Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 12/2017

10-11-2017

Investigation of Thermal Conductivities and Expansion Coefficients of (Yb1 − x La x )2AlTaO7 Ceramics

Authors: Chen Xiaoge, Zhang Hongsong, Su Sai, Zhao Yongde, Tang An, Zhang Haoming

Published in: Journal of Materials Engineering and Performance | Issue 12/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The (Yb1 − x La x )2AlTaO7 (x = 0, 0.1, 0.3, 0.5) ceramics were prepared by solid-state reaction method. The phase composition, microstructure, thermophysical properties of (Yb1 − x La x )2AlTaO7 ceramics were investigated. Results reveal that (Yb1 − x La x )2AlTaO7 (x = 0, 0.1, 0.3) ceramics exhibit a single pyrochlore-type structure, and the (Yb0.5La0.5)2AlTaO7 has an orthorhombic weberite structure. The thermal conductivities of (Yb1 − x La x )2AlTaO7 (x = 0, 0.1, 0.3) ceramics decrease with increasing Yb2O3 contents. (Yb0.5La0.5)2AlTaO7 has the highest thermal conductivity among all the ceramics studied, within the range of 1.48-1.75 W/m K (20-1200 °C). The thermal expansion coefficients of (Yb1 − x La x )2AlTaO7 ceramics decrease gradually with increasing La2O3 fractions, and the thermal expansion coefficients are close to those of YSZ.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference K. Bobzin, L.D. Zhao, M. Ote, and T.F. Linke, Deposition and Characterization of Thermal Barrier Coatings of ZrO2-4 mol.%Y2O3-1 mol.% Gd2O3-1 mol.%Yb2O3, Surf. Coat. Technol., 2015, 268, p 205–208CrossRef K. Bobzin, L.D. Zhao, M. Ote, and T.F. Linke, Deposition and Characterization of Thermal Barrier Coatings of ZrO2-4 mol.%Y2O3-1 mol.% Gd2O3-1 mol.%Yb2O3, Surf. Coat. Technol., 2015, 268, p 205–208CrossRef
2.
go back to reference Y.H. Wang, J.H. Ouyang, and Z.G. Liu, Preparation and Thermo-Physical Properties of La1 − x NdxMgAl11O19 (x = 0, 0.1, 0.2) Ceramics, Ceram. Inter., 2009, 485, p 734–738 Y.H. Wang, J.H. Ouyang, and Z.G. Liu, Preparation and Thermo-Physical Properties of La1 − x NdxMgAl11O19 (x = 0, 0.1, 0.2) Ceramics, Ceram. Inter., 2009, 485, p 734–738
3.
go back to reference O. Fabrachnaya, R. Wulf, M.J. Kriegel, G. Savinykh, M. Dopita, J. Seidel, H.C. Heitz, O. Nashed, U. Gross, and H.J. Seifert, Thermophyscial Properties of Pyrochlore and Fluorite Phases in the Ln2Zr2O7-Y2O3 Systems (La, Nd, Sm): 2. Comparison of Conventionally Sintered and SPS Samples in the Systems Nd2Zr2O7-Y2O3 and Sm2Zr2O7-Y2O3, J. Alloys Compds., 2015, 625, p 200–207CrossRef O. Fabrachnaya, R. Wulf, M.J. Kriegel, G. Savinykh, M. Dopita, J. Seidel, H.C. Heitz, O. Nashed, U. Gross, and H.J. Seifert, Thermophyscial Properties of Pyrochlore and Fluorite Phases in the Ln2Zr2O7-Y2O3 Systems (La, Nd, Sm): 2. Comparison of Conventionally Sintered and SPS Samples in the Systems Nd2Zr2O7-Y2O3 and Sm2Zr2O7-Y2O3, J. Alloys Compds., 2015, 625, p 200–207CrossRef
4.
