 106:1181–1191CrossRef
18.
Yu RL, Soon CK, Hyung-il L, Han MJ, Anjanapura VR, Kakarla RR, Byung KK (2011) Graphite oxides as effective fire retardants of epoxy resin. Macromol Res 19:66–71CrossRef
19.
Kumar Ravi, Anupama S, Mahadevan N (2012) Grafting modification of the polysaccharide by the use of microwave irradiation—a review. Int J Recent Adv Pharm Res 2:45–53
20.
Nuran I, Fatma K, Murat I (2010) Graft copolymerization of itaconic acid onto sodium alginate using benzoyl peroxide. Carbohydr Polym 79:665–672CrossRef
21.
Isıklan N, Sanlı O (2004) Permeation and separation characteristics of acetic acid/water mixtures through poly(vinyl alcohol-g-itaconic acid) membranes by pervaporation, evapomeation, and temperature-difference evapomeation. J Appl Polym Sci 93:2322–2333CrossRef
22.
Pulat M, Babayigit D (2001) Surface modification of PU membranes by graft copolymerization with acrylamide and itaconic acid monomers. Polym Test 20:209–216CrossRef
23.
Pulat M, Isakoca C (2006) Chemically induced graft copolymerization of vinyl monomers onto cotton fibers. J Appl Polym Sci 100:2343–2347CrossRef
24.
Rebecca JW, Anaïs P-B, Nigel K, Andrew PD, Rachel KO (2016) Cyclic graft copolymer unimolecular micelles: effects of cyclization on particle morphology and thermoresponsive behavior. Macromolecules 49(7):2802–2813CrossRef
25.
Kakarla RR, Kwang-Pill L, Ju YK, Youngil L (2008) Self-assembly and graft polymerization route to monodispersed Fe3O4@SiO2—polyaniline core-shell composite nanoparticles: physical properties. J Nanosci Nanotechnol 8:5632–5639CrossRef
26.
Kakarla RR, Byung CS, Kwang SR, Jin-Chun K, Hoeil C, Youngil L (2009) Conducting polymer functionalized multi-walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603CrossRef
27.
Hai-Qing S, Dou Xue-Bo, Li Rui-Quan, Bing-Ran Yu, Zhao Na-Na, Fu-Jian Xu (2015) A general strategy to prepare different types of polysaccharide-graft-poly(aspartic acid) as degradable gene carriers. Acta Biomater 12:156–165CrossRef
28.
Baljit S, Vikrant S, Pal Lok (2011) Formation of sterculia polysaccharide networks by gamma rays induced graft copolymerization for biomedical applications. Carbohydr Polym 86:1371–1380CrossRef
29.
Chunhua Gu, Le Vanminh, Lang Meidong, Liu Jianwen (2014) Preparation of polysaccharide derivates chitosan-graft-poly(ɛ-caprolactone) amphiphilic copolymer micelles for 5-fluorouracil drug delivery. Colloids Surf, B 116:745–750CrossRef
30.
Anita GS, Lata SM, Tejraj MA (2010) Novel pH-sensitive hydrogels prepared from the blends of poly(vinyl alcohol) with acrylic acid-graft-guar gum matrixes for isoniazid delivery. Ind Eng Chem Res 49:7323–7329CrossRef
31.
Hua W, Mozhen W, Xuewu G (2009) Graft copolymers of polyurethane with various vinyl monomers via radiation-induced miniemulsion polymerization: influential factors to grafting efficiency and particle morphology. Rad Phys Chem 78:112–118CrossRef
32.
Shojaei A, Fathi R, Sheikh N (2007) Adhesion modification of polyethylenes for metallization using radiation-induced grafting of vinyl monomers. Surf Coat Techn 201:7519–7529CrossRef
33.
Goldstein AM, Alter EN, Seaman JK (1973) Guar gum. In: Whistler WL (ed) Industrial gums, polysaccharides and their derivatives. Academic press, New York, pp 303–321
34.
Krishnanaiah YSR, Kartikeyan RS, Gouri SV, Satyanarayan V (2002) Three-layer guar gum matrix tablet formulations for oral controlled delivery of highly soluble trimetazidine dihydrochloride. J Control Release 81:45–56CrossRef
35.
Srivastava A, Mishra V, Singh SK, Kumar R (2010) Vanadium (V)/mandelic acid initiated graft copolymerization of acrylamide onto guar gum in an aqueous medium. J App Polym Sci 115:2375–2385CrossRef
36.
