Skip to main content
Top
Published in: Journal of Materials Science 24/2015

01-12-2015 | Original Paper

In-plane mechanical properties of carbon nanotube films fabricated by floating catalyst chemical vapor decomposition

Authors: Fujun Xu, Baochun Wei, Wei Liu, Hongfei Zhu, Yongyi Zhang, Yiping Qiu

Published in: Journal of Materials Science | Issue 24/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Large-scale carbon nanotube (CNT) films fabricated by floating catalyst chemical vapor deposition (FCCVD) are promising reinforcement materials for high performance composites. However, little research has been reported on the four independent in-plane engineering constants of FCCVD CNT films, which are essential for understanding and prediction of mechanical behavior of FCCVD CNT film-based structures. The tensile strength in CNT-oriented direction is 127 MPa and the tensile modulus in oriented and transverse directions are 3.0 and 0.3 GPa, respectively. These mechanical properties are mainly attributed to the as-grown CNT-to-CNT contacts in the films. The Poisson’s ratio in the oriented direction at 5 % strain is 0.75. A negative Poisson’s ratio of −0.99 is observed at 0.1 % strain in CNT-oriented direction. The in-plane shear modulus is 0.57 GPa, which is derived from the coordinate transformation between the on-axis and 45° off-axis compliance matrices. The in-situ scanning electron microscopy is adopted to observe the microstructure at different tensile strains. During the tensile testing, the reorientation of CNT bundles in CNT film is evaluated by numerical image processing and Raman spectroscopy.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef
2.
go back to reference De Volder MFL, Tawfick SH, Baughman RH, Hart AJ (2013) Carbon nanotubes: present and future commercial applications. Science 339:535–539CrossRef De Volder MFL, Tawfick SH, Baughman RH, Hart AJ (2013) Carbon nanotubes: present and future commercial applications. Science 339:535–539CrossRef
3.
go back to reference Jung Y, Kim T, Park CR (2015) Effect of polymer infiltration on structure and properties of carbon nanotube yarns. Carbon 88:60–69CrossRef Jung Y, Kim T, Park CR (2015) Effect of polymer infiltration on structure and properties of carbon nanotube yarns. Carbon 88:60–69CrossRef
4.
go back to reference Parikh K, Cattanach K, Rao R, Suh DS, Wu A, Manohar SK (2006) Flexible vapour sensors using single walled carbon nanotubes. Sens Actuators B 113:55–63CrossRef Parikh K, Cattanach K, Rao R, Suh DS, Wu A, Manohar SK (2006) Flexible vapour sensors using single walled carbon nanotubes. Sens Actuators B 113:55–63CrossRef
5.
go back to reference Wang Y, Yang Z, Hou Z, Xu D, Wei L, Kong ESW et al (2010) Flexible gas sensors with assembled carbon nanotube thin films for DMMP vapor detection. Sens Actuators B Chem 150:708–714CrossRef Wang Y, Yang Z, Hou Z, Xu D, Wei L, Kong ESW et al (2010) Flexible gas sensors with assembled carbon nanotube thin films for DMMP vapor detection. Sens Actuators B Chem 150:708–714CrossRef
6.
go back to reference Li Z, Dharap P, Nagarajaiah S, Barrera EV, Kim JD (2004) Carbon nanotube film sensors. Adv Mater 16:640–643CrossRef Li Z, Dharap P, Nagarajaiah S, Barrera EV, Kim JD (2004) Carbon nanotube film sensors. Adv Mater 16:640–643CrossRef
7.
go back to reference Coleman JN, Khan U, Blau WJ, Gun’ko YK (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44:1624–1652CrossRef Coleman JN, Khan U, Blau WJ, Gun’ko YK (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44:1624–1652CrossRef
8.
