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Rheologica Acta

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24-07-2023 | Original Contribution

Influence of dispersion liquid and silica concentration on rheological properties of shear thickening fluids (STFs)

Authors: Abdulhalim Aşkan, Mahmut Çapkurt, Emre Acar, Murat Aydın

Published in: Rheologica Acta | Issue 9/2023

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Abstract

The rheological behavior of shear thickening fluid suspensions synthesized using three dispersion liquids, namely polyethylene glycol, glycerin, and diethylene glycol, having different numbers of hydroxyl groups at the ends of the chain and distinct chain lengths, was researched. The primary objective of this study is to investigate the effects of the length of the chain molecular, the number of –OH groups at the ends of the chain, and the density of dispersion liquids on the rheological behavior. Evaluations were made by taking into account the thickening ratio which expresses the maximum change in the viscosity of the fluid relative to the initial viscosity and the thickening period which states the difference between the shear rate at which the maximum viscosity is obtained and the critical shear rate. As a result of the evaluation made by considering these parameters, the rheological performance of shear thickening fluid suspensions synthesized with liquids having longer molecular chain lengths, higher –OH number, and higher density came to the fore. Samples synthesized with glycerin, which have more hydroxyl groups at the molecular chain ends, provided a more stable distribution by making stronger hydrogen bonds with silica. This situation significantly reduced the thinning behavior in the first region of the rheology curves and provided a stable and continuous thickening behavior after the critical shear rate. In addition, with the increase in the silica ratio, the thickening situation changed from continuous to discontinuous. Increment of silica also decreased the critical shear rate while increasing the initial and maximum viscosity. Increasing the silica content from 22 to 26% resulted in the thickening ratio increasing by 686% from 6.6 to 45 in the samples synthesized with polyethylene glycol while decreasing the thickening period from 559 to 41.2. Similar situations are observed in the samples synthesized with glycerin and diethylene glycol. All of the samples obtained exhibited a reversible behavior rheologically. When the applied shear rate was removed, the sample returned to its former fluid state. Moreover, suspensions synthesized by mixing dispersion liquids showed superior performance compared to single-liquid samples. It is thought that the dispersion liquids interact to form a branched network by making more bonds both with each other and with the silica particles, and it provides an increase in the resistance of the fluid against deformation under high shear stress.

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Antosik A, Gluszek M, Zurowski R, Szafran M (2017) Influence of carrier fluid on the electrokinetic and rheological properties of shear thickening fluids. Ceram Int 43(15):12293–12301. https://doi.org/10.1016/j.ceramint.2017.06.092CrossRef

Arora S, Majumdar A, Butola BS (2020) Soft armour design by angular stacking of shear thickening fluid impregnated high-performance fabrics for quasi-isotropic ballistic response. Composite Structures 233(October 2019):111720. https://doi.org/10.1016/j.compstruct.2019.111720CrossRef

Baharvandi HR, Alebooyeh M, Alizadeh M, Heydari MS, Kordani N, Khaksari P (2016) The influences of particle–particle interaction and viscosity of carrier fluid on characteristics of silica and calcium carbonate suspensions-coated Twaron® composite. J Exp Nanosci 11(7):550–563. https://doi.org/10.1080/17458080.2015.1094190CrossRef

Boersma WH, Laven J, Stein HN (1992) Viscoelastic properties of concentrated shear-thickening dispersions. J Colloid Interf Sci 149(1):10–22. https://doi.org/10.1016/0021-9797(92)90385-YCrossRef

Bossis G, Brady JF (1989) The rheology of Brownian suspensions. J Chem Phys 91(3):1866–1874. https://doi.org/10.1063/1.457091CrossRef

Brady JF, Bossis G (1985) The rheology of concentrated suspensions of spheres in simple shear flow by numerical simulation. J Fluid Mech 155:105–129. https://doi.org/10.1017/S0022112085001732CrossRef