go back to reference Z.H. Song, X. Qiang, W.F. Chi, L. Ling, W. Yuan, and C.X. Ge, Preparation and Thermophyscial Properties of (Sm0.5La0.5)2(Zr0.8Ce0.2)2O7 Ceramics for Thermal Barrier Coatings, J. Alloys Compds., 2009, 475, p 624–628CrossRef Z.H. Song, X. Qiang, W.F. Chi, L. Ling, W. Yuan, and C.X. Ge, Preparation and Thermophyscial Properties of (Sm0.5La0.5)2(Zr0.8Ce0.2)2O7 Ceramics for Thermal Barrier Coatings, J. Alloys Compds., 2009, 475, p 624–628CrossRef
5.
go back to reference Z.H. Song, C.X. Ge, L. Gang, W.X. Li, and D.X. Dan, Influence of Gd2O3 Addition on Thermophyscial Properties of La2Ce2O7 Ceramics for Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2012, 32, p 3693–3700CrossRef Z.H. Song, C.X. Ge, L. Gang, W.X. Li, and D.X. Dan, Influence of Gd2O3 Addition on Thermophyscial Properties of La2Ce2O7 Ceramics for Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2012, 32, p 3693–3700CrossRef
6.
go back to reference J. Wu, X.Z. Wei, N.P. Padture, P.G. Klemens, and M. Gell, Low Thermal Conductivity Rare Earth Zirconates for Potential Thermal Barrier Coating Applications, J. Am. Ceram. Soc., 2002, 85, p 3031–3035CrossRef J. Wu, X.Z. Wei, N.P. Padture, P.G. Klemens, and M. Gell, Low Thermal Conductivity Rare Earth Zirconates for Potential Thermal Barrier Coating Applications, J. Am. Ceram. Soc., 2002, 85, p 3031–3035CrossRef
7.
go back to reference J. Feng, B. Xiao, R. Zhou, and W. Pan, Thermal Expansion and Conductivity of RE2Sn2O7 (RE = La, Nd, Sm, Gd, Er and Yb) Pyrochlores, Scripta Mater., 2013, 69, p 401–404CrossRef J. Feng, B. Xiao, R. Zhou, and W. Pan, Thermal Expansion and Conductivity of RE2Sn2O7 (RE = La, Nd, Sm, Gd, Er and Yb) Pyrochlores, Scripta Mater., 2013, 69, p 401–404CrossRef
8.
go back to reference B. Liu, J.Y. Wang, F.Z. Li, and Y.C. Zhou, Theoretical Elastic Stiffness, Structural Stability and Thermal Conductivity of La2T2O7 (T = Ge, Ti, Sn, Zr, Hf) Pyrochlore, Acta Mater., 2010, 58, p 4369–4377CrossRef B. Liu, J.Y. Wang, F.Z. Li, and Y.C. Zhou, Theoretical Elastic Stiffness, Structural Stability and Thermal Conductivity of La2T2O7 (T = Ge, Ti, Sn, Zr, Hf) Pyrochlore, Acta Mater., 2010, 58, p 4369–4377CrossRef
9.
go back to reference X. Zhou, Z.H. Xu, X.Z. Fan, S.M. Zhao, X.Q. Cao, and L.M. He, Y4Al2O9 Ceramics as Novel Thermal Barrier Coating Materials for High-Temperature Applications, Mater. Lett., 2014, 134, p 146–148CrossRef X. Zhou, Z.H. Xu, X.Z. Fan, S.M. Zhao, X.Q. Cao, and L.M. He, Y4Al2O9 Ceramics as Novel Thermal Barrier Coating Materials for High-Temperature Applications, Mater. Lett., 2014, 134, p 146–148CrossRef
10.
go back to reference X.Y. Xie, H.B. Guo, S.K. Gong, and H.B. Xu, Lanthanum-Titanium-Aluminum Oxide: A Novel Thermal Barrier Coating Material for Applications at 1300 °C, J. Eur. Ceram. Soc., 2011, 31, p 1677–1683CrossRef X.Y. Xie, H.B. Guo, S.K. Gong, and H.B. Xu, Lanthanum-Titanium-Aluminum Oxide: A Novel Thermal Barrier Coating Material for Applications at 1300 °C, J. Eur. Ceram. Soc., 2011, 31, p 1677–1683CrossRef
11.
