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2017 | OriginalPaper | Chapter

5. Mechanistic Pathways of Non-Enzymatic Flavor Formation

Author : Marcus A. Glomb

Published in: Springer Handbook of Odor

Publisher: Springer International Publishing

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Abstract

This chapter focusses on the formation of flavor active structures by mechanisms based on the degradation of reducing carbohydrates in the presence of amines. As model reactions have led to the elucidation of a confusing diversity of compounds, special attention is given to the understanding of the basic reaction pathways explaining the evolution of the most abundant odorants predominately shaping the aroma profile of most foods.

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Literature
[1]
go back to reference F. Ledl, E. Schleicher: New aspects of the Maillard reaction in foods and in the human body, Angew. Chem. Int. Ed. Engl. 29, 565–594 (1990)CrossRef F. Ledl, E. Schleicher: New aspects of the Maillard reaction in foods and in the human body, Angew. Chem. Int. Ed. Engl. 29, 565–594 (1990)CrossRef
[2]
go back to reference M. Hellwig, T. Henle: Baking, ageing, diabetes: A short history of the Maillard reaction, Angew. Chem. Int. Ed. Engl. 53, 10316–10329 (2014)CrossRef M. Hellwig, T. Henle: Baking, ageing, diabetes: A short history of the Maillard reaction, Angew. Chem. Int. Ed. Engl. 53, 10316–10329 (2014)CrossRef
[3]
go back to reference J. Gobert, M.A. Glomb: Degradation of glucose: Reinvestigation of reactive α-dicarbonyl compounds, J. Agric. Food Chem. 57, 8591–8597 (2009)CrossRef J. Gobert, M.A. Glomb: Degradation of glucose: Reinvestigation of reactive α-dicarbonyl compounds, J. Agric. Food Chem. 57, 8591–8597 (2009)CrossRef
[4]
go back to reference M. Smuda, M.A. Glomb: Novel insights into the Maillard catalyzed degradation of maltose, J. Agric. Food Chem. 59, 13254–13264 (2011)CrossRef M. Smuda, M.A. Glomb: Novel insights into the Maillard catalyzed degradation of maltose, J. Agric. Food Chem. 59, 13254–13264 (2011)CrossRef
[5]
go back to reference A. Dunkel, M. Steinhaus, M. Kotthoff, B. Nowak, D. Krautwurst, P. Schieberle, T. Hofmann: Nature’s chemical signatures in human olfaction: A foodborne perspective for future biotechnology, Angew. Chem. Int. Ed. Engl. 53, 7124–7143 (2014)CrossRef A. Dunkel, M. Steinhaus, M. Kotthoff, B. Nowak, D. Krautwurst, P. Schieberle, T. Hofmann: Nature’s chemical signatures in human olfaction: A foodborne perspective for future biotechnology, Angew. Chem. Int. Ed. Engl. 53, 7124–7143 (2014)CrossRef
[6]
go back to reference P. Schieberle: The carbon module labeling (CAMOLA) technique: A useful tool for identifying transient intermediates in the formation of Maillard-type target molecules, Ann. N.Y. Acad. Sci. 1043, 236–248 (2005)CrossRef P. Schieberle: The carbon module labeling (CAMOLA) technique: A useful tool for identifying transient intermediates in the formation of Maillard-type target molecules, Ann. N.Y. Acad. Sci. 1043, 236–248 (2005)CrossRef
[7]
go back to reference K.M. Biemel, J. Conrad, M.O. Lederer: Unexpected carbonyl mobility in aminoketoses: The key to major Maillard crosslinks, Angew. Chem. Int. Ed. Engl. 41, 801–804 (2002)CrossRef K.M. Biemel, J. Conrad, M.O. Lederer: Unexpected carbonyl mobility in aminoketoses: The key to major Maillard crosslinks, Angew. Chem. Int. Ed. Engl. 41, 801–804 (2002)CrossRef