Brown E, Jaeger HM (2014) Shear thickening in concentrated suspensions: phenomenology, mechanisms and relations to jamming. Rep Progr Phys 77(4):046602. https://doi.org/10.1088/0034-4885/77/4/046602CrossRef

Büyüksırıt T, Kuleaşan H (2014) Fourier Dönüşümlü Kizilötesi (FTIR) Spektroskopisi ve Gıda Analizlerinde Kullanımı. Gıda 39(4):235–241. https://doi.org/10.5505/gida.43434CrossRef

Chen Y, Li X, Zeng G, Liu W (2015) The influence of continuous shear, shear history and relaxation on the rheological behavior of SiO2/glycerine suspensions. Appl Rheol 25(4):1–9. https://doi.org/10.3933/APPLRHEOL-25-44806CrossRef

Cheng X, McCoy JH, Israelachvili JN, Cohen I (2011) Imaging the microscopic structure of shear thinning and thickening colloidal suspensions. Science 333(6047):1276–1279. https://doi.org/10.1126/science.1207032CrossRef

Chu B, Brady AT, Mannhalter BD, Salem DR (2014) Effect of silica particle surface chemistry on the shear thickening behaviour of concentrated colloidal suspensions. J Phys D: Appl Phys 47(33):335302. https://doi.org/10.1088/0022-3727/47/33/335302CrossRef

Cwalina CD, Dombrowski RD, McCutcheon CJ, Christiansen EL, Wagner NJ (2015) MMOD puncture resistance of EVA suits with shear thickening fluid (STF) - Armortm absorber layers. Proc Eng 103:97–104. https://doi.org/10.1016/j.proeng.2015.04.014CrossRef

Ding J, Tian T, Meng Q, Guo Z, Li W, Zhang P, Ciacchi FT, Huang J, Yang W (2013) Smart multifunctional fluids for lithium ion batteries: enhanced rate performance and intrinsic mechanical protection. Sci Rep 3:1–7. https://doi.org/10.1038/srep02485CrossRef

Fischer C, Bennani A, Michaud V, Jacquelin E, Månson JAE (2010) Structural damping of model sandwich structures using tailored shear thickening fluid compositions. Smart Mater Struct 19(3):035017. https://doi.org/10.1088/0964-1726/19/3/035017CrossRef

Galindo-Rosales FJ, Rubio-Hernandez FJ (2010) Static and dynamic yield stresses of aerosil® 200 suspensionsin polypropylene glycol. Appl Rheol 20(2):1–10. https://doi.org/10.3933/ApplRheol-20-22787CrossRef

Ghosh A, Majumdar A, Butola BS (2020) Modulating the rheological response of shear thickening fluids by variation in molecular weight of carrier fluid and its correlation with impact resistance of treated p-aramid fabrics. Polymer Testing 91(August):106830. https://doi.org/10.1016/j.polymertesting.2020.106830CrossRef

Ghosh A, Majumdar A, Butola BS (2020) Rheometry of novel shear thickening fluid and its application for improving the impact energy absorption of p-aramid fabric. Thin-Walled Structures 155(March):106954. https://doi.org/10.1016/j.tws.2020.106954CrossRef

Gürgen S (2017) Kayma altında katılaşan sıvı takviyeli zırh kumaşının seramik toz katkıları ile özelliklerinin geliştirilmesi. Ph.D. Thesis, Thesis No. 491693, In Graduate School of Natural and Applied Sciences, Eskişehir Osmangazi University, Turkey

Gürgen S, Kuşhan MC (2017) The stab resistance of fabrics impregnated with shear thickening fluids including various particle size of additives. Compos A Appl Sci Manuf 94:50–60. https://doi.org/10.1016/j.compositesa.2016.12.019CrossRef

Hasanzadeh M, Mottaghitalab V (2014) The role of shear-thickening fluids (STFs) in ballistic and stab-resistance improvement of flexible armor. J Mater Eng Perform 23(4):1182–1196. https://doi.org/10.1007/s11665-014-0870-6CrossRef