go back to reference Rinzler A, Liu J, Dai H, Nikolaev P, Huffman C, Rodriguez-Macias F et al (1998) Large-scale purification of single-wall carbon nanotubes: process, product, and characterization. Appl Phys A Mater Sci Process 67:29–37CrossRef Rinzler A, Liu J, Dai H, Nikolaev P, Huffman C, Rodriguez-Macias F et al (1998) Large-scale purification of single-wall carbon nanotubes: process, product, and characterization. Appl Phys A Mater Sci Process 67:29–37CrossRef
9.
go back to reference Jiang Q, Li Y, Xie J, Sun J, Hui D, Qiu Y (2013) Plasma functionalization of bucky paper and its composite with phenylethynyl-terminated polyimide. Compos B Eng 45:1275–1281CrossRef Jiang Q, Li Y, Xie J, Sun J, Hui D, Qiu Y (2013) Plasma functionalization of bucky paper and its composite with phenylethynyl-terminated polyimide. Compos B Eng 45:1275–1281CrossRef
10.
go back to reference Jiang Q, Wang X, Zhu Y, Hui D, Qiu Y (2014) Mechanical, electrical and thermal properties of aligned carbon nanotube/polyimide composites. Compos B Eng 56:408–412CrossRef Jiang Q, Wang X, Zhu Y, Hui D, Qiu Y (2014) Mechanical, electrical and thermal properties of aligned carbon nanotube/polyimide composites. Compos B Eng 56:408–412CrossRef
11.
go back to reference Oh JY, Yang SJ, Park JY, Kim T, Lee K, Kim YS et al (2014) Easy preparation of self-assembled high-density buckypaper with enhanced mechanical properties. Nano Lett 15:190–197CrossRef Oh JY, Yang SJ, Park JY, Kim T, Lee K, Kim YS et al (2014) Easy preparation of self-assembled high-density buckypaper with enhanced mechanical properties. Nano Lett 15:190–197CrossRef
12.
go back to reference Zhang M, Fang S, Zakhidov AA, Lee SB, Aliev AE, Williams CD et al (2005) Materials science: strong, transparent, multifunctional, carbon nanotube sheets. Science 309:1215–1219CrossRef Zhang M, Fang S, Zakhidov AA, Lee SB, Aliev AE, Williams CD et al (2005) Materials science: strong, transparent, multifunctional, carbon nanotube sheets. Science 309:1215–1219CrossRef
13.
go back to reference Liu W, Zhao H, Yong Z, Xu G, Wang X, Xu F et al (2013) Improving mechanical and electrical properties of oriented polymer-free multi-walled carbon nanotube paper by spraying while winding. Compos B Eng 53:342–346CrossRef Liu W, Zhao H, Yong Z, Xu G, Wang X, Xu F et al (2013) Improving mechanical and electrical properties of oriented polymer-free multi-walled carbon nanotube paper by spraying while winding. Compos B Eng 53:342–346CrossRef
14.
go back to reference Zhang L, Zhang G, Liu C, Fan S (2012) High-density carbon nanotube buckypapers with superior transport and mechanical properties. Nano Lett 12:4848–4852CrossRef Zhang L, Zhang G, Liu C, Fan S (2012) High-density carbon nanotube buckypapers with superior transport and mechanical properties. Nano Lett 12:4848–4852CrossRef
15.
go back to reference Song L, Ci L, Lv L, Zhou Z, Yan X, Liu D et al (2004) Direct synthesis of a macroscale single-walled carbon nanotube non-woven material. Adv Mater 16:1529–1534CrossRef Song L, Ci L, Lv L, Zhou Z, Yan X, Liu D et al (2004) Direct synthesis of a macroscale single-walled carbon nanotube non-woven material. Adv Mater 16:1529–1534CrossRef
16.
go back to reference Zhang X (2008) Hydroentangling: a novel approach to high-speed fabrication of carbon nanotube membranes. Adv Mater 20:4140–4144 Zhang X (2008) Hydroentangling: a novel approach to high-speed fabrication of carbon nanotube membranes. Adv Mater 20:4140–4144
17.
go back to reference Rigueur JL,Hasan SA, Mahajan SV, Dickerson JH (2010) Buckypaper fabrication by liberation of electrophoretically deposited carbon nanotubes. Carbon 48:4090–4099, 11 Rigueur JL,Hasan SA, Mahajan SV, Dickerson JH (2010) Buckypaper fabrication by liberation of electrophoretically deposited carbon nanotubes. Carbon 48:4090–4099, 11
18.
