Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science
Published in: Journal of Materials Science 8/2020

15-11-2019 | Energy materials

Highly scattered Ir oxides on TiN as an efficient oxygen evolution reaction electrocatalyst in acidic media

Authors: Kaikai Zhang, Wanshan Mai, Jin Li, Huan Wang, Guoqiang Li, Wei Hu

Published in: Journal of Materials Science | Issue 8/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Here, a support-type composite catalyst TiN/IrO2 with an outstanding catalytic activity for OER in acid electrolyte was prepared by a colloidal method. It was found the ultra-fine IrO2 nanoclusters (1.41 ± 0.19 nm) scattered on the TiN support like strawberry seeds, which not only provided the higher active surface area, but also exposed much more surface unsaturated Ir atoms with the higher reactive activity compared to saturated iridium atoms. And the mesoporous structure and high surface area inherited from the TiN carrier were also maintained in the composite. Benefit from these characteristics, the as-prepared TiN/IrO2 with IrO2 loading of 31 wt% possessed a mass-normalized OER activity of 874.0 A g−1(IrO2) at the potential of 1.6 V that was about 5.0 times of the unsupported IrO2 (176.0 A g−1IrO2).
previous article Template directed hydrothermal synthesis of flowerlike NiSex/C composites as lithium/sodium ion battery anodes
next article Hydrogen evolution from photocatalytic water splitting by LaMnO3 modified with amorphous CoSx

