Skip to main content
Top

2014 | OriginalPaper | Chapter

Gypsum Crystals Formation and Habits, Umm Said Sabkha, Qatar

Author : Mariam Al-Youssef

Published in: Sabkha Ecosystems

Publisher: Springer Netherlands

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This is the first study of gypsum crystal habits and crystallography in the famous, large, costal Umm Said Sabkha in the Qatar Peninsula. Eighty one sediment samples rich in crystals, four shallow core samples and eleven brine samples were collected for detailed studies. Gypsum crystals of various habits and sizes are formed in the surface crust and at shallow depths in the Sabkha sediments. The proportion of gypsum crystals increases in the location of fine sediments than in the sand sediments. The crystals are of acicular, prismatic, lenticular and sub-lenticular, inter-grown sub-lenticular, pyramidal, elliptical and semi-elliptical, and pseudo-tetragonal shapes. The crystals are euhedral, simple and tabular on (010), and the cleavage (010) is very good. Twinning on the (101) and the (100) is common. The crystals faces are parallel to two axes and include (110) prism, (111) pyramid, (011) a-dome, (101) b-dome and the a, b and c pinacoids.
Prismatic and acicular crystals of large and thick size are the dominant habits in the deposits within the Sabkha. Pyramidal, lenticular and sub-lenticular crystals are less dominant and occur mainly in the locations of fine sediments saturated by halite, whereas the crystals of desert raised shape are dominant in the sand dune area in the southwestern part of the Sabkha. The crystals formed above groundwater level and a few centimeters depth from the surface.
Shallow groundwater level, saturation of sediments by brines, high temperature, high evaporation and saturation of brines by SO4 −2 and CaO3 2− provide suitable conditions for the formation of gypsum crystals in the sediments. In addition, the type of host sediments plays an important role in the amount and habit of gypsum crystals in the Sabkha. The general elevation of Umm Said Sabkha above sea level (+1) leads to greater rates of evaporation over groundwater recharge in the Sabkha.
The main conclusion of this study are: (1) the conditions for formation of gypsum in the Umm Said Sabkha are available and accordingly, this Sabkha is a suitable place for establishing a project for cultivation of this important mineral and exploiting it economically; (2) making a center for scientific students and researchers to study the growth and development stages of gypsum crystals, and the conditions affecting their form, shapes, size and other aspects; and (3) This work can be used as a model for the study and utilization of the coastal and inland Sabkhas in Qatar and neighboring countries.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Cavelier C (1970) Geological survey and mineral substances exploration in Qatar, Arabian Gulf. Government of Qatar, Department of Petroleum Affairs, p 100 Cavelier C (1970) Geological survey and mineral substances exploration in Qatar, Arabian Gulf. Government of Qatar, Department of Petroleum Affairs, p 100
2.
go back to reference Illing LV, Wells AJ, Taylor JCM (1965) Pencontemporary dolomite in the Persian Gulf. In: Dolomitization and limestone diagenesis. In: Pray LC, Murray RC (eds) Proceedings of symposium society of economic paleontologists and mineralogists, Tulsa, Oklahoma, USA, pp 89–111 Illing LV, Wells AJ, Taylor JCM (1965) Pencontemporary dolomite in the Persian Gulf. In: Dolomitization and limestone diagenesis. In: Pray LC, Murray RC (eds) Proceedings of symposium society of economic paleontologists and mineralogists, Tulsa, Oklahoma, USA, pp 89–111
3.
go back to reference Al-Hitmi HH (1987) Geological, mineralogical and geochemical studies on the sabkha deposits of Umm Said area, east of Qatar. Dissertation, Ain-Shams University, Cairo, Egypt Al-Hitmi HH (1987) Geological, mineralogical and geochemical studies on the sabkha deposits of Umm Said area, east of Qatar. Dissertation, Ain-Shams University, Cairo, Egypt
4.
