Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 19/2019

10-09-2019

Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method

Authors: Jinhui Xie, Nan Ding, Xibing Li, Wentao Huang, Huijie Yang, Jue Wang, Lixi Wang, Qitu Zhang

Published in: Journal of Materials Science: Materials in Electronics | Issue 19/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A series of double perovskite (Gd1−xTbx)2MgTiO6 (x = 0.01, 0.05, 0.1, 0.15, 0.2, 0.3 and 0.4) phosphors were successfully synthesized by solid-state reaction method. The A-site in the host is occupied by two Gd3+ ions, which facilitates the doping of Tb3+ ions. The crystal structure, morphology and luminescence performance were evaluated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, photoluminescence and calculation of CIE color coordinates. A weak emission peak (5D47F6, 490 nm) and a strong emission peak (5D47F5, 545 nm) existed in the emission spectra under 313 nm excitation. The quenching concentration of Tb3+ reached up to 20.0 mol% was observed in Gd1.8Tb0.2MgTiO6 phosphors. In order to explore the potential application of Gd2−2xMgTiO6:xTb3+ phosphors in white LED solid-state lighting, the fluorescence decay curves and thermal stability were carried out.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference F. Xue, Y. Hu, C. Li et al., Photoluminescence and long persistent luminescence properties of a novel green emitting phosphor Ca3TaAl3Si2O14:Tb3+. J. Mater. Sci.: Mater. Electron. 27(8), 8486–8492 (2016) F. Xue, Y. Hu, C. Li et al., Photoluminescence and long persistent luminescence properties of a novel green emitting phosphor Ca3TaAl3Si2O14:Tb3+. J. Mater. Sci.: Mater. Electron. 27(8), 8486–8492 (2016)
2.
go back to reference N.C. George, K.A. Denault, R. Seshadri, Phosphors for solid-state white lighting. Annu. Rev. Mater. Res. 43(43), 481–501 (2013)CrossRef N.C. George, K.A. Denault, R. Seshadri, Phosphors for solid-state white lighting. Annu. Rev. Mater. Res. 43(43), 481–501 (2013)CrossRef
4.
go back to reference J. Zhong, S. Zhou, D. Chen et al., Enhanced luminescence of a Ba2GdSbO6:Mn4+ red phosphor via cation doping for warm white light-emitting diodes. Dalton Trans. 47(25), 8248–8256 (2018)CrossRef J. Zhong, S. Zhou, D. Chen et al., Enhanced luminescence of a Ba2GdSbO6:Mn4+ red phosphor via cation doping for warm white light-emitting diodes. Dalton Trans. 47(25), 8248–8256 (2018)CrossRef
5.
go back to reference M. Zhao, H. Liao, M.S. Molokeev et al., Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition. Light: Sci. Appl. 8(1), 38 (2019)CrossRef M. Zhao, H. Liao, M.S. Molokeev et al., Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition. Light: Sci. Appl. 8(1), 38 (2019)CrossRef
6.
go back to reference J. Zhou, J. Luo, X. Rong et al., Lead-free perovskite derivative Cs2SnCl6−xBrx single crystals for narrowband photodetectors. Adv. Opt. Mater. 7(10), 1900139 (2019)CrossRef J. Zhou, J. Luo, X. Rong et al., Lead-free perovskite derivative Cs2SnCl6−xBrx single crystals for narrowband photodetectors. Adv. Opt. Mater. 7(10), 1900139 (2019)CrossRef
7.
go back to reference J. Qiao, L. Ning, M.S. Molokeev et al., Eu2+ site preferences in the mixed cation K2BaCa(PO4)2 and thermally stable luminescence. J. Am. Chem. Soc. 140(30), 9730–9736 (2018)CrossRef J. Qiao, L. Ning, M.S. Molokeev et al., Eu2+ site preferences in the mixed cation K2BaCa(PO4)2 and thermally stable luminescence. J. Am. Chem. Soc. 140(30), 9730–9736 (2018)CrossRef
8.
go back to reference J. Li, Q. Liang, J.-Y. Hong et al., White light emission and enhanced color stability in a single-component host. ACS Appl. Mater. Interfaces 10(21), 18066–18072 (2018)CrossRef J. Li, Q. Liang, J.-Y. Hong et al., White light emission and enhanced color stability in a single-component host. ACS Appl. Mater. Interfaces 10(21), 18066–18072 (2018)CrossRef
9.
