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Journal of Nanoparticle Research

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01-11-2018 | Research Paper

Hydrothermally grown nano-manganese oxide on clinoptilolite for low-temperature propane-selective catalytic reduction of NO_x

Authors: Ali Mirzaei Dakdareh, Cavus Falamaki, Naser Ghasemian

Published in: Journal of Nanoparticle Research | Issue 11/2018

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Abstract

A novel nano-size Mn_xO_y/clinoptilolite catalyst of high activity for propane-SCR reaction of NO_x at low temperatures has been synthesized by a hydrothermal method in a temperature range of 80–180 °C. The optimum synthesis temperature resulting in maximum NO_x conversion was 150 °C. An optimum manganese oxide loading of 0.2 wt.% results in the best catalytic behavior (71% NO_x conversion). All catalysts exhibited an optimal propane-SCR reaction temperature of 200 °C. The optimum catalyst produces no detectable CO (GHSV 27,000 h) at 200 °C. Manganese in the optimum catalyst exists as Mn²⁺ (37.8%), Mn³⁺ (14.2%), and Mn⁴⁺ (48%).

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Title: Hydrothermally grown nano-manganese oxide on clinoptilolite for low-temperature propane-selective catalytic reduction of NOx
Authors: Ali Mirzaei Dakdareh
Cavus Falamaki
Naser Ghasemian
Publication date: 01-11-2018
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 11/2018
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-018-4414-0

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