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Sun W, Zhou Z, Zaman WQ, Cao L, Yang J (2017) Rational manipulation of IrO2 lattice strain on α-MnO2 nanorods as a highly efficient water-splitting catalyst. ACS Appl Mater Interfaces 9(48):41855–41862
2.
Tariq M, Zaman WQ, Sun W, Zhou Z, Wu Y, Cao L, Yang J (2018) Unraveling the beneficial electrochemistry of IrO2/MoO3 hybrid as a highly stable and efficient oxygen evolution reaction catalyst. ACS Sustain Chem Eng 6(4):4854–4862
3.
Tackett BM, Sheng W, Kattel S, Yao S, Yan B, Kuttiyiel KA, Chen JG (2018) Reducing iridium loading in oxygen evolution reaction electrocatalysts using core-shell particles with nitride cores. ACS Catal 8(3):2615–2621
4.
Reier T, Nong HN, Teschner D, Schlögl R, Strasser P (2017) Electrocatalytic oxygen evolution reaction in acidic environments—reaction mechanisms and catalysts. Adv Energy Mater 7(1):1601275
5.
Hu W, Wang Y, Hu X, Zhou Y, Chen S (2012) Three-dimensional ordered macroporous IrO2 as electrocatalyst for oxygen evolution reaction in acidic medium. J Mater Chem 22(13):6010–6016
6.
Reier T, Oezaslan M, Strasser P (2012) Electrocatalytic oxygen evolution reaction (OER) on Ru, Ir, and pt catalysts: a comparative study of nanoparticles and bulk materials. ACS Catal 2(8):1765–1772
7.
Xu J, Aili D, Li Q, Christensen E, Jensen JO, Zhang W, Bjerrum NJ (2014) Oxygen evolution catalysts on supports with a 3-D ordered array structure and intrinsic proton conductivity for proton exchange membrane steam electrolysis. Energy Environ Sci 7(2):820–830
8.
Hu W, Chen S, Xia Q (2014) IrO2/Nb-TiO2 electrocatalyst for oxygen evolution reaction in acidic medium. Int J Hydrogen Energy 39(13):6967–6976
9.
10.
Zhao S, Stocks A, Rasimick B, More K, Xu H (2018) Highly active, durable dispersed iridium nanocatalysts for PEM water electrolyzers. J Electrochem Soc 165(2):F82–F89
11.
Oh HS, Nong HN, Strasser P (2015) Preparation of mesoporous Sb-, F-, and In-doped SnO2 bulk powder with high surface area for use as catalyst supports in electrolytic cells. Adv Funct Mater 25(7):1074–1081
12.
Huang K, Li Y, Yan L, Xing Y (2014) Nanoscale conductive niobium oxides made through low temperature phase transformation for electrocatalyst support. RSC Adv 4(19):9701–9708
13.
Oh H-S, Nong HN, Reier T, Gliech M, Strasser P (2015) Oxide-supported Ir nanodendrites with high activity and durability for the oxygen evolution reaction in acid PEM water electrolyzers. Chem Sci 6(6):3321–3328
14.
Karimi F, Peppley BA (2017) Metal carbide and oxide supports for iridium-based oxygen evolution reaction electrocatalysts for polymer-electrolyte-membrane water electrolysis. Electrochim Acta 246:654–670
15.
Kuttiyiel KA, Sasaki K, Chen W, Su D, Adzic RR (2014) Core–shell, hollow-structured iridium–nickel nitride nanoparticles for the hydrogen evolution reaction. J Mater Chem A 2(3):591–594
16.
Rudenja S, Pan J, Wallinder IO, Leygraf C, Kulu P (1999) Passivation and anodic oxidation of duplex TiN coating on stainless steel. J Electrochem Soc 146(11):4082–4086
17.
Kakinuma K, Wakasugi Y, Uchida M, Kamino T, Uchida H, Watanabe M (2011) Electrochemical activity and durability of platinum catalysts supported on nanometer-size titanium nitride particles for polymer electrolyte fuel cells. Electrochemistry 79(5):399–403
18.
Yang S, Tak YJ, Kim J, Soon A, Lee H (2017) Support effect in single-atom platinum catalyst for electrochemical oxygen reduction support effect in single-atom platinum catalyst for electrochemical oxygen reduction. ACS Catal 7(2):1301–1307
19.
Zheng Y, Zhang J, Zhan H, Sun D, Dang D, Tian XL (2018) Porous and three dimensional titanium nitride supported platinum as an electrocatalyst for oxygen reduction reaction. Electrochem Commun 91:31–35
20.
Yang S, Kim J, Tak YJ, Soon A, Lee H (2016) Single-atom catalyst of platinum supported on titanium nitride for selective electrochemical reactions. Angew Chem Int Ed 55(6):2058–2062
21.
Li G, Li K, Yang L, Chang J, Ma R, Wu Z, Xing W (2018) Boosted performance of Ir species by employing TiN as the support toward oxygen evolution reaction. ACS Appl Mater Interfaces 10(44):38117–38124
22.
Cheng J, Zhang H, Ma H, Zhong H, Zou Y (2009) Preparation of Ir0.4Ru0.6MoxOy for oxygen evolution by modified Adams’ fusion method. Int J Hydrogen Energy 34(16):6609–6661
23.
Ioroi T, Kitazawa N, Yasuda K, Yamamoto Y, Takenaka H (2000) Iridium oxide/platinum electrocatalysts for unitized regenerative polymer electrolyte fuel cells. J Electrochem Soc 147(6):2018–2022
24.
Ioroi T, Kitazawa N, Yasuda K, Yamamoto Y, Takenaka H (2001) IrO2-deposited Pt electrocatalysts for unitized regenerative polymer electrolyte fuel cells. J Appl Electrochem 31(11):1179–1183
25.
Dong Y, Wu Y, Liu M, Li J (2013) Electrocatalysis on shape-controlled titanium nitride nanocrystals for the oxygen reduction reaction. ChemSusChem 6(10):2016–2021
26.
Wei Z, Wang Y, Zhang J (2018) Electrochemical detection of NGF using a reduced graphene oxide-titanium nitride nanocomposite. Sci Rep 8(1):6929
27.
Li C, Shi J, Zhu L, Zhao Y, Lu J, Xu L (2018) Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries. Nano Res 11(8):4302–4312
28.
Liao Y, Xiang J, Yuan L, Hao Z, Gu J, Chen X, Huang Y (2018) Biomimetic root-like TiN/C@S nanofiber as a freestanding cathode with high sulfur loading for lithium-sulfur batteries. ACS Appl Mater Interfaces 10(44):37955–37962
29.
Yang C, Wang H, Lu S, Wu C, Liu Y, Tan Q, Xiang Y (2015) Titanium nitride as an electrocatalyst for V(II)/V(III) redox couples in all-vanadium redox flow batteries. Electrochim Acta 182:834–840
30.
Oktay S, Kahraman Z, Urgen M, Kazmanli K (2015) XPS investigations of tribolayers formed on TiN and (Ti, Re)N coatings. Appl Surf Sci 328:255–261
31.
