Skip to main content
Top
Published in: Journal of Polymer Research 12/2015

01-12-2015 | Original Paper

Melt compounding of poly (Lactic Acid) and talc: assessment of material behavior during processing and resulting crystallization

Authors: Felice De Santis, Roberto Pantani

Published in: Journal of Polymer Research | Issue 12/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The influence of talc incorporation by melt compounding on a commercial grade of poly (lactic acid) (PLA), and the choice of the optimal compounding conditions were investigated. Two types of talc, having micrometric and submicrometric distribution, were adopted. Since the compounding itself has a dramatic influence on the properties of PLA, a study was carried out aimed at assessing the effect of processing on this resin and choosing the most suitable processing conditions. It was found that the incorporation of talc increases the viscosity during the compounding and helps the stability of the viscosity during the mixing. Furthermore, the talc, acting as a nucleating agent, enhances crystallization kinetics, so that crystallization half time can be reduced by one order of magnitude with respect to the pure PLA processed in the same way.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Kolstad JJ (1996) Crystallization kinetics of poly (L‐lactide‐co‐meso‐lactide). J Appl Polym Sci 62(7):1079–91CrossRef Kolstad JJ (1996) Crystallization kinetics of poly (L‐lactide‐co‐meso‐lactide). J Appl Polym Sci 62(7):1079–91CrossRef
2.
go back to reference Soroudi A, Jakubowicz I (2013) Recycling of bioplastics, their blends and biocomposites: a review. Eur Polym J 49(10):2839–58CrossRef Soroudi A, Jakubowicz I (2013) Recycling of bioplastics, their blends and biocomposites: a review. Eur Polym J 49(10):2839–58CrossRef
3.
go back to reference Bergsma J, Rozema F, Bos R, Boering G, De Bruijn W, Pennings A (1995) In vivo degradation and biocompatibility study of in vitro pre-degraded as-polymerized polylactide particles. Biomaterials 16(4):267–74CrossRef Bergsma J, Rozema F, Bos R, Boering G, De Bruijn W, Pennings A (1995) In vivo degradation and biocompatibility study of in vitro pre-degraded as-polymerized polylactide particles. Biomaterials 16(4):267–74CrossRef
4.
go back to reference Suuronen R, Pohjonen T, Hietanen J, Lindqvist C (1998) A 5-year in vitro and in vivo study of the biodegradation of polylactide plates. J Oral Maxillofac Surg 56(5):604–14CrossRef Suuronen R, Pohjonen T, Hietanen J, Lindqvist C (1998) A 5-year in vitro and in vivo study of the biodegradation of polylactide plates. J Oral Maxillofac Surg 56(5):604–14CrossRef
5.
go back to reference Ignjatovic N, Uskokovic D (2004) Synthesis and application of hydroxyapatite/polylactide composite biomaterial. Appl Surf Sci 238(1):314–9CrossRef Ignjatovic N, Uskokovic D (2004) Synthesis and application of hydroxyapatite/polylactide composite biomaterial. Appl Surf Sci 238(1):314–9CrossRef
6.
go back to reference Gupta A, Kumar V (2007) New emerging trends in synthetic biodegradable polymers–polylactide: a critique. Eur Polym J 43(10):4053–74CrossRef Gupta A, Kumar V (2007) New emerging trends in synthetic biodegradable polymers–polylactide: a critique. Eur Polym J 43(10):4053–74CrossRef
7.
go back to reference Singh S, Ray SS (2007) Polylactide based nanostructured biomaterials and their applications. J Nanosci Nanotechnol 7(8):2596–615CrossRef Singh S, Ray SS (2007) Polylactide based nanostructured biomaterials and their applications. J Nanosci Nanotechnol 7(8):2596–615CrossRef
8.
go back to reference De Santis F, Gorrasi G, Pantani R (2015) A spectroscopic approach to assess transport properties of water vapor in PLA. Polym Test 44:15–22CrossRef De Santis F, Gorrasi G, Pantani R (2015) A spectroscopic approach to assess transport properties of water vapor in PLA. Polym Test 44:15–22CrossRef
9.
