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Published in: Journal of Nanoparticle Research 11/2018

01-11-2018 | Research Paper

The synthesis of graphene-TiO2/g-C3N4 super-thin heterojunctions with enhanced visible-light photocatalytic activities

Authors: Shuaiqi Gong, Zhengjun Jiang, Sheng Zhu, Jinchen Fan, Qunjie Xu, Yulin Min

Published in: Journal of Nanoparticle Research | Issue 11/2018

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Abstract

In this paper, an efficient strategy for the synthesis of graphene nanobelt-titanium dioxide/graphitic carbon nitride (graphene-TiO2/g-C3N4) heterostructure photocatalyst was applied to fabricate a kind of visible-light-driven photocatalyst. The heterostructure shows higher absorption edge towards harvesting more solar energy compared with pure TiO2 and pure g-C3N4 respectively. Furthermore, the as-prepared graphene-TiO2/g-C3N4 heterostructure can show enhanced photocatalytic activity under visible-light irradiation. These outstanding performances of photocatalytic activities for graphene-TiO2/g-C3N4 composites can be attributed to the heterojunction interfaces which can separate the electron-hole pairs and impede the recombination of electrons and holes more efficiently. This study conclusively demonstrates a facile and environmentally friendly new strategy to design highly efficient graphene-TiO2/g-C3N4 heterostructure photocatalytic materials for potential applications under visible-light irradiation.

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Appendix
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Literature
go back to reference Akhavan O, Abdolahad M, Abdi Y, Mohajerzadeh S (2009) Synthesis of titania/carbon nanotube heterojunction arrays for photoinactivation of E. coli in visible light irradiation. Carbon 47(14):3280–3287CrossRef Akhavan O, Abdolahad M, Abdi Y, Mohajerzadeh S (2009) Synthesis of titania/carbon nanotube heterojunction arrays for photoinactivation of E. coli in visible light irradiation. Carbon 47(14):3280–3287CrossRef
go back to reference And YC, Choi W, Lee CH, Taeghwan Hyeon A, Lee HI (2001) Visible light-induced degradation of carbon tetrachloride on dye-sensitized TiO2. Environ Sci Technol 35(5):966–970CrossRef And YC, Choi W, Lee CH, Taeghwan Hyeon A, Lee HI (2001) Visible light-induced degradation of carbon tetrachloride on dye-sensitized TiO2. Environ Sci Technol 35(5):966–970CrossRef
go back to reference Ardo S, Meyer GJ (2009) Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces. Chem Soc Rev 38(1):115–164CrossRef Ardo S, Meyer GJ (2009) Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces. Chem Soc Rev 38(1):115–164CrossRef
go back to reference Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293(5528):269–271CrossRef Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293(5528):269–271CrossRef
go back to reference Cai L, Cho IS, Logar M, Mehta A, He J, Lee CH, Rao PM, Feng Y, Wilcox J, Prinz FB (2014) Sol-flame synthesis of cobalt-doped TiO2 nanowires with enhanced electrocatalytic activity for oxygen evolution reaction. Phys Chem Chem Phys 16(24):12299–12306CrossRef Cai L, Cho IS, Logar M, Mehta A, He J, Lee CH, Rao PM, Feng Y, Wilcox J, Prinz FB (2014) Sol-flame synthesis of cobalt-doped TiO2 nanowires with enhanced electrocatalytic activity for oxygen evolution reaction. Phys Chem Chem Phys 16(24):12299–12306CrossRef