[8]
go back to reference M. Smuda, M.A. Glomb: Fragmentation pathways during Maillard-induced carbohydrate degradation, J. Agric. Food Chem. 61, 10198–10208 (2013)CrossRef M. Smuda, M.A. Glomb: Fragmentation pathways during Maillard-induced carbohydrate degradation, J. Agric. Food Chem. 61, 10198–10208 (2013)CrossRef
[9]
go back to reference Y.V. Pfeifer, L.W. Kroh: Investigation of reactive α-dicarbonyl compounds generated from the Maillard reaction of l-methionine with reducing sugars via their quinoxaline derivatives, J. Agric. Food Chem. 58, 8293–8299 (2010)CrossRef Y.V. Pfeifer, L.W. Kroh: Investigation of reactive α-dicarbonyl compounds generated from the Maillard reaction of l-methionine with reducing sugars via their quinoxaline derivatives, J. Agric. Food Chem. 58, 8293–8299 (2010)CrossRef
[10]
go back to reference M. Voigt, M. Smuda, C. Pfahler, M.A. Glomb: Oxygen-dependent fragmentation reactions during the degradation of 1-deoxy-d-erythro-hexo-2,3-diulose, J. Agric. Food Chem. 58, 5685–5691 (2010)CrossRef M. Voigt, M. Smuda, C. Pfahler, M.A. Glomb: Oxygen-dependent fragmentation reactions during the degradation of 1-deoxy-d-erythro-hexo-2,3-diulose, J. Agric. Food Chem. 58, 5685–5691 (2010)CrossRef
[11]
go back to reference P.J. Thornalley, A. Langborg, H.S. Minhas: Formation of glyoxal, methylglyoxal and 3-deoxyglucosone in the glycation of proteins by glucose, Biochem. J. 344, 109–116 (1999)CrossRef P.J. Thornalley, A. Langborg, H.S. Minhas: Formation of glyoxal, methylglyoxal and 3-deoxyglucosone in the glycation of proteins by glucose, Biochem. J. 344, 109–116 (1999)CrossRef
[12]
go back to reference T. Davidek, S. Devaud, F. Robert, I. Blank: Sugar fragmentation in the Maillard reaction cascade: Isotope labeling studies on the formation of acetic acid by a hydrolytic β-dicarbonyl cleavage mechanism, J. Agric. Food Chem. 54, 6667–6676 (2006)CrossRef T. Davidek, S. Devaud, F. Robert, I. Blank: Sugar fragmentation in the Maillard reaction cascade: Isotope labeling studies on the formation of acetic acid by a hydrolytic β-dicarbonyl cleavage mechanism, J. Agric. Food Chem. 54, 6667–6676 (2006)CrossRef
[13]
go back to reference M. Voigt, M.A. Glomb: Reactivity of 1-deoxy-d-erythro-hexo-2,3-diulose: A key intermediate in the Maillard chemistry of hexoses, J. Agric. Food Chem. 57, 4765–4770 (2009)CrossRef M. Voigt, M.A. Glomb: Reactivity of 1-deoxy-d-erythro-hexo-2,3-diulose: A key intermediate in the Maillard chemistry of hexoses, J. Agric. Food Chem. 57, 4765–4770 (2009)CrossRef
[14]
go back to reference M. Smuda, M.A. Glomb: Maillard degradation pathways of vitamin C, Angew. Chem. Int. Ed. 52, 4887–4891 (2013)CrossRef M. Smuda, M.A. Glomb: Maillard degradation pathways of vitamin C, Angew. Chem. Int. Ed. 52, 4887–4891 (2013)CrossRef
[15]
go back to reference M. Granvogl, E. Beksan, M. Schieberle: New insights into the formation of aroma-active Strecker aldehydes from 3-oxazolines as transient intermediates, J. Agric. Food Chem. 60, 6312–6322 (2012)CrossRef M. Granvogl, E. Beksan, M. Schieberle: New insights into the formation of aroma-active Strecker aldehydes from 3-oxazolines as transient intermediates, J. Agric. Food Chem. 60, 6312–6322 (2012)CrossRef
[16]
