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Journal of Materials Science
Published in: Journal of Materials Science 2/2018

19-09-2017 | Energy materials

Manganese oxides derived from Mn(II)-based metal–organic framework as supercapacitor electrode materials

Authors: Ling-Dong Chen, Yue-Qing Zheng, Hong-Lin Zhu

Published in: Journal of Materials Science | Issue 2/2018

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Abstract

Manganese oxides have been received increasing interest due to their potential application in supercapacitor electrode material. In this paper, a new metal–organic framework Mn3(MA)(H2O)2(ipa)3 (1) (H2ipa = isophthalic acid; MA = melamine) was synthesized via hydrothermal reaction; it presents a 3D network structure which can be simplified as an unusual non-interpenetrated pseudo-primitive 6-connected cubic topology. The Mn-MOF was regarded as a precursor to prepare variety of manganese oxides via calcination in different environments. Cyclic voltammetry and galvanostatic charge–discharge measurements were employed to characterize the electrochemical performance of MnO X materials in Na2SO4 electrolyte. The results show that the MnO X materials reveal excellent long-term cycling stability with enhanced capacitance after charge–discharge cycles. The optimum specific capacitance can be 150 F g−1 with a current density of 1.0 A g−1.
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Appendix
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Literature
1.
Wang GP, Zhang L, Zhang JJ (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828CrossRef
2.
Chen LB, Chen YR, Wu JF, Wang JW, Bai H, Li L (2014) Electrochemical supercapacitor with polymeric active electrolyte. J Mater Chem A 2:10526–10531CrossRef
3.
Zhao Y, Song ZX, Li X, Sun Q, Cheng NC, Lawes S, Sun XL (2016) Metal organic frameworks for energy storage and conversion. Energy Storage Mater 2:35–62CrossRef
4.
Simon P, Gogotsi Y, Dunn B (2014) Where do batteries end and supercapacitors begin. Science 343:1210–1211CrossRef
5.
Klankowski SA, Pandey GP, Malek G, Thomas CR, Bernasek SL, Wu J, Li J (2015) Higher-power supercapacitor electrodes based on mesoporous manganese oxide coating on vertically aligned carbon nanofibers. Nanoscale 7:8485–8494CrossRef
6.
Tang YF, Liu YY, Yu SX, Mu SC, Xiao SH, Zhao YF, Gao FM (2014) Morphology controlled synthesis of monodisperse cobalt hydroxide for supercapacitor with high performance and long cycle life. J Power Sources 256:160–169CrossRef
7.
Yang PH, Mai WJ (2014) Flexible solid-state electrochemical supercapacitors. Nano Energy 8:274–290CrossRef
8.
Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Kluwer Academic/Plenum, New YorkCrossRef
9.
Jiang H, Lee PS, Li C (2013) 3D carbon based nanostructures for advanced supercapacitors. Energy Environ Sci 6:41–53CrossRef
10.
Li WY, Shao JJ, Liu Q, Liu XJ, Zhou XY, Hu JQ (2015) Facile synthesis of porous Mn2O3 nanocubics for high-rate supercapacitors. Electrochim Acta 157:108–114CrossRef
11.
Wu ZS, Ren WC, Wang DW, Li F, Liu B, Cheng HM (2010) High-energy MnO2 nanowire/graphene and graphene asymmetric electrochemical capacitors. ACS Nano 4:5835–5842CrossRef
12.
Wang DW, Fang HT, Li F, Chen ZG, Zhong QS, Lu GQ, Cheng HM (2008) Aligned titania nanotubes as an intercalation anode material for hybrid electrochemical energy storage. Adv Funct Mater 18:3787–3793CrossRef
13.
Qu QT, Shi Y, Li LL, Guo WL, Wu YP, Zhang HP, Guan SY, Holze R (2009) V2O5·0.6H2O nanoribbons as cathode material for asymmetric supercapacitor in K2SO4 Solution. Electrochem Commun 11:1325–1328CrossRef