go back to reference Cai J, Wang Y, Zhu Y, Wu M, Zhang H, Li X, Jiang Z, Meng M (2015) In situ formation of disorder-engineered tio2(b)-anatase heterophase junction for enhanced photocatalytic hydrogen evolution. ACS Appl Mater Interfaces 7(45):24987–24992CrossRef Cai J, Wang Y, Zhu Y, Wu M, Zhang H, Li X, Jiang Z, Meng M (2015) In situ formation of disorder-engineered tio2(b)-anatase heterophase junction for enhanced photocatalytic hydrogen evolution. ACS Appl Mater Interfaces 7(45):24987–24992CrossRef
go back to reference Cao S, Yu J (2013) G-c3n4-based photocatalysts for hydrogen generation. J Phys Chem Lett 4(5):2101–2107 Cao S, Yu J (2013) G-c3n4-based photocatalysts for hydrogen generation. J Phys Chem Lett 4(5):2101–2107
go back to reference Cao S, Low J, Yu J, Jaroniec M (2015) Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater 27(13):2150–2176CrossRef Cao S, Low J, Yu J, Jaroniec M (2015) Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater 27(13):2150–2176CrossRef
go back to reference Chen X, Liu L, Yu PY, Mao SS (2011) Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331(6018):746–750CrossRef Chen X, Liu L, Yu PY, Mao SS (2011) Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331(6018):746–750CrossRef
go back to reference Gao ZD, Qu YF, Zhou X, Wang L, Song YY, Schmuki P (2016) Pt-decorated g-c3n4/TiO2 nanotube arrays with enhanced visible-light photocatalytic activity for H2 evolution. Chemistryopen 5(3):197–200CrossRef Gao ZD, Qu YF, Zhou X, Wang L, Song YY, Schmuki P (2016) Pt-decorated g-c3n4/TiO2 nanotube arrays with enhanced visible-light photocatalytic activity for H2 evolution. Chemistryopen 5(3):197–200CrossRef
go back to reference Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Cheminform abstract: photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew Chem Int Ed 52(29):7372–7408CrossRef Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Cheminform abstract: photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew Chem Int Ed 52(29):7372–7408CrossRef
go back to reference Hirakawa T, Kamat PV (2005) Charge separation and catalytic activity of ag@TiO2 core-shell composite clusters under UV-irradiation. J Am Chem Soc 127(11):3928–3934CrossRef Hirakawa T, Kamat PV (2005) Charge separation and catalytic activity of ag@TiO2 core-shell composite clusters under UV-irradiation. J Am Chem Soc 127(11):3928–3934CrossRef
go back to reference Hirsch A (2009) Unzipping carbon nanotubes: a peeling method for the formation of graphene nanoribbons. Angew Chem Int Ed 48(36):6594–6596CrossRef Hirsch A (2009) Unzipping carbon nanotubes: a peeling method for the formation of graphene nanoribbons. Angew Chem Int Ed 48(36):6594–6596CrossRef
go back to reference Jiang Z, Zhu C, Wan W, Qian K, Xie J (2015) Constructing graphite-like carbon nitride modified hierarchical yolk–shell TiO2 spheres for water pollution treatment and hydrogen production. J Mater Chem A 4(5):1806–1818CrossRef Jiang Z, Zhu C, Wan W, Qian K, Xie J (2015) Constructing graphite-like carbon nitride modified hierarchical yolk–shell TiO2 spheres for water pollution treatment and hydrogen production. J Mater Chem A 4(5):1806–1818CrossRef
go back to reference Kai L, Gao S, Wang Q, Hui X, Wang Z, Huang B, Ying D, Lu J (2015) In-situ-reduced synthesis of Ti3+ self-doped TiO2/g-c3n4 heterojunctions with high photocatalytic performance under led light irradiation. ACS Appl Mater Interfaces 7(17):9023–9030CrossRef Kai L, Gao S, Wang Q, Hui X, Wang Z, Huang B, Ying D, Lu J (2015) In-situ-reduced synthesis of Ti3+ self-doped TiO2/g-c3n4 heterojunctions with high photocatalytic performance under led light irradiation. ACS Appl Mater Interfaces 7(17):9023–9030CrossRef
