Top

Journal of Polymer Research

Published in:

01-10-2018 | ORIGINAL PAPER

Microencapsulated self-healing polymers via controlled, surface initiated atom transfer radical polymerization from the surface of graphene oxide

Authors: Junali Handique, Swapan Kumar Dolui

Published in: Journal of Polymer Research | Issue 10/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Polymers were grown directly on the surface of graphene oxide (GO). The method involved the covalent attachment of an atom transfer radical polymerization (ATRP) initiator on the surface of GO followed by the polymerization of methylmethacrylate, styrene or t-butyl acrylate using it as the macroinitiator. The surface initiated poly(methylmethacrylate) (PMMA-IGO) was embedded with microcapsules containing glycidyl methacrylate (GMA) to introduce self-healing property. The polymeric chains grown on the surface of the GO exhibited self-healing behaviour on rupture of the microcapsules. These polymer chains on the surface of GO preserved living characteristics and was able to resume copolymerization with released GMA on rupture of the microcapsules and get infiltrated into the cracks. As a result, the cracked planes were covalently re-bonded, offering almost 92% recovery of strength.

previous article Morphology rearrangement of PEO and PG blocks of amphiphilic copolymer particles in solution affected by FeCl3/acidified water addition

next article Preparation of TiO2 incorporated polyacrylonitrile electrospun nanofibers for adsorption of heavy metal ions

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Guimard NK, Oehlenschlaeger KK, Zhou J, Hilf S, Schmidt FG, Barner-Kowollik C (2012) Current trends in the field of self-healing materials. Macromol Chem Phys 213:131–143CrossRef

Chen X, Dam MA, Ono K, Mal A, Shen H, Nutt SR, Wudl F (2002) A thermally re-mendable cross-linked polymeric material. Science 295:1698–1702CrossRef

Keller MW, White SR, Sottos NR (2007) A self-healing poly (dimethyl siloxane) elastomer. Adv Funct Mater 17:2399–2404CrossRef

Guan Z, Roland JT, Bai JZ, Ma SX, McIntire TM, Nguyen M (2004) Modular domain structure: a biomimetic strategy for advanced polymeric materials. J Am Chem Soc 126:2058–2065CrossRef

Varley RJ, van der Zwaag S (2008) Development of a quasi-static test method to investigate the origin of self-healing in ionomers under ballistic conditions. Polym Test 27:11–19CrossRef

Tadano K, Hirasawa E, Yamamoto H, Yano S (1989) Order-disorder transition of ionic clusters in ionomers. Macromolecules 22:226–233CrossRef

Zare P, Mahrova M, Tojo E, Stojanovic A, Binder WH (2013) Ethylene glycol-based ionic liquids via azide/alkyne click chemistry. J Polym Sci A Polym Chem 51:190–202CrossRef

Gragert M, Schunack M, Binder WH (2011) Azide/alkyne-“click”-reactions of encapsulated reagents: toward self-healing materials. Macromol Rapid Commun 32:419–425CrossRef

Yao L, Yuan YC, Rong MZ, Zhang MQ (2011) Self-healing linear polymers based on RAFT polymerization. Polymer 52:3137–3145CrossRef

10.

Wang HP, Yuan YC, Rong MZ, Zhang MQ (2009) Self-healing of thermoplastics via living polymerization. Macromolecules 43:595–598CrossRef

11.

Kirkby EL, Michaud VJ, Månson JA, Sottos NR, White SR (2009) Performance of self-healing epoxy with microencapsulated healing agent and shape memory alloy wires. Polymer 50:5533–5538CrossRef

12.

Noh HH, Lee JK (2013) Microencapsulation of self-healing agents containing a fluorescent dye. Express Polym Lett 7:88–94CrossRef

13.

Hu J, Chen HQ, Zhang Z (2009) Mechanical properties of melamine formaldehyde microcapsules for self-healing materials. Mater Chem Phys 118:63–70CrossRef

14.

Gao H, Matyjaszewski K (2006) Synthesis of star polymers by a combination of ATRP and the “click” coupling method. Macromolecules 39:4960–4965CrossRef

15.

Ruiz-Muelle AB, Contreras-Cáceres R, Oña-Burgos P, Rodríguez-Dieguez A, López-Romero JM, Fernández I (2018) Polyacrylic acid polymer brushes as substrates for the incorporation of anthraquinone derivatives. Unprecedented application of decorated polymer brushes on organocatalysis. Appl Surf Sci 428:566–578CrossRef

16.

Saikia BJ, Nath BC, Borah C, Dolui SK (2015) Mn2+ anchored CdS polymer nanocomposites: an efficient alternative for Mn2+ doped CdS nanoparticles. J Lumin 168:178–185CrossRef

17.

Yuan YC, Yin T, Rong MZ, Zhang MQ (2008) Self healing in polymers and polymer composites. Concepts, realization and outlook: a review. Express Polym Lett 2:238–250CrossRef

18.