go back to reference J. Feng, B. Xiao, R. Zhou, W. Pan, and D.R. Clarke, Anisotropic Elastic and Thermal Properties of the Double Perovskite Slab-Rock Salt Layer Ln2SrAl2O7 (Ln = La, Nd, Sm, Eu, Gd or Dy) Natural Super-Lattice Structure, Acta Mater., 2012, 60, p 3380–3392CrossRef J. Feng, B. Xiao, R. Zhou, W. Pan, and D.R. Clarke, Anisotropic Elastic and Thermal Properties of the Double Perovskite Slab-Rock Salt Layer Ln2SrAl2O7 (Ln = La, Nd, Sm, Eu, Gd or Dy) Natural Super-Lattice Structure, Acta Mater., 2012, 60, p 3380–3392CrossRef
12.
go back to reference L.H. Ran, W.C. An, Z.C. Guang, and T.S. Yan, Thermo-Physical Properties of Rare-Earth Hexaaluminates LnMgAl11O19 (Ln: La, Pr, Nd, Sm, Eu and Gd) Magnetoplumbite for Advanced Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2015, 35, p 1297–1306CrossRef L.H. Ran, W.C. An, Z.C. Guang, and T.S. Yan, Thermo-Physical Properties of Rare-Earth Hexaaluminates LnMgAl11O19 (Ln: La, Pr, Nd, Sm, Eu and Gd) Magnetoplumbite for Advanced Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2015, 35, p 1297–1306CrossRef
13.
go back to reference H.R. Lu, C.A. Wang, and C.G. Zhang, Low Thermal Conductivity Sr2+, Zn2+ and Ti4+ Ions Co-doped LaMgAl11O19 for Potential Thermal Barrier Coating Applications, Ceram. Inter., 2014, 40, p 16273–16279CrossRef H.R. Lu, C.A. Wang, and C.G. Zhang, Low Thermal Conductivity Sr2+, Zn2+ and Ti4+ Ions Co-doped LaMgAl11O19 for Potential Thermal Barrier Coating Applications, Ceram. Inter., 2014, 40, p 16273–16279CrossRef
14.
go back to reference L.H. Ran, W.C. An, and Z.C. Guang, Influence of Ln3+ and B3+ Ions Co-substitution on Thermophysical Properties of LnMB11O19-Type Magnetoplumbite LaMgAl11O19 for Advanced Thermal Barrier Coatings, J. Am. Ceram. Soc., 2013, 96, p 1063–1066CrossRef L.H. Ran, W.C. An, and Z.C. Guang, Influence of Ln3+ and B3+ Ions Co-substitution on Thermophysical Properties of LnMB11O19-Type Magnetoplumbite LaMgAl11O19 for Advanced Thermal Barrier Coatings, J. Am. Ceram. Soc., 2013, 96, p 1063–1066CrossRef
15.
go back to reference D.R. Clarke, Materials Selection Guidelines for Low Thermal Conductivity Thermal Barrier Coatings, Surf. Coat. Technol., 2003, 163–164, p 67–74CrossRef D.R. Clarke, Materials Selection Guidelines for Low Thermal Conductivity Thermal Barrier Coatings, Surf. Coat. Technol., 2003, 163–164, p 67–74CrossRef
16.
go back to reference D.R. Clarke and S.R. Phillpot, Thermal Barrier Coating Materials, Mater. Today, 2005, 8, p 22–29CrossRef D.R. Clarke and S.R. Phillpot, Thermal Barrier Coating Materials, Mater. Today, 2005, 8, p 22–29CrossRef
17.
go back to reference Y.J. Liang, Y.C. Che, and X.X. Liu, Manual of Practical Inorganic Matter Thermodynamics, Northeastern University Press, Shenyang, 1993 Y.J. Liang, Y.C. Che, and X.X. Liu, Manual of Practical Inorganic Matter Thermodynamics, Northeastern University Press, Shenyang, 1993
18.
