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Introduction: Some Essential Attributes of Glassiness Regarding the Nature of Non-crystalline Solids Read chapter Read first chapter

2011 | OriginalPaper | Chapter

2. Heat Capacity and Entropy Functions in Strong and Fragile Glass-Formers, Relative to Those of Disordering Crystalline Materials

Author : C. Austen Angell

Published in: Glassy, Amorphous and Nano-Crystalline Materials

Publisher: Springer Netherlands

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Abstract

The glassy state problem is often separated into two major components [1, 2]. One of these concerns the reasons that glasses form in the first place, and deals with the circumstance that glasses are usually metastable with respect to crystals so that crystallization must be avoided. The second deals with the question of how liquids behave when crystals do not form, and it is with this component that we are concerned in this chapter. Here the central phenomenon with which we must deal, in seeking to understand vitrification, is the heat capacity function and the change in that function that accompanies the freezing in of the disordered state. This phenomenon is illustrated in Fig. 2.1 for a typical molecular liquid, 2-pentene vitrified by both liquid cooling and by vapor deposition [3].

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previous chapter Introduction: Some Essential Attributes of Glassiness Regarding the Nature of Non-crystalline Solids
next chapter Vibration Forms in the Vicinity of Glass Transition, Structural Changes and the Creation of Voids When Assuming the Role of Polarizability
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Metadata
Title
Heat Capacity and Entropy Functions in Strong and Fragile Glass-Formers, Relative to Those of Disordering Crystalline Materials
Author
C. Austen Angell
Copyright Year
2011
Publisher
Springer Netherlands
Book
Glassy, Amorphous and Nano-Crystalline Materials

Print ISBN: 978-90-481-2881-5

Electronic ISBN: 978-90-481-2882-2

Copyright Year: 2011

DOI
https://doi.org/10.1007/978-90-481-2882-2_2

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