go back to reference T. Hofmann, P. Münch, P. Schieberle: Quantitativ model studies on the formation of aroma-active aldehydes and acids by Strecker-type reactions, J. Agric. Food Chem. 48, 434–440 (2000)CrossRef T. Hofmann, P. Münch, P. Schieberle: Quantitativ model studies on the formation of aroma-active aldehydes and acids by Strecker-type reactions, J. Agric. Food Chem. 48, 434–440 (2000)CrossRef
[17]
go back to reference M. Granvogl, S. Bugan, P. Schieberle: Formation of amines and aldehydes from parent amino acids during thermal processing of cocoa and model systems: New insights into pathways of the Strecker reaction, J. Agric. Food Chem. 54, 1730–1739 (2006)CrossRef M. Granvogl, S. Bugan, P. Schieberle: Formation of amines and aldehydes from parent amino acids during thermal processing of cocoa and model systems: New insights into pathways of the Strecker reaction, J. Agric. Food Chem. 54, 1730–1739 (2006)CrossRef
[18]
go back to reference T. Hofmann, P. Schieberle: Formation of aroma-active Strecker-aldehydes by a direct oxidative degradation of Amadori compounds, J. Agric. Food Chem. 48, 4301–4305 (2000)CrossRef T. Hofmann, P. Schieberle: Formation of aroma-active Strecker-aldehydes by a direct oxidative degradation of Amadori compounds, J. Agric. Food Chem. 48, 4301–4305 (2000)CrossRef
[19]
go back to reference P.V. Guerra, V.A. Yaylayan: Dimerization of azomethine ylides: An alternate route to pyrazine formation in the Maillard reaction, J. Agric. Food Chem. 58, 12523–12529 (2010)CrossRef P.V. Guerra, V.A. Yaylayan: Dimerization of azomethine ylides: An alternate route to pyrazine formation in the Maillard reaction, J. Agric. Food Chem. 58, 12523–12529 (2010)CrossRef
[20]
go back to reference R. Zamora, R.M. Delgado, F.J. Hildalgo: Chemical conversion of phenylethylamine into phenylacetaldehyde by carbonyl-amine reaction in model systems, J. Agric. Food Chem. 60, 5491–5496 (2012)CrossRef R. Zamora, R.M. Delgado, F.J. Hildalgo: Chemical conversion of phenylethylamine into phenylacetaldehyde by carbonyl-amine reaction in model systems, J. Agric. Food Chem. 60, 5491–5496 (2012)CrossRef
[21]
go back to reference F. Chu, V.A. Yaylayan: Isotope labeling studies in the origin of 3,4-hexandione and 1,2-butandione in an alanine/glucose model system, J. Agric. Food Chem. 57, 9740–9746 (2009)CrossRef F. Chu, V.A. Yaylayan: Isotope labeling studies in the origin of 3,4-hexandione and 1,2-butandione in an alanine/glucose model system, J. Agric. Food Chem. 57, 9740–9746 (2009)CrossRef
[22]
go back to reference A. Adams, V. Polizzi, M. Van Boekel, N. De Kimpe: Formation of pyrazines and a novel pyrrol in Maillard model systems of 1,3-dihydroxyacetone and 2-oxopropanal, J. Agric. Food Chem. 56, 2147–2153 (2008)CrossRef A. Adams, V. Polizzi, M. Van Boekel, N. De Kimpe: Formation of pyrazines and a novel pyrrol in Maillard model systems of 1,3-dihydroxyacetone and 2-oxopropanal, J. Agric. Food Chem. 56, 2147–2153 (2008)CrossRef
[23]
go back to reference T. Hofmann, P. Schieberle: 2-Oxopropanal, hydroxy-2-propanone, and 1-pyrroline-important intermediates in the generation of the roast-smelling food flavor compounds 2-acetyl-1-pyrroline and 2-acetyltetrahydropyridine, J. Agric. Food Chem. 46, 2270–2277 (1998)CrossRef T. Hofmann, P. Schieberle: 2-Oxopropanal, hydroxy-2-propanone, and 1-pyrroline-important intermediates in the generation of the roast-smelling food flavor compounds 2-acetyl-1-pyrroline and 2-acetyltetrahydropyridine, J. Agric. Food Chem. 46, 2270–2277 (1998)CrossRef
[24]