go back to reference Z.G. Liu, J.H. Ouyang, K.N. Sun, and X.L. Xia, Effect of Gd and Yb Co-doping on Structure and Electrical Conductivity of the Sm2Zr2O7 Pyrochlore, J Power Source., 2010, 195, p 7225–7229CrossRef Z.G. Liu, J.H. Ouyang, K.N. Sun, and X.L. Xia, Effect of Gd and Yb Co-doping on Structure and Electrical Conductivity of the Sm2Zr2O7 Pyrochlore, J Power Source., 2010, 195, p 7225–7229CrossRef
19.
go back to reference R. Abe, M. Higashi, K. Sayama, Y. Abe, and H. Sugihara, Photocatalytic Activity of R3MO7 and R2Ti2O7 (R = Y, Gd, La; M = Nb, Ta) for Water Splitting into H2 and O2, J. Phy. Chem. B., 2006, 110, p 2219–2226CrossRef R. Abe, M. Higashi, K. Sayama, Y. Abe, and H. Sugihara, Photocatalytic Activity of R3MO7 and R2Ti2O7 (R = Y, Gd, La; M = Nb, Ta) for Water Splitting into H2 and O2, J. Phy. Chem. B., 2006, 110, p 2219–2226CrossRef
20.
go back to reference Y.X. Li, G. Chen, H.J. Zhang, and Z.H. Li, Photo-Catalytic Water Splitting of La2AlTaO7 and the Effect of Aluminum on the Electronic Structure, J. Phy. Chem. Solids., 2009, 70, p 536–540CrossRef Y.X. Li, G. Chen, H.J. Zhang, and Z.H. Li, Photo-Catalytic Water Splitting of La2AlTaO7 and the Effect of Aluminum on the Electronic Structure, J. Phy. Chem. Solids., 2009, 70, p 536–540CrossRef
21.
go back to reference Z.H. Ming, F. Yan, C.X. Ge, Z.H. Song, L.Y. Xu, T. An, and R. Bo, Thernal Properties of La3TaO7 and La2AlTaO7, Ceram. Inter, 2017, 43, p 755–759CrossRef Z.H. Ming, F. Yan, C.X. Ge, Z.H. Song, L.Y. Xu, T. An, and R. Bo, Thernal Properties of La3TaO7 and La2AlTaO7, Ceram. Inter, 2017, 43, p 755–759CrossRef
22.
go back to reference T.X. De, Y.H. Qi, M.C. Xia, and Z. Zhi, A Novel Visible Light Driven Photocatalyst Sm2InNbO7 for H2 or O2 Evolution, Chem. Phys., 2009, 484, p 48–53 T.X. De, Y.H. Qi, M.C. Xia, and Z. Zhi, A Novel Visible Light Driven Photocatalyst Sm2InNbO7 for H2 or O2 Evolution, Chem. Phys., 2009, 484, p 48–53
23.
go back to reference L.J. Fei, L. Ming, M. Kun, L.Y. Mei, and Z.Z. Gang, Photo-Catalytic Activity of Novel Y2InSbO7 and Y2GdSbO7 Nano-Catalysts for Degradation of Environmental Pollutant Rhodamine B Under Visible Light Irradiation, Chem. Eng. J., 2011, 167, p 161–171 L.J. Fei, L. Ming, M. Kun, L.Y. Mei, and Z.Z. Gang, Photo-Catalytic Activity of Novel Y2InSbO7 and Y2GdSbO7 Nano-Catalysts for Degradation of Environmental Pollutant Rhodamine B Under Visible Light Irradiation, Chem. Eng. J., 2011, 167, p 161–171
24.
go back to reference M.A. Subramanian, G. Aravamudan, and G.V. Subba, Rao, Oxide Pyrochlores-a Review, Prog. Solid State Chem., 1983, 15, p 55–143CrossRef M.A. Subramanian, G. Aravamudan, and G.V. Subba, Rao, Oxide Pyrochlores-a Review, Prog. Solid State Chem., 1983, 15, p 55–143CrossRef
25.