Kunj B, Jaya B, Arti S, Dinesh Kumar M (2005) Studies on graft copolymerization of N-vinyl formamide onto guar gum initiated by bromate/ascorbic acid redox pair. Ind J Chem Techn 12:664–670
37.
Reddy TT, Subbarami Reddy N, Shekharam T (2003) Synthesis and characterization of guar gum-graft-polyacrylonitrile. Polym Adv Technol 14:663–668CrossRef
38.
Soppirnath KS, Aminabhavi TM (2002) Water transport and drug release study from cross-linked polyacrylamide grafted guar gum hydrogel microspheres for the controlled release application. Eur J Pharm Biopharm 53:87–98CrossRef
39.
Sun T, Xu P, Liu Q, Xue J, Xie W (2003) Graft copolymerization of methacrylic acid onto carboxymethyl chitosan. Eur Polym J 39:189–192CrossRef
40.
Kang BG, Yoon SH, Lee SH (1996) Studies on the physical properties of modified starch-filled HDPE film. J Appl Polym Sci 60:1977–1984CrossRef
41.
Naguib HF (2002) Chemically induced graft copolymerization of itaconic acid onto sisal fibers. J Polym Res 9:207–211CrossRef
42.
Hon DNS, Chan HC (1982) Photoinduced grafting reactions in cellulose and cellulose derivatives. In: Graft copolymerization of lignocellulosic fibers, symposium series 187. American Chemical Society, Washington DC, p 101
43.
Misra BN, Dogra R, Kaur I, Jassal JK (1979) Grafting onto cellulose. IV. Effect of complexing agents on fenton’s reagent (Fe2+–H2O2)-initiated grafting of poly(vinyl acetate). J Polym Sci Polym Chem Edition 17:1861–1863CrossRef
44.
Mino G, Kaizerman SA (1958) New method for the preparation of graft copolymers. Polymerization initiated by ceric ion redox systems. J Polym Sci 31:242–243CrossRef
45.
Bains MS (1972) Inorganic redox systems in graft polymerization onto cellulosic materials. J Polym Sci Part C: Polym Symp 37:125–151CrossRef
46.
Gaylord NA (1972) A proposed new mechanism for catalyzed and uncatalyzed graft polymerization onto cellulose. J Polym Sci 37:153–172
47.
Fakhru’L-Razi A, Qudsieh IYM, Rahman MZA, Ahmad MB (2001) Graft copolymerization of methyl methacrylate onto sago starch using ceric ammonium nitrate and potassium persulfate as redox initiator systems. J Appl Polym Sci 82:1375–1381CrossRef
48.
Misra BN, Inderjeet KM, Ramesh D (1978) Graft copolymerization of poly(ethyl acrylate) onto wool in the presence of ceric ammonium nitrate as redox initiator. J Macromol Sci Chem 12:1513–1521CrossRef
Metadata
Title
Graft copolymerization of itaconic acid onto guar gum using ceric ammonium sulfate as an initiator and its characterizations
Authors
Anita G. Sullad
Ashok V. Gaddi
Rahul B. Nemagouda
Mallikarjun Buradiyavar
Vijay P. Gaonkar
Praveen N. Naik
Publication date
11-10-2016
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 5/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1809-x

Other articles of this Issue 5/2017

Polymer Bulletin 5/2017 Go to the issue

Original Paper

PVDF-PAni blend: a free-standing film with variable electrical resistance

Original Paper

Improvement in toughness of polylactide/poly(butylene adipate-co-terephthalate) blend by adding nitrile rubber

Original Paper

Oligoetherols based on melamine–formaldehyde–butanone resins

Original Paper

Efficient modification of nanosilica particles in preparation of anti-scratch transparent polyacrylic films through miniemulsion polymerization

Original Paper

The effects of carbon nanotubes, blend composition and glycidyl methacrylate-grafted polypropylene compatibilizer on the morphology, mechanical and electrical properties of polypropylene-polyamide 6 blends

Original Paper

Synthesis of poly(n-octadecyl methacrylate-co-2-hydroxyethyl methacrylate) copolymer and their utilization as polymeric stabilizer in the preparation of PCL microspheres

Premium Partners

    Image Credits