go back to reference Ragab AI, Hilmy ME, Al-Hitmy HH (1991) Sediment distribution, mineralogy and geochemistry of the sabkha sequence of Umm Said, Qatar. Earth Sci Ser 5:1–15 Ragab AI, Hilmy ME, Al-Hitmy HH (1991) Sediment distribution, mineralogy and geochemistry of the sabkha sequence of Umm Said, Qatar. Earth Sci Ser 5:1–15
5.
go back to reference Curtis R, Evans G, Kinsman DJJ, Shearman DJ (1962) Association of dolomite and anhydrite in the recent sediments of the Persian Gulf. In: Kirkland DW, Evans R (eds) Marine evaporites: origin, diagenesis and geochemistry. Dowden Hutchinson and Ross, Stroudsburg, pp 58–60 Curtis R, Evans G, Kinsman DJJ, Shearman DJ (1962) Association of dolomite and anhydrite in the recent sediments of the Persian Gulf. In: Kirkland DW, Evans R (eds) Marine evaporites: origin, diagenesis and geochemistry. Dowden Hutchinson and Ross, Stroudsburg, pp 58–60
6.
go back to reference Evans G, Kendall C, Skipwith P (1964) Origin of the coastal flats, the Sabkha of the Trucial coast, Persian Gulf. Nature 202:759–761CrossRef Evans G, Kendall C, Skipwith P (1964) Origin of the coastal flats, the Sabkha of the Trucial coast, Persian Gulf. Nature 202:759–761CrossRef
7.
go back to reference Evans G, Bush P (1969) Some oceanographical and sedimentological observations on a Persian Gulf lagoon. Lagunas Costeras, UN Simposio Mem. Simp. Intern. Lagunas Costeras, UNAM-UNESCO, Mexico, D. F., pp 155–170 Evans G, Bush P (1969) Some oceanographical and sedimentological observations on a Persian Gulf lagoon. Lagunas Costeras, UN Simposio Mem. Simp. Intern. Lagunas Costeras, UNAM-UNESCO, Mexico, D. F., pp 155–170
8.
go back to reference Kinsman DJJ (1966) Gypsum and anhydrite of recent age, Trucial Coast, Persian Gulf. Paper presented at second symposium on salt, vol 1. Northern Ohio Geological Society, Cleveland, OH, pp 302–326 Kinsman DJJ (1966) Gypsum and anhydrite of recent age, Trucial Coast, Persian Gulf. Paper presented at second symposium on salt, vol 1. Northern Ohio Geological Society, Cleveland, OH, pp 302–326
9.
go back to reference Kinsman DJJ (1966) Experimental studies and recent occurrence of gypsum, bassanite and anhydrite. Paper presented at 7th international sedimentological congress, Mexico (Special paper) Kinsman DJJ (1966) Experimental studies and recent occurrence of gypsum, bassanite and anhydrite. Paper presented at 7th international sedimentological congress, Mexico (Special paper)
10.
go back to reference Kinsman DJJ (1969) Mode of formation, sedimentary associations, and diagnostic features of shallow-water and supra tidal evaporates. AAPG Bull 53:30–840 Kinsman DJJ (1969) Mode of formation, sedimentary associations, and diagnostic features of shallow-water and supra tidal evaporates. AAPG Bull 53:30–840
11.
go back to reference Kinsman DJJ (1976) Evaporites: relative humidity control of primary mineral facies. J Sediment Petrol 46:273–279 Kinsman DJJ (1976) Evaporites: relative humidity control of primary mineral facies. J Sediment Petrol 46:273–279
12.
go back to reference Shearman DJ (1966) Marine evaporites: origin, diagenesis and geochemistry. In: Kirkland DW, Evens R (eds) Benchmark papers in geology. Dowden, Hutchinson and Ross, Stroudsburg, pp 61–68 Shearman DJ (1966) Marine evaporites: origin, diagenesis and geochemistry. In: Kirkland DW, Evens R (eds) Benchmark papers in geology. Dowden, Hutchinson and Ross, Stroudsburg, pp 61–68
13.
