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Journal of Materials Science
Published in: Journal of Materials Science 10/2015

01-05-2015 | Original Paper

Influence of photopolymerization conditions on the structure and property of poly (divinylbenzene) shells

Authors: Yi Yang, Jiayi Zhu, Xiaojun Wang, Jia Wang, Zefu Li, Xuan Luo, Lin Zhang

Published in: Journal of Materials Science | Issue 10/2015

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Abstract

Low-density, porous, millimeter-size poly (divinylbenzene) (PDVB) shells were produced by the use of a microfluidic device under ultraviolet (UV) irradiation at ambient temperature. We studied the effects of monomer concentrations and illumination times on the density, shrinkage, surface area, porosity characteristics, and compression properties of PDVB shells. It was found that actual densities, shrinkages, and surface areas of PDVB shells varied from 70 to 210 mg/cm3, 8.5 to 15.2 %, and 457 to 848 m2/g, respectively, with the changes of monomer concentrations and illumination times. The analytic results of nitrogen adsorption/desorption isotherms indicated that the mesoporous structures of PDVB shells were affected by monomer concentrations and illumination times. Moreover, the photopolymerization of DVB monomers was essentially a solvent polymerization. The phase separation process induced the formation of pore structures. Different morphologies of the inwall and outwall of PDVB shells were obtained. Furthermore, a reasonable growth mechanism of PDVB shells was proposed.
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Metadata
Title
Influence of photopolymerization conditions on the structure and property of poly (divinylbenzene) shells
Authors
Yi Yang
Jiayi Zhu
Xiaojun Wang
Jia Wang
Zefu Li
Xuan Luo
Lin Zhang
Publication date
01-05-2015
Publisher
Springer US
Published in
Journal of Materials Science / Issue 10/2015
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-8926-z

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