go back to reference Kim DW, Kim YH, Jeong HS, Jung HT (2011) Direct visualization of large-area graphene domains and boundaries by optical birefringency. Nat Nanotechnol 7(1):29–34CrossRef Kim DW, Kim YH, Jeong HS, Jung HT (2011) Direct visualization of large-area graphene domains and boundaries by optical birefringency. Nat Nanotechnol 7(1):29–34CrossRef
go back to reference Kleinfeld E, Ton-That T (2013) Novel visible light active graphitic c3n4–TiO2 composite photocatalyst: synergistic synthesis, growth and photocatalytic treatment of hazardous pollutants. Appl Catal B Environ 142–143(5):718–728 Kleinfeld E, Ton-That T (2013) Novel visible light active graphitic c3n4–TiO2 composite photocatalyst: synergistic synthesis, growth and photocatalytic treatment of hazardous pollutants. Appl Catal B Environ 142–143(5):718–728
go back to reference Li XF, Wang LL, Chen KQ, Luo Y (2011) Design of graphene-nanoribbon heterojunctions from first principles. J Phys Chem C 115(25):12616–12624CrossRef Li XF, Wang LL, Chen KQ, Luo Y (2011) Design of graphene-nanoribbon heterojunctions from first principles. J Phys Chem C 115(25):12616–12624CrossRef
go back to reference Li Q, Zhang N, Yang Y, Wang G, Ng DH (2014) High efficiency photocatalysis for pollutant degradation with mos2/c3n4 heterostructures. Langmuir the Acs Journal of Surfaces & Colloids 30(29):8965–8972CrossRef Li Q, Zhang N, Yang Y, Wang G, Ng DH (2014) High efficiency photocatalysis for pollutant degradation with mos2/c3n4 heterostructures. Langmuir the Acs Journal of Surfaces & Colloids 30(29):8965–8972CrossRef
go back to reference Liu J, Bai H, Wang Y, Liu Z, Zhang X, Sun DD (2010) Self-assembling tionanorods on large graphene oxide sheets at a two-phase interface and their anti-recombination in photocatalytic applications. Adv Funct Mater 20(23):4175–4181CrossRef Liu J, Bai H, Wang Y, Liu Z, Zhang X, Sun DD (2010) Self-assembling tionanorods on large graphene oxide sheets at a two-phase interface and their anti-recombination in photocatalytic applications. Adv Funct Mater 20(23):4175–4181CrossRef
go back to reference Liu G, Yin LC, Wang J, Niu P, Zhen C, Xie Y, Cheng HM (2012) A red anatase TiO2 photocatalyst for solar energy conversion. Energy Environ Sci 5(11):9603–9610CrossRef Liu G, Yin LC, Wang J, Niu P, Zhen C, Xie Y, Cheng HM (2012) A red anatase TiO2 photocatalyst for solar energy conversion. Energy Environ Sci 5(11):9603–9610CrossRef
go back to reference Liu J, Liu Y, Liu N, Han Y, Zhang X, Huang H, Lifshitz Y, Lee ST, Zhong J, Kang Z (2015) Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Cheminform 46(23):970–974 Liu J, Liu Y, Liu N, Han Y, Zhang X, Huang H, Lifshitz Y, Lee ST, Zhong J, Kang Z (2015) Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Cheminform 46(23):970–974
go back to reference Lu YH, Wu RQ, Shen L, Yang M, Sha ZD, Cai YQ, He PM, Feng YP (2009) Effects of edge passivation by hydrogen on electronic structure of armchair graphene nanoribbon and band gap engineering. Appl Phys Lett 94(12):491CrossRef Lu YH, Wu RQ, Shen L, Yang M, Sha ZD, Cai YQ, He PM, Feng YP (2009) Effects of edge passivation by hydrogen on electronic structure of armchair graphene nanoribbon and band gap engineering. Appl Phys Lett 94(12):491CrossRef