go back to reference Shearman DJ (1981) Displacement of sand grains in sandy gypsum crystals. Geol Mag 118:303–306CrossRef Shearman DJ (1981) Displacement of sand grains in sandy gypsum crystals. Geol Mag 118:303–306CrossRef
14.
go back to reference Park RK (1977) The preservation potential of some recent stromtolites. In: Hsu K, Matter A (eds) Sedimentology: the journal of the international association of sedimentologists. Blackwell, Oxford/London Park RK (1977) The preservation potential of some recent stromtolites. In: Hsu K, Matter A (eds) Sedimentology: the journal of the international association of sedimentologists. Blackwell, Oxford/London
15.
go back to reference Butler GP (1969) Modern evaporite deposition and geochemistry of coexisting brines, the sabkha, Trucial Coast, Arabian Gulf. J Sediment Petrol 39:70–89 Butler GP (1969) Modern evaporite deposition and geochemistry of coexisting brines, the sabkha, Trucial Coast, Arabian Gulf. J Sediment Petrol 39:70–89
16.
go back to reference Butler GP (1970) Holocene gypsum and anhydrite of the Abu Dhabi Sabkha, Trucial Coast: an alternative explanation of origin. In: Rau JL, Dellwing LF (eds) Proceedings of the 3rd symposium on salt, Northern Ohio, Geological Society, Cleveland, OH Butler GP (1970) Holocene gypsum and anhydrite of the Abu Dhabi Sabkha, Trucial Coast: an alternative explanation of origin. In: Rau JL, Dellwing LF (eds) Proceedings of the 3rd symposium on salt, Northern Ohio, Geological Society, Cleveland, OH
17.
go back to reference Butler GP, Krouse RH, Mitchell R (1973) Sulphur-isotope geochemistry of an arid, supratidal evaporite environment, Trucial Coast. In: Purser BH (ed) The Persian Gulf. Holocene carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/New York, p 471 Butler GP, Krouse RH, Mitchell R (1973) Sulphur-isotope geochemistry of an arid, supratidal evaporite environment, Trucial Coast. In: Purser BH (ed) The Persian Gulf. Holocene carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/New York, p 471
18.
go back to reference Drever JI (ed) (1982) The geochemistry of natural waters. Prentice-Hall, Englewood Cliffs, p 388 Drever JI (ed) (1982) The geochemistry of natural waters. Prentice-Hall, Englewood Cliffs, p 388
19.
go back to reference Gunatilaka A, Mwango S (1987) Continental Sabkha pans and associated Nebkhas in southern Kuwait, Arabian Gulf. In: Frostick L, Reid I (eds) Desert sediments. Ancient and Modern, Geological Society special publication 35. London, pp 187–203 Gunatilaka A, Mwango S (1987) Continental Sabkha pans and associated Nebkhas in southern Kuwait, Arabian Gulf. In: Frostick L, Reid I (eds) Desert sediments. Ancient and Modern, Geological Society special publication 35. London, pp 187–203
20.
go back to reference Behairy AKA, Durgaprasada Rao NVN, El-Shater A (1991) A siliciclastic coastal Sabkha, Red Sea Coast, Saudi Arabia JKU. Mar Sci 2:65–77 Behairy AKA, Durgaprasada Rao NVN, El-Shater A (1991) A siliciclastic coastal Sabkha, Red Sea Coast, Saudi Arabia JKU. Mar Sci 2:65–77
21.
go back to reference Mougenot D (2000) Sand rosses of Saudi Arabia. The Dhahran Geoscience Society. Oil Drop 12:3–11 Mougenot D (2000) Sand rosses of Saudi Arabia. The Dhahran Geoscience Society. Oil Drop 12:3–11
22.
go back to reference Hurlbert SH, Berry RW, Lopez M, Pezzani S (1976) Lago Verde and Lago Flaco: gypsum-bound lakes of the Chilean altiplano. Limnol Oceanogr 21:637–645CrossRef Hurlbert SH, Berry RW, Lopez M, Pezzani S (1976) Lago Verde and Lago Flaco: gypsum-bound lakes of the Chilean altiplano. Limnol Oceanogr 21:637–645CrossRef
23.