go back to reference P. Schieberle: The role of free amino acids present in yeast as precursors of the odorants 2-acetyl-1-pyrroline and 2-acetyltetrahydropyridine in wheat bread crust, Z. Lebensm.-Unters. Forsch. 191, 206–209 (1990)CrossRef P. Schieberle: The role of free amino acids present in yeast as precursors of the odorants 2-acetyl-1-pyrroline and 2-acetyltetrahydropyridine in wheat bread crust, Z. Lebensm.-Unters. Forsch. 191, 206–209 (1990)CrossRef
[25]
go back to reference T. Davidek, D. Festring, T. Dufossé, O. Novotny, I. Blank: Study to elucidate formation pathways of selected roast-smelling odorants upon extrusion cooking, J. Agric. Food Chem. 61, 10215–10219 (2013)CrossRef T. Davidek, D. Festring, T. Dufossé, O. Novotny, I. Blank: Study to elucidate formation pathways of selected roast-smelling odorants upon extrusion cooking, J. Agric. Food Chem. 61, 10215–10219 (2013)CrossRef
[26]
go back to reference I. Blank, S. Devaud, W. Matthey-Doret, F. Robert: Formation of odorants in Maillard model systems based on l-proline as affected by pH, J. Agric. Food Chem. 51, 3643–3650 (2003)CrossRef I. Blank, S. Devaud, W. Matthey-Doret, F. Robert: Formation of odorants in Maillard model systems based on l-proline as affected by pH, J. Agric. Food Chem. 51, 3643–3650 (2003)CrossRef
[27]
go back to reference D. Rewicki, R. Tressl, U. Ellerbeck, E. Kersten, E. Burgert, M. Gorzynski, R.S. Hauck, B. Helak: Formation and synthesis of some Maillard generated aroma compounds. In: Progress in Flavor Precursor Studies, ed. by P. Schreier, P. Winterhalter (Allured Publishing, Carol Stream 1993) pp. 301–314 D. Rewicki, R. Tressl, U. Ellerbeck, E. Kersten, E. Burgert, M. Gorzynski, R.S. Hauck, B. Helak: Formation and synthesis of some Maillard generated aroma compounds. In: Progress in Flavor Precursor Studies, ed. by P. Schreier, P. Winterhalter (Allured Publishing, Carol Stream 1993) pp. 301–314
[28]
go back to reference T. Hofmann, P. Schieberle: Flavor contribution and formation of the intense roast-smelling odorants 2-propionyl-1-pyrroline and 2-propionyltetrahydropyridine in Maillard-type reactions, J. Agric. Food Chem. 46, 2721–2726 (1998)CrossRef T. Hofmann, P. Schieberle: Flavor contribution and formation of the intense roast-smelling odorants 2-propionyl-1-pyrroline and 2-propionyltetrahydropyridine in Maillard-type reactions, J. Agric. Food Chem. 46, 2721–2726 (1998)CrossRef
[29]
go back to reference L. Gijs, P. Perpete, A. Timmermans, S. Collin: 3-Methylthiopropionaldehyde as precursor of dimethyl trisulfide in aged beers, J. Agric. Food Chem. 48, 6196–6199 (2000)CrossRef L. Gijs, P. Perpete, A. Timmermans, S. Collin: 3-Methylthiopropionaldehyde as precursor of dimethyl trisulfide in aged beers, J. Agric. Food Chem. 48, 6196–6199 (2000)CrossRef
[30]
go back to reference T. Hofmann: Acetylformoin – A chemical switch in the formation of colored Maillard reaction products from hexoses and primary and secondary amino acids, J. Agric. Food Chem. 46, 3918–3928 (1998)CrossRef T. Hofmann: Acetylformoin – A chemical switch in the formation of colored Maillard reaction products from hexoses and primary and secondary amino acids, J. Agric. Food Chem. 46, 3918–3928 (1998)CrossRef
[31]