go back to reference Concilio S, Iannelli P, Sessa L, Olivieri R, Porta A, De Santis F et al. (2015) Biodegradable antimicrobial films based on poly(lactic acid) matrices and active azo compounds. Journal of applied polymer science. 132 (33) 10.1002/App.42357 Concilio S, Iannelli P, Sessa L, Olivieri R, Porta A, De Santis F et al. (2015) Biodegradable antimicrobial films based on poly(lactic acid) matrices and active azo compounds. Journal of applied polymer science. 132 (33) 10.​1002/​App.​42357
10.
go back to reference Saeidlou S, Huneault MA, Li H, Park CB (2012) Poly (lactic acid) crystallization. Prog Polym Sci 37(12):1657–77CrossRef Saeidlou S, Huneault MA, Li H, Park CB (2012) Poly (lactic acid) crystallization. Prog Polym Sci 37(12):1657–77CrossRef
11.
go back to reference Shakoor A, Thomas NL (2014) Talc as a nucleating agent and reinforcing filler in poly (lactic acid) composites. Polym Eng Sci 54(1):64–70CrossRef Shakoor A, Thomas NL (2014) Talc as a nucleating agent and reinforcing filler in poly (lactic acid) composites. Polym Eng Sci 54(1):64–70CrossRef
12.
go back to reference Lim L-T, Auras R, Rubino M (2008) Processing technologies for poly (lactic acid). Prog Polym Sci 33(8):820–52CrossRef Lim L-T, Auras R, Rubino M (2008) Processing technologies for poly (lactic acid). Prog Polym Sci 33(8):820–52CrossRef
13.
go back to reference Garlotta D (2001) A literature review of poly (lactic acid). J Polym Environ 9(2):63–84CrossRef Garlotta D (2001) A literature review of poly (lactic acid). J Polym Environ 9(2):63–84CrossRef
14.
go back to reference De Santis F, Pantani R (2015) Physical changes of poly (Lactic acid) induced by water sorption. AIP Conference Proceedings De Santis F, Pantani R (2015) Physical changes of poly (Lactic acid) induced by water sorption. AIP Conference Proceedings
15.
go back to reference Raquez J-M, Habibi Y, Murariu M, Dubois P (2013) Polylactide (PLA)-based nanocomposites. Prog Polym Sci 38(10):1504–42CrossRef Raquez J-M, Habibi Y, Murariu M, Dubois P (2013) Polylactide (PLA)-based nanocomposites. Prog Polym Sci 38(10):1504–42CrossRef
16.
go back to reference Gahleitner M, Grein C, Kheirandish S, Wolfschwenger J (2011) Nucleation of polypropylene homo-and copolymers. Int Polym Process 26(1):2–20CrossRef Gahleitner M, Grein C, Kheirandish S, Wolfschwenger J (2011) Nucleation of polypropylene homo-and copolymers. Int Polym Process 26(1):2–20CrossRef
17.
go back to reference Ke T, Sun X (2003) Melting behavior and crystallization kinetics of starch and poly (lactic acid) composites. J Appl Polym Sci 89(5):1203–10CrossRef Ke T, Sun X (2003) Melting behavior and crystallization kinetics of starch and poly (lactic acid) composites. J Appl Polym Sci 89(5):1203–10CrossRef
18.
go back to reference Battegazzore D, Bocchini S, Frache A (2011) Crystallization kinetics of poly (lactic acid)-talc composites. Express Polym Lett 5(10):849–58CrossRef Battegazzore D, Bocchini S, Frache A (2011) Crystallization kinetics of poly (lactic acid)-talc composites. Express Polym Lett 5(10):849–58CrossRef
19.
go back to reference Russo P, Acierno D, Vignali A, Lavorgna M (2014) Poly (lactic acid)‐based systems filled with talc microparticles: thermal, structural, and morphological issues. Polym Compos 35(6):1093–103. doi:10.1002/pc.22757 Russo P, Acierno D, Vignali A, Lavorgna M (2014) Poly (lactic acid)‐based systems filled with talc microparticles: thermal, structural, and morphological issues. Polym Compos 35(6):1093–103. doi:10.​1002/​pc.​22757
20.
go back to reference Liu X, Wang T, Chow LC, Yang M, Mitchell JW (2014) Effects of inorganic fillers on the thermal and mechanical properties of poly (lactic acid). Int J Polym Sci. doi:10.1155/2014/827028 Liu X, Wang T, Chow LC, Yang M, Mitchell JW (2014) Effects of inorganic fillers on the thermal and mechanical properties of poly (lactic acid). Int J Polym Sci. doi:10.​1155/​2014/​827028