Hassan TA, Rangari VK, Jeelani S (2010) Synthesis, processing and characterization of shear thickening fluid (STF) impregnated fabric composites. Mater Sci Eng, A 527(12):2892–2899. https://doi.org/10.1016/j.msea.2010.01.018CrossRef

Hayes WC, Robinovitch SN, McMahon TA (1997) Bone fracture prevention garment and method. US Patent 5599290. https://patents.google.com/patent/US5599290A/en

Heussinger C (2013) Shear thickening in granular suspensions: interparticle friction and dynamically correlated clusters. Phys Rev E Stat Nonlinear Soft Matter Phys 88(5):22–24. https://doi.org/10.1103/PhysRevE.88.050201CrossRef

Hoffman RL (1972) Discontinuous and dilatant viscosity behavior in concentrated suspensions I. Observation of a flow instability. Trans Soc Rheol 16(1):155–173. https://doi.org/10.1122/1.549250CrossRef

Hoffman RL (1973) Discontinuous and dilatant viscosity behavior in concentrated suspensions II. Theory and experimental tests. J Colloid Interf Sci 46(3):491–506. https://doi.org/10.1016/0021-9797(74)90059-9CrossRef

Jiang W, Ye F, He Q, Gong X, Feng J, Lu L, Xuan S (2014) Study of the particles’ structure dependent rheological behavior for polymer nanospheres based shear thickening fluid. J Colloid Interf Sci 413:8–16. https://doi.org/10.1016/j.jcis.2013.09.020CrossRef

Kang TJ, Kim CY, Hong KH (2010) Rheological behavior of concentrated silica suspension and its application to Soft Armor. J Appl Polym Sci 116(5):2658–2667. https://doi.org/10.1002/app.34843CrossRef

Kenneth DS, Manes E (2016) Landing gear systems having shear-thickening and shear-thinning fluid responses. US Patent US9453550B2. https://patents.google.com/patent/US9453550B2/en

Khodadadi A, Liaghat G, Vahid S, Sabet AR, Hadavinia H (2019) Ballistic performance of Kevlar fabric impregnated with nanosilica/PEG shear thickening fluid. Composites Part B: Engineering 162(March 2018):643–652. https://doi.org/10.1016/j.compositesb.2018.12.121CrossRef

Kim SY, Meyer HW, Saalwächter K, Zukoski CF (2012) Polymer dynamics in PEG-silica nanocomposites: effects of polymer molecular weight, temperature and solvent dilution. Macromolecules 45(10):4225–4237. https://doi.org/10.1021/ma300439kCrossRef

Kim SY, Schweizer KS, Zukoski CF (2011) Multiscale structure, interfacial cohesion, adsorbed layers, and thermodynamics in dense polymer-nanoparticle mixtures. Phys Rev Lett 107(22):1–5. https://doi.org/10.1103/PhysRevLett.107.225504CrossRef

Korn M, Killmann E, Eisenlauer J (1980) Infrared and microcalorimetric studies of the adsorption of monofunctional ketones, esters, ethers, and alcohols at the silica/carbon tetrachloride interface. J Colloid Interf Sci 76(1):7–18. https://doi.org/10.1016/0021-9797(80)90266-0CrossRef

Lammer H, Rosenkranz H, Kotze J, Schwenger R (2012) System and method of using shear thickening materials in sports products. US Patent US8105184B2. https://patents.google.com/patent/US8105184B2/en

Lee YS, Wetzel ED, Wagner NJ (2003) The ballistic impact characteristics of Kevlar® woven fabrics impregnated with a colloidal shear thickening fluid. J Mater Sci 38(13):2825–2833. https://doi.org/10.1023/A:1024424200221CrossRef

Li D, Wang R, Liu X, Zhang S, Fang S, Yan R (2020) Effect of dispersing media and temperature on inter-yarn frictional properties of Kevlar fabrics impregnated with shear thickening fluid. Composite Structures 249(May):112557. https://doi.org/10.1016/j.compstruct.2020.112557CrossRef