go back to reference T. Hofmann, P. Schieberle: Acetylformoin – An important progenitor of 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 2-acetyltetrahydropyridine during thermal food processing, Proc. 6th Wartburg Aroma Symp. Flavor 2000 Perception Release Evaluation Formation Acceptance Nutrition/Health, Eisenach (2001) pp. 311–322 T. Hofmann, P. Schieberle: Acetylformoin – An important progenitor of 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 2-acetyltetrahydropyridine during thermal food processing, Proc. 6th Wartburg Aroma Symp. Flavor 2000 Perception Release Evaluation Formation Acceptance Nutrition/Health, Eisenach (2001) pp. 311–322
[32]
go back to reference T. Hofmann, P. Schieberle: Identification of potent aroma compounds in termally treated mixtures of glucose/cysteine and rhamnose/cysteine using aroma extract dilution techniques, J. Agric. Food Chem. 45, 898–906 (1997)CrossRef T. Hofmann, P. Schieberle: Identification of potent aroma compounds in termally treated mixtures of glucose/cysteine and rhamnose/cysteine using aroma extract dilution techniques, J. Agric. Food Chem. 45, 898–906 (1997)CrossRef
[33]
go back to reference Y. Wang, C.-T. Ho: Formation of 2,5-dimethyl-4-hydroxy-3(2H)-furanone through methylglyoxal: A Maillard reaction intermediate, J. Agric. Food Chem. 56, 7405–7409 (2008)CrossRef Y. Wang, C.-T. Ho: Formation of 2,5-dimethyl-4-hydroxy-3(2H)-furanone through methylglyoxal: A Maillard reaction intermediate, J. Agric. Food Chem. 56, 7405–7409 (2008)CrossRef
[34]
go back to reference I. Blank, L.B. Fay: Formation of 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 4-hydroxy-2(or 5)-ethyl-5(or 2)-methyl-3(2H)-furanone through Maillard reaction based on pentose sugars, J. Agric. Food Chem. 44, 531–536 (1996)CrossRef I. Blank, L.B. Fay: Formation of 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 4-hydroxy-2(or 5)-ethyl-5(or 2)-methyl-3(2H)-furanone through Maillard reaction based on pentose sugars, J. Agric. Food Chem. 44, 531–536 (1996)CrossRef
[35]
go back to reference K. Takahashi, M. Tadenuma, S. Sato: 3-Hydroxy-4,5-dimethyl-2(5H)-furanone, a burnt flavoring compound from aged sake, Agric. Biol. Chem. 40, 325–330 (1976) K. Takahashi, M. Tadenuma, S. Sato: 3-Hydroxy-4,5-dimethyl-2(5H)-furanone, a burnt flavoring compound from aged sake, Agric. Biol. Chem. 40, 325–330 (1976)
[36]
go back to reference B. Martin, P.X. Etievant, J.L. Le Quere, P. Schlich: More clues about sensory impact of sotolone in some flor sherry wines, J. Agric. Food Chem. 40, 475–478 (1992)CrossRef B. Martin, P.X. Etievant, J.L. Le Quere, P. Schlich: More clues about sensory impact of sotolone in some flor sherry wines, J. Agric. Food Chem. 40, 475–478 (1992)CrossRef
[37]
go back to reference I. Blank, J. Lin, R. Fumeaux, D.H. Welti, L.B. Fay: Formation of 3-hydroxy-4,5-dimethyl-2(5H)-furanone (sotolone) from 4-hydroxy-l-isoleucine and 3-amino-4,5-dimethyl-3,4-dihydro-2(5H)-furanone, J. Agric. Food Chem. 44, 1851–1856 (1996)CrossRef I. Blank, J. Lin, R. Fumeaux, D.H. Welti, L.B. Fay: Formation of 3-hydroxy-4,5-dimethyl-2(5H)-furanone (sotolone) from 4-hydroxy-l-isoleucine and 3-amino-4,5-dimethyl-3,4-dihydro-2(5H)-furanone, J. Agric. Food Chem. 44, 1851–1856 (1996)CrossRef
[38]
go back to reference T. Hofmann: Characterization of Intense Odorants in Carbohydrate/Cysteine Model Reactions and Elucidation of Formation Pathways, Ph.D. Thesis, (Technical University Munich, Munich 1996) T. Hofmann: Characterization of Intense Odorants in Carbohydrate/Cysteine Model Reactions and Elucidation of Formation Pathways, Ph.D. Thesis, (Technical University Munich, Munich 1996)