go back to reference I. Won Bin, G. Nathan, K. Joshua et al., Efficient and color-tunable oxyfluoride solid solution phosphors for solid-state white lighting. Adv. Mater. 23(20), 2300–2305 (2011)CrossRef I. Won Bin, G. Nathan, K. Joshua et al., Efficient and color-tunable oxyfluoride solid solution phosphors for solid-state white lighting. Adv. Mater. 23(20), 2300–2305 (2011)CrossRef
10.
go back to reference W. Feng, L. Xiaogang, Multicolor tuning of lanthanide-doped nanoparticles by single wavelength excitation. Acc. Chem. Res. 47(4), 1378–1385 (2014)CrossRef W. Feng, L. Xiaogang, Multicolor tuning of lanthanide-doped nanoparticles by single wavelength excitation. Acc. Chem. Res. 47(4), 1378–1385 (2014)CrossRef
11.
go back to reference W. Chen, Z. Liu, L. Shen et al., Design and energy transfer mechanism for single-phased Gd2MgTiO6:Bi3+, Eu3+ tunable white light-emitting phosphors. J. Mater. Sci. 54(5), 4056–4072 (2019)CrossRef W. Chen, Z. Liu, L. Shen et al., Design and energy transfer mechanism for single-phased Gd2MgTiO6:Bi3+, Eu3+ tunable white light-emitting phosphors. J. Mater. Sci. 54(5), 4056–4072 (2019)CrossRef
12.
go back to reference G. Ning, Y. Song, H. You et al., Optical properties and energy transfer of NaCaPO4:Ce3 + , Tb3 + phosphors for potential application in light-emitting diodes. Eur. J. Inorg. Chem. 2010(29), 4636–4642 (2010)CrossRef G. Ning, Y. Song, H. You et al., Optical properties and energy transfer of NaCaPO4:Ce3 + , Tb3 + phosphors for potential application in light-emitting diodes. Eur. J. Inorg. Chem. 2010(29), 4636–4642 (2010)CrossRef
13.
go back to reference Q. Liu, L.X. Wang, L. Zhang et al., Enhanced luminescence and structure evolution of double perovskite (K, Na)LaMgWO6:Eu3+ phosphor for white LEDs. J. Mater. Sci.: Mater. Electron. 26(10), 8083–8088 (2015) Q. Liu, L.X. Wang, L. Zhang et al., Enhanced luminescence and structure evolution of double perovskite (K, Na)LaMgWO6:Eu3+ phosphor for white LEDs. J. Mater. Sci.: Mater. Electron. 26(10), 8083–8088 (2015)
14.
go back to reference X. Huang, H. Guo, A novel highly efficient single-composition tunable white-light-emitting LiCa3MgV3O12:Eu3+ phosphor. Dyes Pigm. 154, 82–86 (2018)CrossRef X. Huang, H. Guo, A novel highly efficient single-composition tunable white-light-emitting LiCa3MgV3O12:Eu3+ phosphor. Dyes Pigm. 154, 82–86 (2018)CrossRef
16.
go back to reference A. Fu, A. Guan, F. Gao et al., A novel double perovskite La2ZnTiO6:Eu3+ red phosphor for solid-state lighting: Synthesis and optimum luminescence. Opt. Laser Technol. 96, 43–49 (2017)CrossRef A. Fu, A. Guan, F. Gao et al., A novel double perovskite La2ZnTiO6:Eu3+ red phosphor for solid-state lighting: Synthesis and optimum luminescence. Opt. Laser Technol. 96, 43–49 (2017)CrossRef
17.
go back to reference Y. Liang, H.M. Noh, W. Ran et al., The design and synthesis of new double perovskite (Na, Li)YMg(W, Mo)O6:Eu3+ red phosphors for white light-emitting diodes. J. Alloy. Compd. 716, 56–64 (2017)CrossRef Y. Liang, H.M. Noh, W. Ran et al., The design and synthesis of new double perovskite (Na, Li)YMg(W, Mo)O6:Eu3+ red phosphors for white light-emitting diodes. J. Alloy. Compd. 716, 56–64 (2017)CrossRef
18.