Li S, Wang J, Cai W, Zhao S, Wang Z, Wang S (2016a) Effect of acid and temperature on the discontinuous shear thickening phenomenon of silica nanoparticle suspensions. Chem Phys Lett 658:210–214. https://doi.org/10.1016/j.cplett.2016.06.055CrossRef

Li W, Xiong D, Zhao X, Sun L, Liu J (2016b) Dynamic stab resistance of ultra-high molecular weight polyethylene fabric impregnated with shear thickening fluid. Mater Des 102:162–167. https://doi.org/10.1016/j.matdes.2016.04.006CrossRef

Lin NYC, Guy BM, Hermes M, Ness C, Sun J, Poon WCK, Cohen I (2015) Hydrodynamic and contact contributions to continuous shear thickening in colloidal suspensions. Phys Rev Lett 115(22):1–5. https://doi.org/10.1103/PhysRevLett.115.228304CrossRef

Lin SY, Wang SL (2012) Advances in simultaneous DSC-FTIR microspectroscopy for rapid solid-state chemical stability studies: some dipeptide drugs as examples. Adv Drug Deliv Rev 64(5):461–478. https://doi.org/10.1016/j.addr.2012.01.009CrossRef

Liu L, Cai M, Liu X, Zhao Z, Chen W (2020) Ballistic impact performance of multi-phase STF-impregnated Kevlar fabrics in aero-engine containment. Thin-Walled Struct 157(29):107103. https://doi.org/10.1016/j.tws.2020.107103CrossRef

Liu L, Yang Z, Zhao Z, Liu X, Chen W (2020) The influences of rheological property on the impact performance of kevlar fabrics impregnated with SiO2/PEG shear thickening fluid. Thin-Walled Structures 151(29):106717. https://doi.org/10.1016/j.tws.2020.106717CrossRef

Liu XQ, Bao RY, Wu XJ, Yang W, Xie BH, Yang MB (2015) Temperature induced gelation transition of a fumed silica/PEG shear thickening fluid. RSC Adv 5(24):18367–18374. https://doi.org/10.1039/c4ra16261gCrossRef

Manukonda BH, Chatterjee VA, Verma SK, Bhattacharjee D, Biswas I, Neogi S (2020) Rheology based design of shear thickening fluid for soft body armor applications. Periodica Polytech, Chem Eng 64(1):75–84. https://doi.org/10.3311/PPch.13626CrossRef

Mawkhlieng U, Majumdar A (2019) Deconstructing the role of shear thickening fluid in enhancing the impact resistance of high-performance fabrics. Composites Part B: Engineering 175(June):107167. https://doi.org/10.1016/j.compositesb.2019.107167CrossRef

Mishra VD, Mishra A, Singh A, Verma L, Rajesh G (2022) Ballistic impact performance of UHMWP fabric impregnated with shear thickening fluid nanocomposite. Composite Structures 281(June 2021):114991. https://doi.org/10.1016/j.compstruct.2021.114991CrossRef

Nakonieczna P, Wierzbicki Ł, Wróblewski R, Płociński T, Leonowicz M (2019) The influence of carbon nanotube addition on the properties of shear thickening fluid. Bull Mater Sci 42(4):2–5. https://doi.org/10.1007/s12034-019-1860-yCrossRef

Orawiec M, Kaczorowski M, Rokicki G (2018) Dilatant effect enhancers for silica dispersions in poly(propylene glycols). J Colloid Interf Sci 528:301–308. https://doi.org/10.1016/j.jcis.2018.05.097CrossRef

Parida SK, Dash S, Patel S, Mishra BK (2006) Adsorption of organic molecules on silica surface. Adv Coll Interf Sci 121(1–3):77–110. https://doi.org/10.1016/j.cis.2006.05.028CrossRef

Park JL, Yoon B il, Paik JG, Kang TJ (2012) Ballistic performance of p-aramid fabrics impregnated with shear thickening fluid; Part I – effect of laminating sequence. Textile Res J 82(6):527–541. https://doi.org/10.1177/0040517511420753CrossRef