14.
Oh I, Kim M, Kim J (2015) Controlling hydrazine reduction to deposit iron oxides on oxidized activated carbon for supercapacitor application. Energy 86:292–299CrossRef
15.
Maiti S, Pramanik A, Mahanty S (2016) Electrochemical energy storage in Mn2O3 porous nanobars derived from morphology-conserved transformation of benzenetricarboxylate-bridged metal-organic framework. CrystEngComm 18:450–461CrossRef
16.
Liu YB, Lin LY, Huang YY, Tu CC (2016) Investigation of the electroactive capability for the supercapacitor electrode with cobalt oxide rhombus nanopillar and nanobrush arrays. J Power Sources 315:23–34CrossRef
17.
Navale ST, Mali VV, Pawar SA, Mane RS, Naushad M, Stadler FJ, Patil VB (2015) Electrochemical supercapacitor development based on electrodeposited nickel oxide film. RSC Adv 5:51961–51965CrossRef
18.
Zhao YF, Zhang XJ, He J, Zhang L, Xia MR, Gao FM (2015) Morphology controlled synthesis of nickel cobalt oxide for supercapacitor application with enhanced cycling stability. Electrochim Acta 174:51–56CrossRef
19.
Xiao W, Chen JS, Lou XW (2011) Synthesis of octahedral Mn3O4 crystals and their derived Mn3O4–MnO2 heterostructures via oriented growth. CrystEngComm 13:5685–5687CrossRef
20.
Song MK, Cheng S, Chen H, Qin W, Nam KW, Xu S, Yang XQ, Bongiorno A, Lee J, Bai J, Tyson TA, Cho J, Liu M (2012) Anomalous pseudocapacitive behavior of a nanostructured, mixed-valent manganese oxide film for electrical energy storage. Nano Lett 12:3483–3490CrossRef
21.
Kolathodi MS, Rao SNH, Natarajan TS, Singh G (2016) Beaded manganese oxide (Mn2O3) nanofibers: preparation and application for capacitive energy storage. J Mater Chem A 4:7883–7891CrossRef
22.
Ma TY, Dai S, Jaroniec M, Qiao SZ (2014) Metal–organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. J Am Chem Soc 136:13925–13931CrossRef
23.
Zanchetta E, Malfatti L, Ricco R, Styles MJ, Lisi F, Coghlan CJ, Doonan CJ, Hill AJ, Brusatin G, Falcaro P (2015) ZnO as an efficient nucleating agent for rapid, room temperature synthesis and patterning of Zn-based metal–organic frameworks. Chem Mater 27:690–699CrossRef
24.
Zhang J, Wang LJ, Xu LL, Ge XM, Zhao X, Lai M, Liu ZL, Chen W (2015) Porous cobalt-manganese oxide nanocubes derived from metal organic frameworks as a cathode catalyst for rechargeable Li-O2 batteries. Nanoscale 7:720–726CrossRef
25.
Nguyen T, Boudard M, Carmezim MJ, Montemor MF (2016) Hydrogen bubbling-induced micro/nano porous MnO2 films prepared by electrodeposition for pseudocapacitor electrodes. Electrochim Acta 202:166–174CrossRef
26.
Li SL, Xu Q (2013) Metal–organic frameworks as platforms for clean energy. Energy Environ Sci 6:1656–1683CrossRef
27.
Wang L, Han YZ, Feng X, Zhou JW, Qi PF, Wang B (2016) Metal–organic frameworks for energy storage: batteries and supercapacitors. Coord Chem Rev 307:361–381CrossRef
28.
Salunkhe RR, Tang J, Kamachi Y, Nakato T, Kim JH, Yamauchi Y (2015) Asymmetric supercapacitors using 3D nanoporous carbon and cobalt oxide electrodes synthesized from a single metal–organic framework. ACS Nano 9:6288–6296CrossRef
29.
Song YH, Li X, Wei CT, Fu JY, Xu FG, Tan HL, Tang J, Wang L (2015) A green strategy to prepare metal oxide superstructure from metal-organic frameworks. Sci Rep 5:8401CrossRef
30.
Song YH, Li X, Sun LL, Wang L (2015) Metal/metal oxide nanostructures derived from metal–organic frameworks. RSC Adv 5:7267–7279CrossRef
31.