go back to reference L. Quan, X. Li, Z. Bing et al., Structure evolution and delayed quenching of the double perovskite NaLaMgWO6:Eu3 + phosphor for white LEDs. Ceram. Int. 42(14), 15294–15300 (2016)CrossRef L. Quan, X. Li, Z. Bing et al., Structure evolution and delayed quenching of the double perovskite NaLaMgWO6:Eu3 + phosphor for white LEDs. Ceram. Int. 42(14), 15294–15300 (2016)CrossRef
19.
go back to reference S. Ida, C. Ogata, M. Eguchi et al., Photoluminescence of perovskite nanosheets prepared by exfoliation of layered oxides, K2Ln2Ti3O10, KLnNb2O7, and RbLnTa2O7 (Ln: lanthanide ion). J. Am. Chem. Soc. 130(22), 7052–7059 (2008)CrossRef S. Ida, C. Ogata, M. Eguchi et al., Photoluminescence of perovskite nanosheets prepared by exfoliation of layered oxides, K2Ln2Ti3O10, KLnNb2O7, and RbLnTa2O7 (Ln: lanthanide ion). J. Am. Chem. Soc. 130(22), 7052–7059 (2008)CrossRef
20.
go back to reference Q. Hu, Z. Deng, M. Hu et al., X-ray scintillation in lead-free double perovskite crystals. Sci. China Chem. 61(12), 1581–1586 (2018)CrossRef Q. Hu, Z. Deng, M. Hu et al., X-ray scintillation in lead-free double perovskite crystals. Sci. China Chem. 61(12), 1581–1586 (2018)CrossRef
21.
go back to reference M. Zhao, Z. Xia, X. Huang et al., Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stability. Sci. Adv. 5(1), 0363 (2019) M. Zhao, Z. Xia, X. Huang et al., Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stability. Sci. Adv. 5(1), 0363 (2019)
22.
go back to reference Y.Y. Tsai, H.R. Shih, M.T. Tsai et al., A novel single-phased white light emitting phosphor of Eu3+ ions-doped Ca2LaTaO6. Mater. Chem. Phys. 143(2), 611–615 (2014)CrossRef Y.Y. Tsai, H.R. Shih, M.T. Tsai et al., A novel single-phased white light emitting phosphor of Eu3+ ions-doped Ca2LaTaO6. Mater. Chem. Phys. 143(2), 611–615 (2014)CrossRef
23.
go back to reference L.X. Wang, Q. Liu, K. Shen et al., A high quenching content red-emitting phosphor based on double perovskite host BaLaMgSbO6 for white LEDs. J. Alloy. Compd. 696, 443–449 (2017)CrossRef L.X. Wang, Q. Liu, K. Shen et al., A high quenching content red-emitting phosphor based on double perovskite host BaLaMgSbO6 for white LEDs. J. Alloy. Compd. 696, 443–449 (2017)CrossRef
24.
go back to reference A.R. Sharits, J.F. Khoury, P.M. Woodward, Evaluating NaREMgWO6 (RE = La, Gd, Y) doubly ordered double perovskites as Eu3+ phosphor hosts. Inorg. Chem. 55(23), 12383–12390 (2016)CrossRef A.R. Sharits, J.F. Khoury, P.M. Woodward, Evaluating NaREMgWO6 (RE = La, Gd, Y) doubly ordered double perovskites as Eu3+ phosphor hosts. Inorg. Chem. 55(23), 12383–12390 (2016)CrossRef
25.
go back to reference P. Karen, P.M. Woodward, J. Lindén et al., Verwey transition in mixed-valence TbBaFe2O5: two attempts to order charges. Phys. Rev. B 64(21), 214405 (2001)CrossRef P. Karen, P.M. Woodward, J. Lindén et al., Verwey transition in mixed-valence TbBaFe2O5: two attempts to order charges. Phys. Rev. B 64(21), 214405 (2001)CrossRef
26.
go back to reference W. Fu, D. Ijdo, New insight into the symmetry and the structure of the double perovskites Ba2LnNbO6 (Ln = lanthanides and Y). J. Solid State Chem. 179(4), 1022–1028 (2006)CrossRef W. Fu, D. Ijdo, New insight into the symmetry and the structure of the double perovskites Ba2LnNbO6 (Ln = lanthanides and Y). J. Solid State Chem. 179(4), 1022–1028 (2006)CrossRef
27.