go back to reference Lu Q, Yu Y, Ma Q, Chen B, Zhang H (2016) 2d transition-metal-dichalcogenide-nanosheet-based composites for photocatalytic and electrocatalytic hydrogen evolution reactions. Adv Mater 28(10):1917–1933CrossRef Lu Q, Yu Y, Ma Q, Chen B, Zhang H (2016) 2d transition-metal-dichalcogenide-nanosheet-based composites for photocatalytic and electrocatalytic hydrogen evolution reactions. Adv Mater 28(10):1917–1933CrossRef
go back to reference Manga KK, Zhou Y, Yan Y, Loh KP (2010) Multilayer hybrid films consisting of alternating graphene and titania nanosheets with ultrafast electron transfer and photoconversion properties. Adv Funct Mater 19(22):3638–3643CrossRef Manga KK, Zhou Y, Yan Y, Loh KP (2010) Multilayer hybrid films consisting of alternating graphene and titania nanosheets with ultrafast electron transfer and photoconversion properties. Adv Funct Mater 19(22):3638–3643CrossRef
go back to reference Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, O'Shea K (2012) A review on the visible light active titanium dioxide photocatalysts for environmental applications. Appl Catal B Environ 125(33):331–349CrossRef Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, O'Shea K (2012) A review on the visible light active titanium dioxide photocatalysts for environmental applications. Appl Catal B Environ 125(33):331–349CrossRef
go back to reference Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, Bahnemann DW (2014) Understanding TiO2 photocatalysis: mechanisms and materials. Chem Rev 114(19):9919–9986CrossRef Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, Bahnemann DW (2014) Understanding TiO2 photocatalysis: mechanisms and materials. Chem Rev 114(19):9919–9986CrossRef
go back to reference Shah MSAS, Park AR, Zhang K, Park JH, Yoo PJ (2012) Green synthesis of biphasic TiO2-reduced graphene oxide nanocomposites with highly enhanced photocatalytic activity. ACS Appl Mater Interfaces 4(8):3893–3901CrossRef Shah MSAS, Park AR, Zhang K, Park JH, Yoo PJ (2012) Green synthesis of biphasic TiO2-reduced graphene oxide nanocomposites with highly enhanced photocatalytic activity. ACS Appl Mater Interfaces 4(8):3893–3901CrossRef
go back to reference Tao J, Luttrell T, Batzill M (2011) A two-dimensional phase of tio2 with a reduced bandgap. Nat Chem 3(4):296–300CrossRef Tao J, Luttrell T, Batzill M (2011) A two-dimensional phase of tio2 with a reduced bandgap. Nat Chem 3(4):296–300CrossRef
go back to reference Tu W, Zhou Y, Zou Z (2013) Versatile graphene-promoting photocatalytic performance of semiconductors: basic principles, synthesis, solar energy conversion, and environmental applications. Adv Funct Mater 23(40):4996–5008CrossRef Tu W, Zhou Y, Zou Z (2013) Versatile graphene-promoting photocatalytic performance of semiconductors: basic principles, synthesis, solar energy conversion, and environmental applications. Adv Funct Mater 23(40):4996–5008CrossRef
go back to reference Wan Z, Zhang G, Wu X, Yin S (2017) Novel visible-light-driven z-scheme bi12geo20/g-c3n4 photocatalyst: oxygen-induced pathway of organic pollutants degradation and proton assisted electron transfer mechanism of cr(vi) reduction. Appl Catal B Environ 207:17–26CrossRef Wan Z, Zhang G, Wu X, Yin S (2017) Novel visible-light-driven z-scheme bi12geo20/g-c3n4 photocatalyst: oxygen-induced pathway of organic pollutants degradation and proton assisted electron transfer mechanism of cr(vi) reduction. Appl Catal B Environ 207:17–26CrossRef