go back to reference Antia DJ (ed) (1979) Authigenic gypsum in marine sediments – a comment, vol 31, Marine Geology. Elsevier Scientific, New York Antia DJ (ed) (1979) Authigenic gypsum in marine sediments – a comment, vol 31, Marine Geology. Elsevier Scientific, New York
24.
go back to reference Xavier A, Klemm DD (1979) Authigenic gypsum in deep-sea manganese nodules. Sedimentology 26:307–310CrossRef Xavier A, Klemm DD (1979) Authigenic gypsum in deep-sea manganese nodules. Sedimentology 26:307–310CrossRef
25.
go back to reference Corselli C, Aghib FS (1987) Brine formation and gypsum precipitation in the Bannock Basin, eastern Mediterranean. Mar Geol 75:185–199CrossRef Corselli C, Aghib FS (1987) Brine formation and gypsum precipitation in the Bannock Basin, eastern Mediterranean. Mar Geol 75:185–199CrossRef
26.
go back to reference Shinn EA (1973) Sedimentary accretion along the leeward S.E. Coast of Qatar Peninsula, Persian Gulf, The Persian Gulf. In: Purser BH (ed) Holocene carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/Heidelberg/New York, p 471 Shinn EA (1973) Sedimentary accretion along the leeward S.E. Coast of Qatar Peninsula, Persian Gulf, The Persian Gulf. In: Purser BH (ed) Holocene carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/Heidelberg/New York, p 471
27.
go back to reference Hunting Surveys LTD (1977) Sand dune movement study, south of Umm Said. Technical report. Ministry of Public Works, Qatar, p 13 Hunting Surveys LTD (1977) Sand dune movement study, south of Umm Said. Technical report. Ministry of Public Works, Qatar, p 13
28.
go back to reference Alsheeb AIM (1988) Coastal geomorphology of the Qatar Peninsula. Dissertation, Swansea University, University of Wales Alsheeb AIM (1988) Coastal geomorphology of the Qatar Peninsula. Dissertation, Swansea University, University of Wales
29.
go back to reference Alsheeb AIM (1996) Coastal Geomorphology of the Qatar Peninsula. University of Qatar. Dar Al-Uloom, Qatar, p 369 (in Arabic) Alsheeb AIM (1996) Coastal Geomorphology of the Qatar Peninsula. University of Qatar. Dar Al-Uloom, Qatar, p 369 (in Arabic)
30.
go back to reference Al-Yousef MMM (2003) Mineralogy, geochemistry and origin of quaternary Sabkhas in the Qatar Peninsula, Arabian Gulf. Dissertation, School of Ocean and Earth Science, UK Al-Yousef MMM (2003) Mineralogy, geochemistry and origin of quaternary Sabkhas in the Qatar Peninsula, Arabian Gulf. Dissertation, School of Ocean and Earth Science, UK
31.
go back to reference Ashour MM, Abdul Mogeath MS, Metwelly AA, Al-Ghzally AJ, Abdul Gafoor AS, Shakespy R, Ali AA (1991) El-Sabkhat in Qatar Peninsula (geomorphological study-vitality-geological). Humanities and Documentation Research Centre, University of Qatar, Doha (in Arabic) Ashour MM, Abdul Mogeath MS, Metwelly AA, Al-Ghzally AJ, Abdul Gafoor AS, Shakespy R, Ali AA (1991) El-Sabkhat in Qatar Peninsula (geomorphological study-vitality-geological). Humanities and Documentation Research Centre, University of Qatar, Doha (in Arabic)
32.
go back to reference Taha YE (1980) Geomorphology of Qatar coast. Dissertation, Cairo University, Cairo, Egypt (in Arabic) Taha YE (1980) Geomorphology of Qatar coast. Dissertation, Cairo University, Cairo, Egypt (in Arabic)
33.