go back to reference X. Yan, G.R. Fern, R. Withnall et al., Effects of the host lattice and doping concentration on the colour of Tb3+ cation emission in Y2O2S:Tb3+ and Gd2O2S:Tb3+ nanometer sized phosphor particles. Nanoscale 5(18), 8640–8646 (2013)CrossRef X. Yan, G.R. Fern, R. Withnall et al., Effects of the host lattice and doping concentration on the colour of Tb3+ cation emission in Y2O2S:Tb3+ and Gd2O2S:Tb3+ nanometer sized phosphor particles. Nanoscale 5(18), 8640–8646 (2013)CrossRef
28.
go back to reference H. Chen, H. Lin, Q. Huang et al., A novel double-perovskite Gd2ZnTiO6:Mn 4+ red phosphor for UV-based w-LEDs: structure and luminescence properties. J. Mater. Chem. C 4(12), 2374–2381 (2016)CrossRef H. Chen, H. Lin, Q. Huang et al., A novel double-perovskite Gd2ZnTiO6:Mn 4+ red phosphor for UV-based w-LEDs: structure and luminescence properties. J. Mater. Chem. C 4(12), 2374–2381 (2016)CrossRef
29.
go back to reference X. Yin, Y. Wang, F. Huang et al., Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M = Sb, Nb, Ta) with distorted coordination environment. J. Solid State Chem. 184(12), 3324–3328 (2011)CrossRef X. Yin, Y. Wang, F. Huang et al., Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M = Sb, Nb, Ta) with distorted coordination environment. J. Solid State Chem. 184(12), 3324–3328 (2011)CrossRef
30.
go back to reference L. Wang, X. Yang, Q. Zhang et al., Luminescence properties of La2O2S:Tb3+ phosphors and phosphor-embedded polymethylmethacrylate films. Mater. Des. 125, 100–108 (2017)CrossRef L. Wang, X. Yang, Q. Zhang et al., Luminescence properties of La2O2S:Tb3+ phosphors and phosphor-embedded polymethylmethacrylate films. Mater. Des. 125, 100–108 (2017)CrossRef
31.
go back to reference P. Jiang, Z. Zhou, W. Gao et al., B-site ordered double perovskite LaBa1−xSrxZnSbO6:Sr(2+)-doping-induced symmetry evolution and structure-luminescence correlations. Dalton Trans. 45(9), 3949–3957 (2016)CrossRef P. Jiang, Z. Zhou, W. Gao et al., B-site ordered double perovskite LaBa1−xSrxZnSbO6:Sr(2+)-doping-induced symmetry evolution and structure-luminescence correlations. Dalton Trans. 45(9), 3949–3957 (2016)CrossRef
32.
go back to reference G. King, L.M. Wayman, P.M. Woodward, Magnetic and structural properties of NaLnMnWO6 and NaLnMgWO6 perovskites. J. Solid State Chem. 182(6), 1319–1325 (2009)CrossRef G. King, L.M. Wayman, P.M. Woodward, Magnetic and structural properties of NaLnMnWO6 and NaLnMgWO6 perovskites. J. Solid State Chem. 182(6), 1319–1325 (2009)CrossRef
33.
go back to reference M. Kim, J. Moon, H. Choi et al., Investigation of the magnetic properties in double perovskite R2CoMnO6 single crystals (R = rare earth: La to Lu). J. Phys.: Condens. Matter 27(42), 426002 (2015) M. Kim, J. Moon, H. Choi et al., Investigation of the magnetic properties in double perovskite R2CoMnO6 single crystals (R = rare earth: La to Lu). J. Phys.: Condens. Matter 27(42), 426002 (2015)
34.
go back to reference P.N. Lekshmi, G. Raji, M. Vasundhara et al., Re-entrant spin glass behaviour and magneto-dielectric effect in insulating Sm2NiMnO6 double perovskite. J. Mater. Chem. C 1(40), 6565–6574 (2013)CrossRef P.N. Lekshmi, G. Raji, M. Vasundhara et al., Re-entrant spin glass behaviour and magneto-dielectric effect in insulating Sm2NiMnO6 double perovskite. J. Mater. Chem. C 1(40), 6565–6574 (2013)CrossRef
35.
go back to reference D. Dexter, J.H. Schulman, Theory of concentration quenching in inorganic phosphors. J. Chem. Phys. 22(6), 1063–1070 (1954)CrossRef D. Dexter, J.H. Schulman, Theory of concentration quenching in inorganic phosphors. J. Chem. Phys. 22(6), 1063–1070 (1954)CrossRef
36.