Xu W, Li TT, Zheng YQ (2016) Porous Co3O4 nanoparticles derived from a Co(II)- cyclohexanehexacarboxylate metal–organic framework and used in a supercapacitor with good cycling stability. RSC Adv 6:86447–86454CrossRef
32.
Zhang L, Li W, Zhang J, Li ZJ, Qin YY, Cheng JK, Yao YG (2008) Antiferromagnetic interactions in melamine-bridged trinuclear cobalt complex. Inorg Chem Commun 11:279–282CrossRef
33.
Lee SH, Lee H, Cho MS, Namb JD, Lee Y (2013) Morphology and composition control of manganese oxide by the pulse reverse electrodeposition technique for high performance supercapacitors. J Mater Chem A 1:14606–14611CrossRef
34.
Gao L, Zhang LL, Jia SY, Liu XC, Wang YH, Xing SX (2016) Facile route to achieve hierarchical hollow MnO2 nanostructures. Electrochim Acta 203:59–65CrossRef
35.
Zhao YC, Misch J, Wang CA (2016) Facile synthesis and characterization of MnO2 nanomaterials as supercapacitor electrode materials. J Mater Sci Mater Electron 27:5533–5542CrossRef
36.
Ren XG, An JW, Yan SH, Gao LZ, Xu SM, Wang XM, Wei GQ (2016) Assembly of Mn3O4/carbon black composite and its supercapacitor application. Int J Electrochem Sci 11:5080–5089CrossRef
37.
Lee E, Lee T, Kim BS (2014) Electrospun nanofiber of hybrid manganese oxides for supercapacitor: relevance to mixed inorganic interfaces. J Power Sources 255:335–340CrossRef
38.
Xuan LY, Chen LY, Yang QQ, Chen WF, Hou XH, Jiang YQ, Zhang Q, Yuan Y (2015) Engineering 2D multi-layer graphene-like Co3O4 thin sheets with vertically aligned nanosheets as basic building units for advanced pseudocapacitor materials. J Mater Chem A 3:17525–17533CrossRef
39.
Chen SL, Liu F, Xiang QJ, Feng XH, Qiu GH (2013) Synthesis of Mn2O3 microstructures and their energy storage ability studies. Electrochim Acta 106:360–371CrossRef
40.
Tao T, Chen Y, Chen YH, Fox DS, Zhang HZ, Zhou MQ, Raveggi M, Barlow AJ, Glushenkov AM (2017) Two-dimensional metal oxide nanoflower- like architectures: a general growth method and their applications in energy storage and as model materials for nanofabrication. ChemPlusChem 82:295–302CrossRef
41.
Zhang F, Zhang XG (2012) Mn2O3 sub-micron powder: preparation via complex thermolysis route and electrochemical properties. Chin J Inorg Chem 28:2626–2632
42.
Liang JY, Bu LT, Cao WG, Chen T, Cao YC (2016) Facile fabrication of coaxial-cable like Mn2O3 nanofiber by electrospinning: application as electrode material for supercapacitor. J Taiwan Inst Chem Eng 65:584–590CrossRef
43.
Pang H, Li XR, Li B, Zhang YZ, Zhao QX, Lai WY, Huang W (2016) Porous dimanganese trioxide microflowers derived from microcoordinations for flexible solid-state asymmetric supercapacitors. Nanoscale 8:11689–11697CrossRef
44.
Fan YF, Zhang XD, Liu YS, Cai Q, Zhang JM (2013) One-pot hydrothermal synthesis of Mn3O4/graphene nanocomposite for supercapacitors. Mater Lett 95:153–156CrossRef
45.
Bhagwan J, Sahoo A, Yadav KL, Sharma Y (2015) Porous, One dimensional and high aspect ratio Mn3O4 nanofibers: fabrication and optimization for enhanced supercapacitive properties. Electrochim Acta 174:992–1001CrossRef
46.
Yang JH, Yang XF, Zhong YL, Ying JY (2015) Porous MnO/Mn3O4 nanocomposites for electrochemical energy storage. Nano Energy 13:702–708CrossRef
Metadata
Title
Manganese oxides derived from Mn(II)-based metal–organic framework as supercapacitor electrode materials
Authors
Ling-Dong Chen
Yue-Qing Zheng
Hong-Lin Zhu
Publication date
19-09-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 2/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1575-7

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