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Journal of Materials Science: Materials in Electronics

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01-03-2024

Highly sensitive, selective, repeatable and flexible chemiresistive NO₂ sensor based on reduced graphene oxide/free based porphyrin composite

Authors: Abhaysinh S. Khune, Rameshwar P. Bongane, Vijaykiran N. Narwade, Nikesh N. Ingle, B. N. Dole, Meng-Lin Tsai, Tibor Hianik, Mahendra D. Shirsat

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2024

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Abstract

A highly sensitive and selective nitrogen dioxide (NO₂) sensor has been developed using reduced graphene oxide (rGO)/5-(4-Methoxycarbonylphenyl)-10,15,20-triphenyl-21H,23H-porphine (MCPTPP) composite. The rGO was prepared by thermal reduction of graphene oxide (GO), which was synthesized via an improved Hummer’s method. Using a drop-casting technique, the rGO/MCPTPP composite was deposited on an Indium Tin Oxide (ITO) flexible electrode. Various rGO/MCPTPP composites were developed by varying MCPTPP concentrations. A range of characterization tools confirmed the successful synthesis of the materials. The rGO/MCPTPP_1:3 composite exhibited high sensitivity, rapid response, and a recovery time of 31s. and 81s. respectively when exposed to 250 ppm NO₂ at room temperature (RT). The sensor demonstrated good repeatability, excellent 60-day stability, and linearity from 50 to 500 ppm of NO₂ concentration. The developed flexible chemiresistive sensor displayed excellent selectivity for NO₂ among all the tested gases. The significant enhancement in NO₂ sensing performance is attributed to the synergistic effect between rGO and MCPTPP. This work highlights the potential of the rGO/MCPTPP composite for sensitive and selective chemiresistive detection of NO₂, making it promising for environmental monitoring and chemical industry applications.

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Title: Highly sensitive, selective, repeatable and flexible chemiresistive NO2 sensor based on reduced graphene oxide/free based porphyrin composite
Authors: Abhaysinh S. Khune
Rameshwar P. Bongane
Vijaykiran N. Narwade
Nikesh N. Ingle
B. N. Dole
Meng-Lin Tsai
Tibor Hianik
Mahendra D. Shirsat
Publication date: 01-03-2024
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 9/2024
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-024-12413-x

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