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Polymer Bulletin
Published in: Polymer Bulletin 2/2012

01-01-2012 | Original Paper

Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications

Authors: Zbigniew Czech, Agnieszka Kowalczyk, Janina Kabatc, Jolanta Świderska, Lu Shao, Yongping Bai

Published in: Polymer Bulletin | Issue 2/2012

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Abstract

This article describes the photoreactive UV-crosslinkable solvent-borne acrylic pressure-sensitive adhesives (PSA) containing unsaturated copolymerizable photoinitiators and their synthesis. The solvent-borne acrylic PSA were synthesized in ethyl acetate as a solvent, and the copolymerizable photoinitiators type II, known as hydrogen abstractors, were incorporated into acrylic polymer chain during conducted radical polymerization process. The synthesized solvent-borne acrylic PSA containing different unsaturated photoinitiators were investigated to evaluate their relevant and significant properties such as tack, peel adhesion, and shear strength after UV exposure.
previous article Competitive mechanism of poly(ethylene glycol) with poly(vinyl methyl ether) in complexing water molecules revealed with elastic light scattering spectroscopy
next article Synthesis and properties of 2-(10,11-dihydrodibenz[b,f]azepine-5-yl)carbazole-based monomers and polymers

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Literature
1.
Czech Z (1999) Crosslinking of pressure-sensitive adhesives based on acrylic. Technical University of Szczecin, Szczecin
2.
3.
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McKenna LW, Mass W (1975) US Patent 3 886 126
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Technical Bulletin Carbodiimide (2002) Stahl Company, Waalwijk, Holland
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Kenneth DW, Meixner LA (1992) US Patent 5 296 277
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8.
Oemke R (1991) A survey of the field of radiation cured PSAs. AFERA, Jahrestagung, Amsterdam, Holland, pp 47–61
9.
Czech Z, Kurzawa R (2007) Acrylic pressure-sensitive adhesive for transdermal drug delivery systems. J Appl Polym Sci 106:2398–2404CrossRef
10.
Czech Z, Loclair H, Wesołowska M (2007) Photoreactivity adjustment of acrylic PSA. Rev Adv Mater Sci 14:141–150
11.
Czech Z, Milker R, Butwin A, Herko E (2008) Removal of organic solvents for the purpose of manufacturing of solvent-free pressure-sensitive adhesives. Polish J Chem Technol 1:37–40CrossRef
Metadata
Title
Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications
Authors
Zbigniew Czech
Agnieszka Kowalczyk
Janina Kabatc
Jolanta Świderska
Lu Shao
Yongping Bai
Publication date
01-01-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0563-3

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