Pinto F, Meo M (2017) Design and manufacturing of a novel shear thickening fluid composite (STFC) with enhanced out-of-plane properties and damage suppression. Appl Compos Mater 24(3):643–660. https://doi.org/10.1007/s10443-016-9532-1CrossRef

Qin J, Guo B, Zhang L, Wang T, Zhang G, Shi X (2020) Soft armor materials constructed with Kevlar fabric and a novel shear thickening fluid. Composites Part B: Engineering 183(October 2019):107686. https://doi.org/10.1016/j.compositesb.2019.107686CrossRef

Raghavan SR, Khan SA (1997) Shear-thickening response of fumed silica suspensions under steady and oscillatory shear. J Colloid Interf Sci 185(1):57–67. https://doi.org/10.1006/jcis.1996.4581CrossRef

Raghavan SR, Walls HJ, Khan SA (2000) Rheology of silica dispersions in organic liquids: new evidence for solvation forces dictated by hydrogen bonding. Langmuir 16(21):7920–7930. https://doi.org/10.1021/la991548qCrossRef

Holt SE, Perez MP (2014) Impact resistant, torsion-reducing protective athletic gear using shear thickening fluid. US Patent US8679047B2. https://patents.google.com/patent/US8679047B2/en

Sahoo SK, Mishra S, Islam E, Nebhani L (2020) Tuning shear thickening behavior via synthesis of organically modified silica to improve impact resistance of Kevlar fabric. Mater Today Commun 23(January):100892. https://doi.org/10.1016/j.mtcomm.2020.100892CrossRef

Santos TF, Santos CM, Fonseca RT, Melo KM, Aquino MS, Oliveira FR, Medeiros JI (2020) Experimental analysis of the impact protection properties for Kevlar® fabrics under different orientation layers and non-Newtonian fluid compositions. J Compos Mater 54(24):3515–3526. https://doi.org/10.1177/0021998320916231CrossRef

Selim G, Melih Cemal K (2016) Kayma Altında Katılaşan Sıvıların Reolojik Özellikleri 19(4):409–414. https://doi.org/10.2339/2016.19.4409-414CrossRef

Shakeel A, Kirichek A, Chassagne C (2020) Effect of pre-shearing on the steady and dynamic rheological properties of mud sediments. Mar Petrol Geol 116:104338. https://doi.org/10.1016/J.MARPETGEO.2020.104338CrossRef

Sharma R, Verma SK, Biswas I, Bhattacharjee D, Kamal P (2019) Effect of thermal surface activation of silica nanoparticles on the rheological behavior of shear thickening fluid. Mater Res Express 6(6):065710. https://doi.org/10.1088/2053-1591/ab102dCrossRef

Singh M, Verma SK, Biswas I, Mehta R (2018) Effect of molecular weight of polyethylene glycol on the rheological properties of fumed silica-polyethylene glycol shear thickening fluid. Mater Res Express 5(5):055704. https://doi.org/10.1088/2053-1591/aac25cCrossRef

Talreja K, Chauhan I, Ghosh A, Majumdar A, Butola BS (2017) Functionalization of silica particles to tune the impact resistance of shear thickening fluid treated aramid fabrics. RSC Adv 7(78):49787–49794. https://doi.org/10.1039/c7ra09834kCrossRef

Talreja K, Ghosh A, Arora S, Majumdar A, Butola BS (2022) Tailoring the rheology of shear thickening fluids by regulating the particle size of dispersed phase for enhancing the impact resistance of aramid fabrics. Fibers Polymers 23(5):1300–1308. https://doi.org/10.1007/s12221-022-4138-8CrossRef

Wagner NJ, Brady JF (2009) Shear thickening in colloidal dispersions. Phys Today 62(10):27–32. https://doi.org/10.1063/1.3248476CrossRef

