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02-03-2024 | Original Research

Influence on the structure and the molecular mobility of cellulose–diamine complexes studied by a multiscale experimental approach

Authors: Agustín Rios de Anda, Axel Ettori, Yoshiharu Nishiyama, Karim Mazeau, Caroll Vergelati, Laurent Heux

Published in: Cellulose | Issue 5/2024

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Abstract

In this paper, the influence of diamines on the intrinsic structure and molecular mobility of cellulosic complexes is discussed. Cellulose was pre-swollen by ethylenediamine then put in contact with a series of aliphatic diamines at a stoechiometric ratio. These materials were then characterized by Wide Angle X-Ray diffraction (WAXS) and solid-state \(^{13}C\) NMR spectroscopy. It was observed by WAXS that diamines are able to swell cellulose along the (010) crystallographic plane and are able to modify unit cell angle \(\gamma \) of cellulose monoclinic structure. Moreover according to their periodicity, ordered- or disordered-phases structures were identified in such cellulosic complexes by Cross Polarization - Magic Angle Spinning (CP-MAS) \(^{13}C\) NMR spectroscpy. Two-dimensional Wide-line Separation (2D WISE) and \(T_1\) relaxation time \(^{13}C\) NMR spectroscopy experiments showed that complexes do exhibit molecular motions between 23 and 90\(^{\circ }\)C. Modulated Differential Scanning Calorymetry (MDSC) further showed the presence of two glass transition temperatures \(T_g\), which were attributed, in combination with the \(^{13}C\) NMR spectroscopy observations through a multiscale approach, to relaxation motions internal to the diamines chemical structure and to the motion of cellulose–diamine planes respectively.

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Title: Influence on the structure and the molecular mobility of cellulose–diamine complexes studied by a multiscale experimental approach
Authors: Agustín Rios de Anda
Axel Ettori
Yoshiharu Nishiyama
Karim Mazeau
Caroll Vergelati
Laurent Heux
Publication date: 02-03-2024
Publisher: Springer Netherlands
Published in: Cellulose / Issue 5/2024
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-024-05786-z

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