go back to reference Nasibulin AG, Kaskela A, Mustonen K, Anisimov AS, Ruiz V, Kivistö S et al (2011) Multifunctional free-standing single-walled carbon nanotube films. ACS Nano 5:3214–3221CrossRef Nasibulin AG, Kaskela A, Mustonen K, Anisimov AS, Ruiz V, Kivistö S et al (2011) Multifunctional free-standing single-walled carbon nanotube films. ACS Nano 5:3214–3221CrossRef
19.
go back to reference Liu L, Ma W, Zhang Z (2011) Macroscopic carbon nanotube assemblies: preparation, properties, and potential applications. Small 7:1504–1520CrossRef Liu L, Ma W, Zhang Z (2011) Macroscopic carbon nanotube assemblies: preparation, properties, and potential applications. Small 7:1504–1520CrossRef
20.
go back to reference Gay D (2014) Mechanical behavior of laminated materials Composite materials: design and applications, 3rd edn. CRC press, Boca Raton Gay D (2014) Mechanical behavior of laminated materials Composite materials: design and applications, 3rd edn. CRC press, Boca Raton
21.
go back to reference Kaw AK (2010) Macromechanical analysis of a lamina. In: Mechanics of composite materials, 2nd edn. CRC press, Boca Raton Kaw AK (2010) Macromechanical analysis of a lamina. In: Mechanics of composite materials, 2nd edn. CRC press, Boca Raton
22.
go back to reference Blighe FM, Lyons PE, De S, Blau WJ, Coleman JN (2008) On the factors controlling the mechanical properties of nanotube films. Carbon 46:41–47CrossRef Blighe FM, Lyons PE, De S, Blau WJ, Coleman JN (2008) On the factors controlling the mechanical properties of nanotube films. Carbon 46:41–47CrossRef
23.
go back to reference Ting JM, Chang CC (2002) Multijunction carbon nanotube network. Appl Phys Lett 80:324–325CrossRef Ting JM, Chang CC (2002) Multijunction carbon nanotube network. Appl Phys Lett 80:324–325CrossRef
24.
go back to reference Pourhabib A, Huang JZ, Wang K, Zhang C, Wang B, Ding Y (2015) Modulus prediction of buckypaper based on multi-fidelity analysis involving latent variables. IIE Trans 47:141–152CrossRef Pourhabib A, Huang JZ, Wang K, Zhang C, Wang B, Ding Y (2015) Modulus prediction of buckypaper based on multi-fidelity analysis involving latent variables. IIE Trans 47:141–152CrossRef
25.
go back to reference Hwang J, Gommans H, Ugawa A, Tashiro H, Haggenmueller R, Winey KI et al (2000) Polarized spectroscopy of aligned single-wall carbon nanotubes. Phys Rev B 62:R13310CrossRef Hwang J, Gommans H, Ugawa A, Tashiro H, Haggenmueller R, Winey KI et al (2000) Polarized spectroscopy of aligned single-wall carbon nanotubes. Phys Rev B 62:R13310CrossRef
26.
go back to reference Lu Q, Keskar G, Ciocan R, Rao R, Mathur RB, Rao AM et al (2006) Determination of carbon nanotube density by gradient sedimentation. J Phys Chem B 110:24371–24376CrossRef Lu Q, Keskar G, Ciocan R, Rao R, Mathur RB, Rao AM et al (2006) Determination of carbon nanotube density by gradient sedimentation. J Phys Chem B 110:24371–24376CrossRef
27.
go back to reference Miao M (2011) Electrical conductivity of pure carbon nanotube yarns. Carbon 49:3755–3761CrossRef Miao M (2011) Electrical conductivity of pure carbon nanotube yarns. Carbon 49:3755–3761CrossRef
28.
go back to reference Špitalský Z, Aggelopoulos C, Tsoukleri G, Tsakiroglou C, Parthenios J, Georga S et al (2009) The effect of oxidation treatment on the properties of multi-walled carbon nanotube thin films. Mater Sci Eng B 165:135–138CrossRef Špitalský Z, Aggelopoulos C, Tsoukleri G, Tsakiroglou C, Parthenios J, Georga S et al (2009) The effect of oxidation treatment on the properties of multi-walled carbon nanotube thin films. Mater Sci Eng B 165:135–138CrossRef
29.
go back to reference Hahn HT, Tsai SW (1980) Off-axis stiffness of unidirectional composites in introduction to composite materials, vol 1. CRC Press, 109, p 65 Hahn HT, Tsai SW (1980) Off-axis stiffness of unidirectional composites in introduction to composite materials, vol 1. CRC Press, 109, p 65