go back to reference Z.H. Li, G. Chen, X.J. Tian, and Y.X. Li, Photocatalytic Property of La2Ti2O7 Synthesized by the Mineralization Polymerizable Complex Method, Mater. Res. Bull., 2008, 43, p 1781–1788CrossRef Z.H. Li, G. Chen, X.J. Tian, and Y.X. Li, Photocatalytic Property of La2Ti2O7 Synthesized by the Mineralization Polymerizable Complex Method, Mater. Res. Bull., 2008, 43, p 1781–1788CrossRef
26.
go back to reference M. Uno, A. Kosuga, M. Okui, K. Horisaka, and S. Yamanaka, Photoelectrochemical Study of Lanthanide Titanium Oxides, Ln2Ti2O7 (Ln = La, Sm, and Gd), J. Alloys Compds., 2005, 400, p 270–275CrossRef M. Uno, A. Kosuga, M. Okui, K. Horisaka, and S. Yamanaka, Photoelectrochemical Study of Lanthanide Titanium Oxides, Ln2Ti2O7 (Ln = La, Sm, and Gd), J. Alloys Compds., 2005, 400, p 270–275CrossRef
27.
go back to reference J.R. Nicholls, K.J. Lawson, A. Johnstone, and D.S. Rickerby, Methods to Reduce the Thermal Conductivity of EB-PVD TBCs, Surf. Coat. Technol., 2002, 151–152, p 383–391CrossRef J.R. Nicholls, K.J. Lawson, A. Johnstone, and D.S. Rickerby, Methods to Reduce the Thermal Conductivity of EB-PVD TBCs, Surf. Coat. Technol., 2002, 151–152, p 383–391CrossRef
28.
go back to reference X.R. Ren, C.L. Wan, M. Zhao, J. Yang, and W. Pei, Mechanical and Thermal Properties of Fine-Grained Quasi-Eutectoid (La1 − x Ybx)2Zr2O7 Ceramics, J. Eur. Ceram. Soc., 2015, 35, p 3145–3154CrossRef X.R. Ren, C.L. Wan, M. Zhao, J. Yang, and W. Pei, Mechanical and Thermal Properties of Fine-Grained Quasi-Eutectoid (La1 − x Ybx)2Zr2O7 Ceramics, J. Eur. Ceram. Soc., 2015, 35, p 3145–3154CrossRef
29.
go back to reference L. Liu, Y.H. Wang, Z. Ma, F.C. Wang, and M.M. Zhu, Preparation and Thermophysical Properties of Yb-doped Ba2DyAlO5 Ceramics, Mater. Lett., 2015, 144, p 33–35CrossRef L. Liu, Y.H. Wang, Z. Ma, F.C. Wang, and M.M. Zhu, Preparation and Thermophysical Properties of Yb-doped Ba2DyAlO5 Ceramics, Mater. Lett., 2015, 144, p 33–35CrossRef
30.
go back to reference P.J. Saines, J.R. Spencer, B.J. Kennedy, Y. Kubota, C. Minakata, H. Hano, K. Kato, and M. Takata, Strctures and Crystal Chemistry of the Double Perovskite Ba2LnB’O6 (Ln = lanthanide and B’ = Nb, Ta): Part II:Temperature Dependence of the Structures of Ba2LnB’O6, J. Solid State Chem., 2007, 180, p 3001–3007CrossRef P.J. Saines, J.R. Spencer, B.J. Kennedy, Y. Kubota, C. Minakata, H. Hano, K. Kato, and M. Takata, Strctures and Crystal Chemistry of the Double Perovskite Ba2LnB’O6 (Ln = lanthanide and B’ = Nb, Ta): Part II:Temperature Dependence of the Structures of Ba2LnB’O6, J. Solid State Chem., 2007, 180, p 3001–3007CrossRef
Metadata
Title
Investigation of Thermal Conductivities and Expansion Coefficients of (Yb1 − x La x )2AlTaO7 Ceramics
Authors
Chen Xiaoge
Zhang Hongsong
Su Sai
Zhao Yongde
Tang An
Zhang Haoming
Publication date
10-11-2017
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 12/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-3062-3

Other articles of this Issue 12/2017

Journal of Materials Engineering and Performance 12/2017 Go to the issue

Premium Partners