Cui Z, Zu C, Zhou W, Manthiram A, Goodenough JB (2016) Mesoporous titanium nitride-enabled highly stable lithium-sulfur batteries. Adv Mater 28(32):6926–6931
32.
Zhao D, Cui Z, Wang S, Qin J, Cao M (2016) VN hollow spheres assembled from porous nanosheets for high-performance lithium storage and the oxygen reduction reaction. J Mater Chem A 4(20):7914–7923
33.
Pfeifer V, Jones TE, Velasco Vélez JJ, Massué C, Arrigo R, Teschner D, Hashagen M (2016) The electronic structure of iridium and its oxides. Surf Interface Anal 48(5):261–273
34.
Xiao H, Jia C, Liu B, Huang Y, Cai W, Li J, Huang Y (2019) Breaking long-range order in iridium oxide by alkali ion for efficient water oxidation. J Am Chem Soc 141(7):3014–3023
35.
Pfeifer V, Jones TE, Velasco Vélez JJ, Arrigo R, Piccinin S, Hävecker M, Schlögl R (2017) In situ observation of reactive oxygen species forming on oxygen-evolving iridium surfaces. Chem Sci 8(3):2143–2149
36.
Lee WH, Kim H (2011) Oxidized iridium nanodendrites as catalysts for oxygen evolution reactions. Catal Commun 12(6):408–411
37.
Kuo D-Y, Kawasaki JK, Nelson JN, Kloppenburg J, Hautier G, Shen KM, Suntivich J (2017) Influence of surface adsorption on the oxygen evolution reaction on IrO2(110). J Am Chem Soc 139(9):3473–3479
38.
Mustain WE, Capuano CB, Maric R, Ayers KE, Zhao S, Danilovic N, Mustain WE (2015) Calculating the electrochemically active surface area of iridium oxide in operating proton exchange membrane electrolyzers. J Electrochem Soc 162(12):F1292–F1298
39.
Lettenmeier P, Wang L, Golla-Schindler U, Gazdzicki P, Cañas NA, Handl M, Friedrich KA (2016) Nanosized IrOx-Ir catalyst with relevant activity for anodes of proton exchange membrane electrolysis produced by a cost-effective procedure. Angew Chem Int Ed 55(2):742–746
40.
Hao C, Lv H, Mi C, Song Y, Ma J (2016) Investigation of mesoporous niobium-doped TiO2 as an oxygen evolution catalyst support in an SPE water electrolyzer. ACS Sustain Chem Eng 4(3):746–756
41.
Han B, Risch M, Belden S, Lee S, Bayer D, Mutoro E, Yang SH (2018) Screening oxide support materials for OER catalysts in acid. J Electrochem Soc 165(10):F813–F820
42.
Rai S, Ikram A, Sahai S, Dass S, Shrivastav R, Satsangi VR (2017) CNT based photoelectrodes for PEC generation of hydrogen: a review. Int J Hydrogen Energy 42(7):3994–4006
43.
Guan J, Li D, Si R, Miao S, Zhang F, Li C (2017) Synthesis and demonstration of subnanometric iridium oxide as highly efficient and robust water oxidation catalyst. ACS Catal 7(9):5983–5986
44.
Zhou X, Yang J, Li C (2012) Theoretical study of structure, stability, and the hydrolysis reactions of small iridium oxide nanoclusters. J Phys Chem A 116(40):9985–9995
45.
Ping Y, Nielsen RJ, Goddard WA (2017) The reaction mechanism with free energy barriers at constant potentials for the oxygen evolution reaction at the IrO2(110) surface. J Am Chem Soc 139(1):149–155
46.
Fuentes RE, Colon-Mercado HR, Martinez-Rodriguez MJ (2013) Pt-Ir/TiC electrocatalysts for PEM fuel cell/electrolyzer process. J Electrochem Soc 161(1):F77–F82
47.
Godínez-Salomón F, Albiter L, Alia SM, Pivovar BS, Camacho-Forero LE, Balbuena PB, Rhodes CP (2018) Self-supported hydrous iridium–nickel oxide two-dimensional nanoframes for high activity oxygen evolution electrocatalysts. ACS Catal 8(11):10498–10520
48.
Fu L, Zeng X, Cheng G, Luo W (2018) IrCo nanodendrite as an efficient bifunctional electrocatalyst for overall water splitting under acidic conditions. ACS Appl Mater Interfaces 10(30):24993–24998
49.
Jiang B, Wang T, Cheng Y, Liao F, Wu K, Shao M (2018) Ir/g-C3N4/nitrogen-doped graphene nanocomposites as bifunctional electrocatalysts for overall water splitting in acidic electrolytes. ACS Appl Mater Interfaces 10(45):39161–39167
50.
Nong HN, Oh HS, Reier T, Willinger E, Willinger MG, Petkov V, Strasser P (2015) Oxide-supported IrNiOx core-shell particles as efficient, cost-effective, and stable catalysts for electrochemical water splitting. Angew Chem Int Ed 54(10):297–2979
51.
Liang X, Shi L, Liu Y, Chen H, Si R, Yan W, Zou X (2019) Activating inert, nonprecious perovskites with iridium dopants for efficient oxygen evolution reaction under acidic conditions. Angew Chem Int Ed 58(23):7631–7635
52.
Frydendal R, Paoli EA, Knudsen BP, Wickman B, Malacrida P, Stephens IEL, Chorkendorff I (2014) Benchmarking the stability of oxygen evolution reaction catalysts: the importance of monitoring mass losses. ChemElectroChem 1:2075–2081
Metadata
Title
Highly scattered Ir oxides on TiN as an efficient oxygen evolution reaction electrocatalyst in acidic media
Authors
Kaikai Zhang
Wanshan Mai
Jin Li
Huan Wang
Guoqiang Li
Wei Hu
Publication date
15-11-2019
Publisher
Springer US
Published in
Journal of Materials Science / Issue 8/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04201-4

Other articles of this Issue 8/2020

Journal of Materials Science 8/2020 Go to the issue

Composites & nanocomposites

Synthesis of heterostructure δ-MnO2/h-MoO3 nanocomposite and the enhanced photodegradation activity of methyl orange in aqueous solutions

Metals & corrosion

Study on the controlling factors for the quenching crack sensitivity of ultra-strong automotive steel

Chemical routes to materials

Fabrication of highly stable CdS/g-C3N4 composite for enhanced photocatalytic degradation of RhB and reduction of CO2

Metals & corrosion

Master sintering curves of nickel-titanium and nickel-titanium open-cell foams fabricated by spark plasma sintering

Energy materials

Centrifugally spun porous carbon microfibers as interlayer for Li–S batteries

Chemical routes to materials

Fluoro-polymer-coated carbon nanotubes for improved interfacial interactions and dielectric properties in MWCNTs/PVDF composites

Premium Partners

    Image Credits