30.
go back to reference Coleman JN, Blau WJ, Dalton AB, Muñoz E, Collins S, Kim BG et al (2003) Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives. Appl Phys Lett 82:1682–1684CrossRef Coleman JN, Blau WJ, Dalton AB, Muñoz E, Collins S, Kim BG et al (2003) Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives. Appl Phys Lett 82:1682–1684CrossRef
31.
go back to reference Wang S, Liang Z, Wang B, Zhang C (2007) High-strength and multifunctional macroscopic fabric of single-walled carbon nanotubes. Adv Mater 19:1257–1261CrossRef Wang S, Liang Z, Wang B, Zhang C (2007) High-strength and multifunctional macroscopic fabric of single-walled carbon nanotubes. Adv Mater 19:1257–1261CrossRef
32.
go back to reference Ma W, Song L, Yang R, Zhang T, Zhao Y, Sun L et al (2007) Directly synthesized strong, highly conducting, transparent single-walled carbon nanotube films. Nano Lett 7:2307–2311CrossRef Ma W, Song L, Yang R, Zhang T, Zhao Y, Sun L et al (2007) Directly synthesized strong, highly conducting, transparent single-walled carbon nanotube films. Nano Lett 7:2307–2311CrossRef
33.
go back to reference Bradford PD, Wang X, Zhao H, Maria J-P, Jia Q, Zhu Y (2010) A novel approach to fabricate high volume fraction nanocomposites with long aligned carbon nanotubes. Compos Sci Technol 70:1980–1985CrossRef Bradford PD, Wang X, Zhao H, Maria J-P, Jia Q, Zhu Y (2010) A novel approach to fabricate high volume fraction nanocomposites with long aligned carbon nanotubes. Compos Sci Technol 70:1980–1985CrossRef
34.
go back to reference Inoue Y, Suzuki Y, Minami Y, Muramatsu J, Shimamura Y, Suzuki K et al (2011) Anisotropic carbon nanotube papers fabricated from multiwalled carbon nanotube webs. Carbon 49:2437–2443CrossRef Inoue Y, Suzuki Y, Minami Y, Muramatsu J, Shimamura Y, Suzuki K et al (2011) Anisotropic carbon nanotube papers fabricated from multiwalled carbon nanotube webs. Carbon 49:2437–2443CrossRef
35.
go back to reference Green MJ, Behabtu N, Pasquali M, Adams WW (2009) Nanotubes as polymers. Polymer 50:4979–4997CrossRef Green MJ, Behabtu N, Pasquali M, Adams WW (2009) Nanotubes as polymers. Polymer 50:4979–4997CrossRef
36.
go back to reference Baughman RH, Stafström S, Cui C, Dantas SO (1998) Materials with negative compressibilities in one or more dimensions. Science 279:1522–1524CrossRef Baughman RH, Stafström S, Cui C, Dantas SO (1998) Materials with negative compressibilities in one or more dimensions. Science 279:1522–1524CrossRef
37.
go back to reference Chen L, Liu C, Wang J, Zhang W, Hu C, Fan S (2009) Auxetic materials with large negative Poisson’s ratios based on highly oriented carbon nanotube structures. Appl Phys Lett 94:253111CrossRef Chen L, Liu C, Wang J, Zhang W, Hu C, Fan S (2009) Auxetic materials with large negative Poisson’s ratios based on highly oriented carbon nanotube structures. Appl Phys Lett 94:253111CrossRef
38.
go back to reference Ma YJ, Yao XF, Zheng QS, Yin YJ, Jiang DJ, Xu GH et al (2010) Carbon nanotube films change Poisson’s ratios from negative to positive. Appl Phys Lett 97:061909CrossRef Ma YJ, Yao XF, Zheng QS, Yin YJ, Jiang DJ, Xu GH et al (2010) Carbon nanotube films change Poisson’s ratios from negative to positive. Appl Phys Lett 97:061909CrossRef
Metadata
Title
In-plane mechanical properties of carbon nanotube films fabricated by floating catalyst chemical vapor decomposition
Authors
Fujun Xu
Baochun Wei
Wei Liu
Hongfei Zhu
Yongyi Zhang
Yiping Qiu
Publication date
01-12-2015
Publisher
Springer US
Published in
Journal of Materials Science / Issue 24/2015
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9395-0

Other articles of this Issue 24/2015

Journal of Materials Science 24/2015 Go to the issue

Premium Partners