go back to reference Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible|[nbsp]|light. Nat Mater 8(1):76–80CrossRef Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible|[nbsp]|light. Nat Mater 8(1):76–80CrossRef
go back to reference Wang X, Blechert S, Antonietti M (2012) Polymeric graphitic carbon nitride for heterogeneous photocatalysis. ACS Catal 2(8):1596–1606CrossRef Wang X, Blechert S, Antonietti M (2012) Polymeric graphitic carbon nitride for heterogeneous photocatalysis. ACS Catal 2(8):1596–1606CrossRef
go back to reference Wang XJ, Yang WY, Li FT, Xue YB, Liu RH, Hao YJ (2013) In situ microwave-assisted synthesis of porous n-TiO2/g-c3n4 heterojunctions with enhanced visible-light photocatalytic properties. Ind Eng Chem Res 52(48):17140–17150CrossRef Wang XJ, Yang WY, Li FT, Xue YB, Liu RH, Hao YJ (2013) In situ microwave-assisted synthesis of porous n-TiO2/g-c3n4 heterojunctions with enhanced visible-light photocatalytic properties. Ind Eng Chem Res 52(48):17140–17150CrossRef
go back to reference Wang H, Zhang L, Chen Z, Hu J, Li S, Wang Z, Liu J, Wang X (2014) Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances. Cheminform 43(15):5234–5244 Wang H, Zhang L, Chen Z, Hu J, Li S, Wang Z, Liu J, Wang X (2014) Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances. Cheminform 43(15):5234–5244
go back to reference Wang S, Pan L, Song JJ, Mi W, Zou JJ, Wang L, Zhang X (2015) Titanium-defected undoped anatase TiO2 with p-type conductivity, room-temperature ferromagnetism, and remarkable photocatalytic performance. J Am Chem Soc 137(8):2975–2983CrossRef Wang S, Pan L, Song JJ, Mi W, Zou JJ, Wang L, Zhang X (2015) Titanium-defected undoped anatase TiO2 with p-type conductivity, room-temperature ferromagnetism, and remarkable photocatalytic performance. J Am Chem Soc 137(8):2975–2983CrossRef
go back to reference Williams G, Seger B, Kamat PV (2008) TiO2-graphene nanocomposites. Uv-assisted photocatalytic reduction of graphene oxide. ACS Nano 2(7):1487–1491CrossRef Williams G, Seger B, Kamat PV (2008) TiO2-graphene nanocomposites. Uv-assisted photocatalytic reduction of graphene oxide. ACS Nano 2(7):1487–1491CrossRef
go back to reference Wu JM, Zhang TW, Zeng YW, Hayakawa S, Tsuru K, Osaka A (2005) Large-scale preparation of ordered titania nanorods with enhanced photocatalytic activity. Langmuir the Acs Journal of Surfaces & Colloids 21(15):6995–7002CrossRef Wu JM, Zhang TW, Zeng YW, Hayakawa S, Tsuru K, Osaka A (2005) Large-scale preparation of ordered titania nanorods with enhanced photocatalytic activity. Langmuir the Acs Journal of Surfaces & Colloids 21(15):6995–7002CrossRef
go back to reference Xiang Q, Yu J, Jaroniec M (2011) Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/c3n4 composites. J Phys Chem C 115(15):7355–7363CrossRef Xiang Q, Yu J, Jaroniec M (2011) Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/c3n4 composites. J Phys Chem C 115(15):7355–7363CrossRef
go back to reference Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of mos2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134(15):6575–6578CrossRef Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of mos2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134(15):6575–6578CrossRef