go back to reference L. Ozawa, Determination of self-concentration quenching mechanisms of rare earth luminescence from intensity measurements on powdered phosphor screens. J. Electrochem. Soc. 126(1), 106–109 (1979)CrossRef L. Ozawa, Determination of self-concentration quenching mechanisms of rare earth luminescence from intensity measurements on powdered phosphor screens. J. Electrochem. Soc. 126(1), 106–109 (1979)CrossRef
37.
go back to reference M. Retuerto, A. Munoz, M.J. Martínez-Lope et al., magnetic interactions in the double perovskites R2NiMnO6 (R = Tb, Ho, Er, Tm) investigated by neutron diffraction. Inorg. Chem. 54(22), 10890–10900 (2015)CrossRef M. Retuerto, A. Munoz, M.J. Martínez-Lope et al., magnetic interactions in the double perovskites R2NiMnO6 (R = Tb, Ho, Er, Tm) investigated by neutron diffraction. Inorg. Chem. 54(22), 10890–10900 (2015)CrossRef
38.
go back to reference Z. Wang, J.-G. Li, Q. Zhu et al., Sacrificial conversion of layered rare-earth hydroxide (LRH) nanosheets into (Y1−xEux) PO4 nanophosphors and investigation of photoluminescence. Dalton Trans. 45(12), 5290–5299 (2016)CrossRef Z. Wang, J.-G. Li, Q. Zhu et al., Sacrificial conversion of layered rare-earth hydroxide (LRH) nanosheets into (Y1−xEux) PO4 nanophosphors and investigation of photoluminescence. Dalton Trans. 45(12), 5290–5299 (2016)CrossRef
39.
go back to reference C. Liu, Z. Xia, M.S. Molokeev et al., Synthesis, crystal structure, and enhanced luminescence of garnet-type Ca3Ga2Ge3O12:Cr3+ by codoping Bi3+. J. Am. Ceram. Soc. 98(6), 1870–1876 (2015)CrossRef C. Liu, Z. Xia, M.S. Molokeev et al., Synthesis, crystal structure, and enhanced luminescence of garnet-type Ca3Ga2Ge3O12:Cr3+ by codoping Bi3+. J. Am. Ceram. Soc. 98(6), 1870–1876 (2015)CrossRef
40.
go back to reference H.F. Yang, Y.H. Tang, X.Y. Sun, Q. Liu, X.G. Huang, L.X. Wang, Z.X. Fu, Q.T. Zhang, S.W. Or, Biomass-derived porous carbon materials with NiS nanoparticles for high performance supercapacitors. J. Mater. Sci.: Mater. Electron. 28, 14874–14883 (2017) H.F. Yang, Y.H. Tang, X.Y. Sun, Q. Liu, X.G. Huang, L.X. Wang, Z.X. Fu, Q.T. Zhang, S.W. Or, Biomass-derived porous carbon materials with NiS nanoparticles for high performance supercapacitors. J. Mater. Sci.: Mater. Electron. 28, 14874–14883 (2017)
41.
go back to reference R. Yu, C. Wang, J. Chen et al., Photoluminescence characteristics of Eu3+-doped double-perovskite phosphors. ECS J. Solid State Sci. Technol. 3(3), R33–R37 (2014)CrossRef R. Yu, C. Wang, J. Chen et al., Photoluminescence characteristics of Eu3+-doped double-perovskite phosphors. ECS J. Solid State Sci. Technol. 3(3), R33–R37 (2014)CrossRef
42.
go back to reference H. Yang, Y. Tang, X. Huang, L. Wang, Q. Zhang, Activated porous carbon derived from walnut shells with promising material properties for supercapacitors. J. Mater. Sci.: Mater. Electron. 28, 18637–18645 (2017) H. Yang, Y. Tang, X. Huang, L. Wang, Q. Zhang, Activated porous carbon derived from walnut shells with promising material properties for supercapacitors. J. Mater. Sci.: Mater. Electron. 28, 18637–18645 (2017)
Metadata
Title
Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method
Authors
Jinhui Xie
Nan Ding
Xibing Li
Wentao Huang
Huijie Yang
Jue Wang
Lixi Wang
Qitu Zhang
Publication date
10-09-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 19/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02146-7

Other articles of this Issue 19/2019

Journal of Materials Science: Materials in Electronics 19/2019 Go to the issue