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22-08-2018 | Original Paper

Hierarchical Porosity Tailoring of Sol–Gel Derived Pt/SiO₂ Catalysts

Authors: Andrés Felipe Sierra-Salazar, André Ayral, Tony Chave, Vasile Hulea, Sergey I. Nikitenko, Siglinda Perathoner, Patrick Lacroix-Desmazes

Published in: Topics in Catalysis | Issue 14/2018

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Abstract

Hierarchically porous materials offer the opportunity for catalyst development in regards to improving catalytic performances. In the present work, the combination of latex synthesis, sonochemical reduction and two-step catalysed sol–gel process has been demonstrated to be a versatile method for preparing supported catalysts with tailored hierarchical porosity. This method has been used to prepare porous Pt/SiO₂ catalysts with mesopore and macropore size ranges as large as 2–15 nm and 90–400 nm, respectively. These hierarchically porous catalysts presented an excellent catalytic performance for the selective hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). Selectivity values up to 100% at 80% conversion of p-CNB and initial reaction rates up to 74.0 mol_CNB/min mol_Pt were obtained, while a commercial catalyst exhibited both a lower selectivity of 90.8% and a lower initial reaction rate of 47.7 mol_CNB/min mol_Pt.

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Title: Hierarchical Porosity Tailoring of Sol–Gel Derived Pt/SiO2 Catalysts
Authors: Andrés Felipe Sierra-Salazar
André Ayral
Tony Chave
Vasile Hulea
Sergey I. Nikitenko
Siglinda Perathoner
Patrick Lacroix-Desmazes
Publication date: 22-08-2018
Publisher: Springer US
Published in: Topics in Catalysis / Issue 14/2018
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-018-1032-0

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