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Journal of Polymer Research
Published in: Journal of Polymer Research 7/2020

01-07-2020 | ORIGINAL PAPER

Investigation of microstructure in poly(methyl methacrylate) prepared via ambient temperature ARGET-ATRP: a combined approach of 1D and 2D NMR spectroscopy

Authors: Anjana Dhar, Upendra Singh, Bishnu P. Koiry, Bikash Baishya, Dhruba J. Haloi

Published in: Journal of Polymer Research | Issue 7/2020

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Abstract

This investigation reports the analysis of different microstructures present in poly(methyl methacrylate) (PMMA) using1D and 2D NMR spectroscopy. The PMMA used in this study has been prepared via activators regenerated by electron transfer atom transfer radical polymerization (ARGET-ATRP) in DMF at ambient temperature using methyl 2-chloro propionate (MCP) as initiator, CuBr2 as catalyst in combination with N, N, N´, N´´, N´´- pentamethyldiethylenetriamine (PMDETA) as ligand and ascorbic acid as reducing agent.13C NMR, which provides good information about tacticity of a polymer, has been used extensively along with 1H NMR spectroscopy to extract the information about the different microstructures present in PMMA. Heteronuclear multiple-bond correlation (HMBC), heteronuclear single-quantum coherence (HSQC), and total correlation spectroscopy (TOCSY) were also used to study the position of protons, couplings with carbon etc. in the PMMA.
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Metadata
Title
Investigation of microstructure in poly(methyl methacrylate) prepared via ambient temperature ARGET-ATRP: a combined approach of 1D and 2D NMR spectroscopy
Authors
Anjana Dhar
Upendra Singh
Bishnu P. Koiry
Bikash Baishya
Dhruba J. Haloi
Publication date
01-07-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 7/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02153-x

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