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Journal of Materials Science
Published in: Journal of Materials Science 13/2019

26-03-2019 | Polymers

Light- and pH-responsive self-healing hydrogel

Authors: Meng Yang, Linlin Wang, Yongbin Cheng, Ke Ma, Xinran Wei, Pengxiang Jia, Yongkuan Gong, Yang Zhang, Jingfa Yang, Jiang Zhao

Published in: Journal of Materials Science | Issue 13/2019

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Abstract

A self-healing hydrogel was synthesized via the multi-component reaction of azobenzene-methacrylamide, β-CD and 3-methacrylamido phenylboronic acid. The orthogonal method was applied to analyze the influence of host–guest inclusion complexation, cross-linker and phenylboronic acid monomers content on mechanical properties and healing efficiency of the hydrogel. The results indicated that hydrogel showed autonomic self-healing behavior. The hydrogel demonstrated light-switchable self-healing ability and pH-sensitive swelling ratio. It was found that hydrogel showed high elongation, excellent resilience and low elastic hysteresis. The design of the combined host–guest interactions and boronate esters on the hydrogel showed advantage for improving the mechanical, self-healing and recovery properties simultaneously.
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Appendix
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Metadata
Title
Light- and pH-responsive self-healing hydrogel
Authors
Meng Yang
Linlin Wang
Yongbin Cheng
Ke Ma
Xinran Wei
Pengxiang Jia
Yongkuan Gong
Yang Zhang
Jingfa Yang
Jiang Zhao
Publication date
26-03-2019
Publisher
Springer US
Published in
Journal of Materials Science / Issue 13/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03547-z

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