Wang QS, Sun RJ, Yao M, Chen MY, Feng Y (2019) The influence of temperature on inter-yarns fictional properties of shear thickening fluids treated Kevlar fabrics. Compos A: Appl Sci Manuf 116(August 2018):46–53. https://doi.org/10.1016/j.compositesa.2018.10.020CrossRef

Warren J, Cole M, Offenberger S, Kota KR, Lacy TE, Toghiani H, Burchell M, Kundu S, Pittman CU (2021) Hypervelocity Impacts on honeycomb core sandwich panels filled with shear thickening fluid. Int J Impact Eng 150(December 2020):103803. https://doi.org/10.1016/j.ijimpeng.2020.103803CrossRef

Wei M, Lin K, Sun L (2022) Shear thickening fluids and their applications. Mater Design 216:110570. https://doi.org/10.1016/j.matdes.2022.110570CrossRef

Wei M, Lv Y, Sun L, Sun H (2020) Rheological properties of multi-walled carbon nanotubes/silica shear thickening fluid suspensions. Colloid Polym Sci 298(3):243–250. https://doi.org/10.1007/s00396-020-04599-3CrossRef

Wetzel ED, Egres RG, Lee YS, Kirkwood KM, Kirkwood JE, Wagner NJ (2004) The effect of rheological parameters on the ballistic properties of shear thickening fluid (STF)-Kevlar composites. AIP Conf Proc 712:288–293. https://doi.org/10.1063/1.1766538CrossRef

Williams TH, Day J, Pickard S (2009) Surgical and medical garments and materials incorporating shear thickening fluids. US Patent US2009/0255023A1. https://patents.google.com/patent/US20090255023A1/en

Yang W, Wu Y, Pei X, Zhou F, Xue Q (2017) Contribution of surface chemistry to the shear thickening of silica nanoparticle suspensions. Langmuir 33(4):1037–1042. https://doi.org/10.1021/acs.langmuir.6b04060CrossRef

Yeh FY, Chang KC, Chen TW, Yu CH (2014) The dynamic performance of a shear thickening fluid viscous damper. J Chin Inst Eng, Transact Chin Inst Eng A 37(8):983–994. https://doi.org/10.1080/02533839.2014.912775CrossRef

Zarei M, Aalaie J (2020) Application of shear thickening fluids in material development. J Market Res 9(5):10411–10433. https://doi.org/10.1016/j.jmrt.2020.07.049CrossRef

Zhang Q, Qin Z, Yan R, Wei S, Zhang W, Lu S, Jia L (2021) Processing technology and ballistic-resistant mechanism of shear thickening fluid/high-performance fiber-reinforced composites: a review. Compos Struct 266(26):113806. https://doi.org/10.1016/j.compstruct.2021.113806CrossRef

Zhang XZ, Li WH, Gong XL (2008) The rheology of shear thickening fluid (STF) and the dynamic performance of anSTF-filled damper. Smart Materials and Structures 17(3):035027. https://doi.org/10.1088/0964-1726/17/3/035027CrossRef

Zhao M, Zhang J, Liu Y, Peng Z, Li X (2022) Rheological characteristics analysis of shear thickening fluids based on response surface methodology. Materials Research Express 9(2):025701. https://doi.org/10.1088/2053-1591/ac4eb6CrossRef

Zhao Q, Yuan J, Jiang H, Yao H, Wen B (2021) Vibration control of a rotor system by shear thickening fluid dampers. J Sound Vibr 494:115883. https://doi.org/10.1016/j.jsv.2020.115883CrossRef

Title: Influence of dispersion liquid and silica concentration on rheological properties of shear thickening fluids (STFs)
Authors: Abdulhalim Aşkan
Mahmut Çapkurt
Emre Acar
Murat Aydın
Publication date: 24-07-2023
Publisher: Springer Berlin Heidelberg
Published in: Rheologica Acta / Issue 9/2023
Print ISSN: 0035-4511
Electronic ISSN: 1435-1528
DOI: https://doi.org/10.1007/s00397-023-01406-y

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