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Topics in Catalysis
Published in: Topics in Catalysis 3-4/2008

01-04-2008 | Original Paper

Liquid-Phase Oxidation of Benzene to Phenol by Molecular Oxygen over La Catalysts Supported on HZSM-5

Authors: Yuichi Ichihashi, Tomohiko Taniguchi, Hiromi Amano, Takashi Atsumi, Satoru Nishiyama, Shigeru Tsuruya

Published in: Topics in Catalysis | Issue 3-4/2008

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Abstract

The liquid-phase oxidation of benzene to phenol over lanthanum oxide catalysts (LaOx/HZSM-5) supported on HZSM-5 was studied in the presences of oxygen as an oxidant and ascorbic acid as a reducing regent. LaOx/HZSM-5 effectively catalyzes the formation of phenol at 353 K under the pressurization of oxygen. The LaOx/HZSM-5 catalysts take place no leaching of lanthanum species from the catalysts to acidic solvent. Therefore, it is demonstrated that the supported lanthanum catalysts are stable and reusable for the benzene oxidation even in the acidic reaction solution.
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Metadata
Title
Liquid-Phase Oxidation of Benzene to Phenol by Molecular Oxygen over La Catalysts Supported on HZSM-5
Authors
Yuichi Ichihashi
Tomohiko Taniguchi
Hiromi Amano
Takashi Atsumi
Satoru Nishiyama
Shigeru Tsuruya
Publication date
01-04-2008
Publisher
Springer US
Published in
Topics in Catalysis / Issue 3-4/2008
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-007-9027-2

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