go back to reference Al-Khayat JAA (1996) Biodiversity and biology of salt marsh and mangalbrachyura in Qatar. Dissertation, University of Wales, UK Al-Khayat JAA (1996) Biodiversity and biology of salt marsh and mangalbrachyura in Qatar. Dissertation, University of Wales, UK
34.
go back to reference Noweir AM (1990) Sedimentary processes. Net sand transport and depositional features around Qatar Peninsula, Arabian Gulf as inferred from aerial photographs and Landsat satellite images. Department of geology, University of Qatar, Doha-Qatar Arabian Gulf. Paper presented or Proceedings of 23rd international symposium on remote sensing of the environment, Bangkok, Thailand, p 6 Noweir AM (1990) Sedimentary processes. Net sand transport and depositional features around Qatar Peninsula, Arabian Gulf as inferred from aerial photographs and Landsat satellite images. Department of geology, University of Qatar, Doha-Qatar Arabian Gulf. Paper presented or Proceedings of 23rd international symposium on remote sensing of the environment, Bangkok, Thailand, p 6
35.
go back to reference Grasshoff K (1983) Determination of salinity. In: Grasshoff K, Ehrhardt M, Kremling K (eds) Methods of seawater analyses, 2nd edn. Verlag Chemie, Weinheim, p 419 Grasshoff K (1983) Determination of salinity. In: Grasshoff K, Ehrhardt M, Kremling K (eds) Methods of seawater analyses, 2nd edn. Verlag Chemie, Weinheim, p 419
36.
go back to reference Strickland JDH, Parsons TR (1968) Determination of dissolved oxygen. A practical handbook of seawater analysis. Fish Res Board Can Bull 167:71–75 Strickland JDH, Parsons TR (1968) Determination of dissolved oxygen. A practical handbook of seawater analysis. Fish Res Board Can Bull 167:71–75
37.
go back to reference Kremling K, Olafsson J, Andreae MO, Koroleff F (1983) Determination of trace metals. In: Grasshoff K, Ehrhardt M, Kremling K (eds) Methods of seawater analyses, 2nd edn. Verlag Chemie, Weinheim, p 419 Kremling K, Olafsson J, Andreae MO, Koroleff F (1983) Determination of trace metals. In: Grasshoff K, Ehrhardt M, Kremling K (eds) Methods of seawater analyses, 2nd edn. Verlag Chemie, Weinheim, p 419
38.
go back to reference Crompton TR (ed) (1989) Analyses of seawater. Butterworths, London Crompton TR (ed) (1989) Analyses of seawater. Butterworths, London
39.
go back to reference Reading HG (ed) (1996) Sedimentary environments: processes, facies and stratigraphy, 3rd edn. Blackwell, Oxford, p 688 Reading HG (ed) (1996) Sedimentary environments: processes, facies and stratigraphy, 3rd edn. Blackwell, Oxford, p 688
40.
go back to reference Cody RD (1976) Lenticular gypsum: occurrences in nature and experimental determinations of effects of soluble green plant material on its formation. J Sediment Petrol 49:1015–1028 Cody RD (1976) Lenticular gypsum: occurrences in nature and experimental determinations of effects of soluble green plant material on its formation. J Sediment Petrol 49:1015–1028
41.
go back to reference Rosen MR, Warren J (1990) The origin and significance of groundwater-seepage gypsum from Bristol dry Lake, California, USA. In: Homewood P, Allen PA, Mckenzie JA (eds) Sedimentology, vol 37. Blackwell, Oxford Rosen MR, Warren J (1990) The origin and significance of groundwater-seepage gypsum from Bristol dry Lake, California, USA. In: Homewood P, Allen PA, Mckenzie JA (eds) Sedimentology, vol 37. Blackwell, Oxford
42.
go back to reference Cody RD (1979) Lenticular gypsum: occurrences in nature and experimental determinations of effects of soluble green plant material on its formation. J Sediment Petrol 49:1015–1028 Cody RD (1979) Lenticular gypsum: occurrences in nature and experimental determinations of effects of soluble green plant material on its formation. J Sediment Petrol 49:1015–1028
43.