go back to reference Xie Y, Heo SH, Yoo SH, Ali G, Cho SO (2010) Synthesis and photocatalytic activity of anatase TiO2 nanoparticles-coated carbon nanotubes. Nanoscale Res Lett 5(3):603–607CrossRef Xie Y, Heo SH, Yoo SH, Ali G, Cho SO (2010) Synthesis and photocatalytic activity of anatase TiO2 nanoparticles-coated carbon nanotubes. Nanoscale Res Lett 5(3):603–607CrossRef
go back to reference Xing M, Fang W, Yang X, Tian B, Zhang J (2014) Highly-dispersed boron-doped graphene nanoribbons with enhanced conductibility and photocatalysis. Chem Commun 50(50):6637–6640CrossRef Xing M, Fang W, Yang X, Tian B, Zhang J (2014) Highly-dispersed boron-doped graphene nanoribbons with enhanced conductibility and photocatalysis. Chem Commun 50(50):6637–6640CrossRef
go back to reference Xu M, Han L, Dong S (2013) Facile fabrication of highly efficient g-c3n4/ag2o heterostructured photocatalysts with enhanced visible-light photocatalytic activity. Appl Mater Interfaces 5(23):12533–12540CrossRef Xu M, Han L, Dong S (2013) Facile fabrication of highly efficient g-c3n4/ag2o heterostructured photocatalysts with enhanced visible-light photocatalytic activity. Appl Mater Interfaces 5(23):12533–12540CrossRef
go back to reference Xu S, Hu Y, Zheng M, Wei C (2016) Solvent-free in situ synthesis of g-c3n4/{0 0 1}TiO2 composite with enhanced uv- and visible-light photocatalytic activity for no oxidation. Appl Catal B Environ 182(5):587–597 Xu S, Hu Y, Zheng M, Wei C (2016) Solvent-free in situ synthesis of g-c3n4/{0 0 1}TiO2 composite with enhanced uv- and visible-light photocatalytic activity for no oxidation. Appl Catal B Environ 182(5):587–597
go back to reference Xue J, Ma S, Zhou Y, Wang Q (2015) Au-loaded porous graphitic c3n4/graphene layered composite as a ternary plasmonic photocatalyst and its visible-light photocatalytic performance. RSC Adv 5(107):88249–88257CrossRef Xue J, Ma S, Zhou Y, Wang Q (2015) Au-loaded porous graphitic c3n4/graphene layered composite as a ternary plasmonic photocatalyst and its visible-light photocatalytic performance. RSC Adv 5(107):88249–88257CrossRef
go back to reference Yan SC, Li ZS, Zou ZG (2009) Photodegradation performance of g-c3n4 fabricated by directly heating melamine. Langmuir 25(17):10397–10401CrossRef Yan SC, Li ZS, Zou ZG (2009) Photodegradation performance of g-c3n4 fabricated by directly heating melamine. Langmuir 25(17):10397–10401CrossRef
go back to reference Yu Y, Yu JC, Yu JG, Kwok YC, Che YK, Zhao JC, Ding L, Ge WK, Wong PK (2005) Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes. Appl Catal A Gen 289(2):186–196CrossRef Yu Y, Yu JC, Yu JG, Kwok YC, Che YK, Zhao JC, Ding L, Ge WK, Wong PK (2005) Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes. Appl Catal A Gen 289(2):186–196CrossRef
go back to reference Yu J, Low J, Xiao W, Zhou P, Jaroniec M (2014) Enhanced photocatalytic CO2-reduction activity of anatase TiO2 by coexposed {001} and {101} facets. J Am Chem Soc 136(25):8839–8842CrossRef Yu J, Low J, Xiao W, Zhou P, Jaroniec M (2014) Enhanced photocatalytic CO2-reduction activity of anatase TiO2 by coexposed {001} and {101} facets. J Am Chem Soc 136(25):8839–8842CrossRef
go back to reference Zhang H, Lv X, Li Y, Wang Y, Li J (2010) P25-graphene composite as a high performance photocatalyst. ACS Nano 4(1):380–386CrossRef Zhang H, Lv X, Li Y, Wang Y, Li J (2010) P25-graphene composite as a high performance photocatalyst. ACS Nano 4(1):380–386CrossRef
