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Published in:
Cover of the book

2000 | OriginalPaper | Chapter

Is a molecule in chemistry explicable as a broken symmetry in quantum mechanics?

Author : Brian Sutcliffe

Published in: Mathematical Models and Methods for Ab Initio Quantum Chemistry

Publisher: Springer Berlin Heidelberg

Included in: Professional Book Archive

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It is argued that incorporating the molecular geometry into the transformation specifications for deriving the standard (Eckart) Hamiltonian used to describe molecular spectra, cannot generally be accomplished without breaking the permutational symmetry requirements on identical nuclei.

next chapter SCF algorithms for HF electronic calculations
Metadata
Title
Is a molecule in chemistry explicable as a broken symmetry in quantum mechanics?
Author
Brian Sutcliffe
Copyright Year
2000
Publisher
Springer Berlin Heidelberg
Book
Mathematical Models and Methods for Ab Initio Quantum Chemistry

Print ISBN: 978-3-540-67631-7

Electronic ISBN: 978-3-642-57237-1

Copyright Year: 2000

DOI
https://doi.org/10.1007/978-3-642-57237-1_1

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