go back to reference Masson PH (1977) An occurrence of gypsum in southern Texas. In: Kirkland DW, Evans R (eds) Marine evaporites: origin, diagenesis and geochemistry. Dowden Hutchinson and Ross, Stroudsburg Masson PH (1977) An occurrence of gypsum in southern Texas. In: Kirkland DW, Evans R (eds) Marine evaporites: origin, diagenesis and geochemistry. Dowden Hutchinson and Ross, Stroudsburg
44.
go back to reference Bearman G (ed) (1989) Seawater, its composition, properties, and behavior. Pergamon Press, New York Bearman G (ed) (1989) Seawater, its composition, properties, and behavior. Pergamon Press, New York
45.
go back to reference Sonnenfeld P (ed) (1984) Brines and evaporites. Academic Press/Harcourt Brace Jovanovich, Orlando, p 613 Sonnenfeld P (ed) (1984) Brines and evaporites. Academic Press/Harcourt Brace Jovanovich, Orlando, p 613
46.
go back to reference Krumgalz B (1980) Salt effect on the pH of hypersaline solutions. In: Nissenbaum A (ed) Hypersaline brines and evaporitic environments. Proceedings of Bat Sheua seminar on saline lakes and natural brines. Elsevier Scientific Publishing Company, Amsterdam-Oxford, New York, p 270 Krumgalz B (1980) Salt effect on the pH of hypersaline solutions. In: Nissenbaum A (ed) Hypersaline brines and evaporitic environments. Proceedings of Bat Sheua seminar on saline lakes and natural brines. Elsevier Scientific Publishing Company, Amsterdam-Oxford, New York, p 270
47.
go back to reference Horne RA (ed) (1969) Marine chemistry: the structure of water and the chemistry of the hydrosphere. Wiley-Interscience, London, p 568 Horne RA (ed) (1969) Marine chemistry: the structure of water and the chemistry of the hydrosphere. Wiley-Interscience, London, p 568
48.
go back to reference Shahid SA, Rehman K (2011) Soil salinity development, classification, assessment and management in irrigated agriculture. In: Passarakli M (ed) Handbook of plant and crop stress, 3rd edn. CRC Press, Boca Raton, pp 23–39 Shahid SA, Rehman K (2011) Soil salinity development, classification, assessment and management in irrigated agriculture. In: Passarakli M (ed) Handbook of plant and crop stress, 3rd edn. CRC Press, Boca Raton, pp 23–39
49.
go back to reference Cavelier C (1970) Geological description of the Qatar Peninsula. Department of Petroleum Affairs. Bureau de Recherches Geologiques et Minieres, Paris, p 39 Cavelier C (1970) Geological description of the Qatar Peninsula. Department of Petroleum Affairs. Bureau de Recherches Geologiques et Minieres, Paris, p 39
50.
go back to reference Al-Kuwari AJ (1987) Petrological, mineralogical and geochemical studies on the Miocene argillaceous rocks in Qatar, Arabian Gulf. Dissertation, Ain Shams University, Cairo, Egypt Al-Kuwari AJ (1987) Petrological, mineralogical and geochemical studies on the Miocene argillaceous rocks in Qatar, Arabian Gulf. Dissertation, Ain Shams University, Cairo, Egypt
51.
go back to reference Groot DK (1973) Geochemistry of tidal flat brines at Umm Said, SE Qatar, Persian Gulf. In: Purser BH (ed) The Persian Gulf: Holocene Carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/New York, p 471 Groot DK (1973) Geochemistry of tidal flat brines at Umm Said, SE Qatar, Persian Gulf. In: Purser BH (ed) The Persian Gulf: Holocene Carbonate sedimentation and diagenesis in a shallow epicontinental sea. Springer, Berlin/New York, p 471
Metadata
Title
Gypsum Crystals Formation and Habits, Umm Said Sabkha, Qatar
Author
Mariam Al-Youssef
Copyright Year
2014
Publisher
Springer Netherlands
DOI
https://doi.org/10.1007/978-94-007-7411-7_2