21.
go back to reference Pantani R, Volpe V, Titomanlio G (2014) Foam injection molding of poly (lactic acid) with environmentally friendly physical blowing agents. J Mater Process Technol 214(12):3098–107CrossRef Pantani R, Volpe V, Titomanlio G (2014) Foam injection molding of poly (lactic acid) with environmentally friendly physical blowing agents. J Mater Process Technol 214(12):3098–107CrossRef
22.
go back to reference Bergeret A, Benezet JC. (2011) Natural fibre-reinforced biofoams. International Journal of Polymer Science Bergeret A, Benezet JC. (2011) Natural fibre-reinforced biofoams. International Journal of Polymer Science
23.
go back to reference Monticelli O, Bocchini S, Gardella L, Cavallo D, Cebe P, Germelli G (2013) Impact of synthetic talc on PLLA electrospun fibers. Eur Polym J 49(9):2572–83CrossRef Monticelli O, Bocchini S, Gardella L, Cavallo D, Cebe P, Germelli G (2013) Impact of synthetic talc on PLLA electrospun fibers. Eur Polym J 49(9):2572–83CrossRef
24.
go back to reference Polymer 2002D (2005) In: Data Sheet Available from: Natureworks LLC Polymer 2002D (2005) In: Data Sheet Available from: Natureworks LLC
25.
go back to reference Huneault MA, Li H (2007) Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer 48(1):270–80CrossRef Huneault MA, Li H (2007) Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer 48(1):270–80CrossRef
26.
go back to reference Li H, Huneault MA, editors (2007) Nucleation and Crystallisation of PLA. Proceedings. Society of Plastics Engineers Annual Technical Conference (ANTEC 2007): Plastics Encounter@ ANTEC 2007 Li H, Huneault MA, editors (2007) Nucleation and Crystallisation of PLA. Proceedings. Society of Plastics Engineers Annual Technical Conference (ANTEC 2007): Plastics Encounter@ ANTEC 2007
27.
go back to reference Othman N, Jazrawi B, Mehrkhodavandi P, Hatzikiriakos SG (2012) Wall slip and melt fracture of poly (lactides). Rheol Acta 51(4):357–69CrossRef Othman N, Jazrawi B, Mehrkhodavandi P, Hatzikiriakos SG (2012) Wall slip and melt fracture of poly (lactides). Rheol Acta 51(4):357–69CrossRef
28.
go back to reference Gorrasi G, Pantani R (2013) Effect of PLA grades and morphologies on hydrolytic degradation at composting temperature: assessment of structural modification and kinetic parameters. Polym Degrad Stab 98(5):1006–14CrossRef Gorrasi G, Pantani R (2013) Effect of PLA grades and morphologies on hydrolytic degradation at composting temperature: assessment of structural modification and kinetic parameters. Polym Degrad Stab 98(5):1006–14CrossRef
29.
go back to reference De Santis F, Pantani R, Titomanlio G (2011) Nucleation and crystallization kinetics of poly (lactic acid). Thermochim Acta 522(1):128–34CrossRef De Santis F, Pantani R, Titomanlio G (2011) Nucleation and crystallization kinetics of poly (lactic acid). Thermochim Acta 522(1):128–34CrossRef
30.
go back to reference Pantani R, De Santis F, Sorrentino A, De Maio F, Titomanlio G (2010) Crystallization kinetics of virgin and processed poly (lactic acid). Polym Degrad Stab 95(7):1148–59CrossRef Pantani R, De Santis F, Sorrentino A, De Maio F, Titomanlio G (2010) Crystallization kinetics of virgin and processed poly (lactic acid). Polym Degrad Stab 95(7):1148–59CrossRef
31.
go back to reference HTP1 and HTPultra5 (2008) In: Data Sheet Available from: IMI Fabi S.p.A HTP1 and HTPultra5 (2008) In: Data Sheet Available from: IMI Fabi S.p.A
Metadata
Title
Melt compounding of poly (Lactic Acid) and talc: assessment of material behavior during processing and resulting crystallization
Authors
Felice De Santis
Roberto Pantani
Publication date
01-12-2015
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 12/2015
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-015-0885-1

Other articles of this Issue 12/2015

Journal of Polymer Research 12/2015 Go to the issue

Premium Partners