[39]
go back to reference O. Novotny: Formation of α-hydroxycarbonyl and α-dicarbonyl compounds during degradation of monosaccharides, Czech J. Food Sci. 25, 119–130 (2007) O. Novotny: Formation of α-hydroxycarbonyl and α-dicarbonyl compounds during degradation of monosaccharides, Czech J. Food Sci. 25, 119–130 (2007)
[40]
go back to reference G.A.M. Van den Ouweland: Compounds contributing to beef flavor. Volatile compounds produced by the reaction of 4-hydroxy-5-methyl-3(2H)-furanone and its thio analog with hydrogen sulfide, J. Agric. Food Chem. 23, 501–505 (1975)CrossRef G.A.M. Van den Ouweland: Compounds contributing to beef flavor. Volatile compounds produced by the reaction of 4-hydroxy-5-methyl-3(2H)-furanone and its thio analog with hydrogen sulfide, J. Agric. Food Chem. 23, 501–505 (1975)CrossRef
[41]
go back to reference C. Cerny, T. Davidek: Formation of aroma compounds from ribose and cysteine during the Maillard reaction, J. Agric. Food Chem. 51, 2714–2721 (2003)CrossRef C. Cerny, T. Davidek: Formation of aroma compounds from ribose and cysteine during the Maillard reaction, J. Agric. Food Chem. 51, 2714–2721 (2003)CrossRef
[42]
go back to reference W. Nedvidek, F. Ledl, P. Fischer: Detection of 5-hydroxymethyl-2-methyl-3(2H)-furanone and of α-dicarbonyl compounds in reaction mixtures of hexoses and pentoses with different amines, Z. Lebensm.-Unters. Forsch. 194, 222–228 (1992)CrossRef W. Nedvidek, F. Ledl, P. Fischer: Detection of 5-hydroxymethyl-2-methyl-3(2H)-furanone and of α-dicarbonyl compounds in reaction mixtures of hexoses and pentoses with different amines, Z. Lebensm.-Unters. Forsch. 194, 222–228 (1992)CrossRef
[43]
go back to reference T. Hofmann: P. Schieberle: Quantitative model studies on the effectiveness of different precursor systems in the formation of the intense food odorants 2-furfurylthiol and 2-methyl-3-furanthiol, J. Agric. Food Chem. 46, 235–241 (1998)CrossRef T. Hofmann: P. Schieberle: Quantitative model studies on the effectiveness of different precursor systems in the formation of the intense food odorants 2-furfurylthiol and 2-methyl-3-furanthiol, J. Agric. Food Chem. 46, 235–241 (1998)CrossRef
[44]
go back to reference R. Silwar, R. Tressl: Gas chromatographic-mass spectrometric investigation of aroma compounds formed in the cysteine-methionine-furfural model system under roasting conditions, Z. Lebensm.-Unters. Forsch. 189, 205–211 (1989)CrossRef R. Silwar, R. Tressl: Gas chromatographic-mass spectrometric investigation of aroma compounds formed in the cysteine-methionine-furfural model system under roasting conditions, Z. Lebensm.-Unters. Forsch. 189, 205–211 (1989)CrossRef
[45]
go back to reference S.M. Lee, Y.-J. Jo, Y.-S. Kim: Investigations of the aroma-active compounds formed in the Maillard reaction between glutathione and reducing sugars, J. Agric. Food Chem. 58, 3116–3124 (2010)CrossRef S.M. Lee, Y.-J. Jo, Y.-S. Kim: Investigations of the aroma-active compounds formed in the Maillard reaction between glutathione and reducing sugars, J. Agric. Food Chem. 58, 3116–3124 (2010)CrossRef
Metadata
Title
Mechanistic Pathways of Non-Enzymatic Flavor Formation
Author
Marcus A. Glomb
Copyright Year
2017
Publisher
Springer International Publishing
DOI
https://doi.org/10.1007/978-3-319-26932-0_5

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