go back to reference Zhang N, Zhang Y, Xu YJ (2012) Recent progress on graphene-based photocatalysts: current status and future perspectives. Nanoscale 4(19):5792–5813CrossRef Zhang N, Zhang Y, Xu YJ (2012) Recent progress on graphene-based photocatalysts: current status and future perspectives. Nanoscale 4(19):5792–5813CrossRef
go back to reference Zhang G, Zhang M, Ye X, Qiu X, Lin S, Wang X (2014) Iodine modified carbon nitride semiconductors as visible light photocatalysts for hydrogen evolution. Adv Mater 26(5):805–809CrossRef Zhang G, Zhang M, Ye X, Qiu X, Lin S, Wang X (2014) Iodine modified carbon nitride semiconductors as visible light photocatalysts for hydrogen evolution. Adv Mater 26(5):805–809CrossRef
go back to reference Zhao W, Ma W, Chen C, Zhao J, Shuai Z (2004) Efficient degradation of toxic organic pollutants with ni2o3/tio(2-x)bx under visible irradiation. J Am Chem Soc 126(15):4782–4783CrossRef Zhao W, Ma W, Chen C, Zhao J, Shuai Z (2004) Efficient degradation of toxic organic pollutants with ni2o3/tio(2-x)bx under visible irradiation. J Am Chem Soc 126(15):4782–4783CrossRef
go back to reference Zheng Y, Liu J, Liang J, Jaroniec M, Qiao SZ (2012) Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy Environ Sci 5(5):6717–6731CrossRef Zheng Y, Liu J, Liang J, Jaroniec M, Qiao SZ (2012) Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy Environ Sci 5(5):6717–6731CrossRef
go back to reference Zheng Y, Lin L, Ye X, Guo F, Wang X (2014) Helical graphitic carbon nitrides with photocatalytic and optical activities. Angew Chem Int Ed 53(44):11926–11930CrossRef Zheng Y, Lin L, Ye X, Guo F, Wang X (2014) Helical graphitic carbon nitrides with photocatalytic and optical activities. Angew Chem Int Ed 53(44):11926–11930CrossRef
go back to reference Zhou W, Hong L, Wang J, Liu D, Du G, Cui J (2010) Ag2o/TiO2 nanobelts heterostructure with enhanced ultraviolet and visible photocatalytic activity. ACS Appl Mater Interfaces 2(8):2385–2392CrossRef Zhou W, Hong L, Wang J, Liu D, Du G, Cui J (2010) Ag2o/TiO2 nanobelts heterostructure with enhanced ultraviolet and visible photocatalytic activity. ACS Appl Mater Interfaces 2(8):2385–2392CrossRef
go back to reference Zhu YP, Ren TZ, Yuan ZY (2015) Mesoporous phosphorus-doped g-c3n4 nanostructured flowers with superior photocatalytic hydrogen evolution performance. ACS Appl Mater Interfaces 7(30):16850–16856CrossRef Zhu YP, Ren TZ, Yuan ZY (2015) Mesoporous phosphorus-doped g-c3n4 nanostructured flowers with superior photocatalytic hydrogen evolution performance. ACS Appl Mater Interfaces 7(30):16850–16856CrossRef
go back to reference Zhu Z, Lu Z, Wang D, Tang X, Yan Y, Shi W, Wang Y, Gao N, Yao X, Dong H (2016) Construction of high-dispersed ag/fe3o4/g-c3n4 photocatalyst by selective photo-deposition and improved photocatalytic activity. Appl Catal B Environ 182:115–122CrossRef Zhu Z, Lu Z, Wang D, Tang X, Yan Y, Shi W, Wang Y, Gao N, Yao X, Dong H (2016) Construction of high-dispersed ag/fe3o4/g-c3n4 photocatalyst by selective photo-deposition and improved photocatalytic activity. Appl Catal B Environ 182:115–122CrossRef
Metadata
Title
The synthesis of graphene-TiO2/g-C3N4 super-thin heterojunctions with enhanced visible-light photocatalytic activities
Authors
Shuaiqi Gong
Zhengjun Jiang
Sheng Zhu
Jinchen Fan
Qunjie Xu
Yulin Min
Publication date
01-11-2018
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 11/2018
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-018-4399-8

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