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Recent Advances in Rare Earth Metal Asymmetric Catalysis Toward Practical Synthesis of Therapeutics Read chapter Read first chapter

2017 | OriginalPaper | Chapter

Metal Catalyzed Synthetic Reactions via Aerobic Oxidation as a Key Step

Authors : Mitsuru Shindo, Kenji Matsumoto

Published in: New Horizons of Process Chemistry

Publisher: Springer Singapore

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Abstract

New aerobic oxidative metal catalyzed synthetic reactions are described: The Cu(II) complex catalyzed the acylation of thioester in Wittig lactonization under neutral conditions and the dissymmetrization of symmetric dithiomalonates via selective monoacylation. The key step in this reaction was the formation of an acylketene, the stability of which would contribute to selectivity. The aerobic Rh/C-catalyzed oxidative homo- and cross-coupling of aryl amines was developed. The coupling reactions afforded symmetrical and nonsymmetrical biaryl amines in excellent yields. These reactions provide a mild, operationally simple, and efficient approach for the synthesis of biaryls which are important to pharmaceutical and materials chemistry.

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previous chapter Recent Advances in Rare Earth Metal Asymmetric Catalysis Toward Practical Synthesis of Therapeutics
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Metadata
Title
Metal Catalyzed Synthetic Reactions via Aerobic Oxidation as a Key Step
Authors
Mitsuru Shindo
Kenji Matsumoto
Copyright Year
2017
Publisher
Springer Singapore
Book
New Horizons of Process Chemistry

Print ISBN: 978-981-10-3420-6

Electronic ISBN: 978-981-10-3421-3

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-981-10-3421-3_2