Toomey R, Tirrell M (2008) Functional polymer brushes in aqueous media from self-assembled and surface-initiated polymers. Annu Rev Phys Chem 59:493–517CrossRef

19.

Zhang G, Wu C (2009) Quartz crystal microbalance studies on conformational change of polymer chains at interface. Macromol Rapid Commun 30:328–335CrossRef

20.

Zhou F, Huck WT (2006) Surface grafted polymer brushes as ideal building blocks for “smart” surfaces. Phys Chem Chem Phys 8:3815–3823CrossRef

21.

Lu Y, Wittemann A, Ballauff M (2009) Supramolecular structures generated by spherical polyelectrolyte brushes and their application in catalysis. Macromol Rapid Commun 30:806–815CrossRef

22.

Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev 101:2921–2990CrossRef

23.

Percec V, Guliashvili T, Ladislaw JS, Wistrand A, Stjerndahl A, Sienkowska MJ, Sahoo S (2006) Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 °C. J Am Chem Soc 128:14156–14165CrossRef

24.

Edmondson S, Osborne VL, Huck WT (2004) Polymer brushes via surface-initiated polymerizations. Chem Soc Rev 33:14–22CrossRef

25.

Ding S, Floyd JA, Walters KB (2009) Comparison of surface confined ATRP and SET-LRP syntheses for a series of amino(meth)acrylate polymer brushes on silicon substrates. J Polym Sci A Polym Chem 47:6552–6560CrossRef

26.

Zhu DY, Rong MZ, Zhang MQ (2013) Preparation and characterization of multilayered microcapsule-like microreactor for self-healing polymers. Polymer 54:4227–4236CrossRef

27.

Zhu DY, Wetzel B, Noll A, Rong MZ, Zhang MQ (2013) Thermo-molded self-healing thermoplastics containing multilayer microreactors. J Mater Chem A 1:7191–7198CrossRef

28.

Hummers Jr WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1339CrossRef

29.

Bel, T., Ulku, G., Kizilcan, N., Cimenoglu, H., Yahya, N., & Baydogan, N. (2016). Production of microencapsulate glycidyl methacrylate with melamine formaldehyde resin shell materials. In AIP Conference Proceedings (Vol. 1787, No. 1, p. 050028). AIP Publishing

30.

Hayes SA, Zhang W, Branthwaite M, Jones FR (2007) Self-healing of damage in fibre-reinforced polymer-matrix composites. J R Soc Interface 4:381–387CrossRef

31.

Jung I, Dikin D, Park S, Cai W, Mielke SL, Ruoff RS (2008) Effect of water vapor on electrical properties of individual reduced graphene oxide sheets. J Phys Chem C 112:20264–20268CrossRef

32.

Savin DA, Pyun J, Patterson GD, Kowalewski T, Matyjaszewski K (2002) Synthesis and characterization of silica-graft-polystyrene hybrid nanoparticles: effect of constraint on the glass-transition temperature of spherical polymer brushes. J Polym Sci B Polym Phys 40:2667–2676CrossRef

33.

Ou B, Li D (2007) Preparation of polystyrene/silica nanocomposites by radical copolymerization of styrene with silica macromonomer. Science in China Series B: Chemistry 50:385–391CrossRef

34.

Wei N, Lv C, Xu Z (2014) Wetting of graphene oxide: a molecular dynamics study. Langmuir 30:3572–3578CrossRef

35.

Badri A, Whittaker MR, Zetterlund PB (2012) Modification of graphene/graphene oxide with polymer brushes using controlled/living radical polymerization. J Polym Sci A Polym Chem 50:2981–2992CrossRef

36.

Paredes JI, Villar-Rodil S, Martínez-Alonso A, Tascon JMD (2008) Graphene oxide dispersions in organic solvents. Langmuir 24:10560–10564CrossRef

37.

Shashidhar MS, Bhatt MV (1987) 2-Formylbenzenesulphonyl chloride as a reagent for the protection of phenols. J Chem Soc Chem Commun 9:654–656CrossRef

38.

Brown EN, Kessler MR, Sottos NR, White SR (2003) In situ poly (urea-formaldehyde) microencapsulation of dicyclopentadiene. J Microencapsul 20:719–730CrossRef

39.

Yuan YC, Rong MZ, Zhang MQ (2008) Preparation and characterization of microencapsulated polythiol. Polymer 49:2531–2541CrossRef

40.

Saikia BJ, Dolui SK (2016) Designing semiencapsulation based covalently self-healable poly (methyl methacrylate) composites by atom transfer radical polymerization. J Polym Sci A Polym Chem 54:1842–1851CrossRef

41.

Kim J, Nam DG, Yeum JH, Suh S, Oh W (2015) Characterization of graphite oxide reduced by thermal and/or chemical treatments. Trans Electr Electron Mater 16:274–279CrossRef

42.

Rule JD, Sottos NR, White SR (2007) Effect of microcapsule size on the performance of self-healing polymers. Polymer 48:3520–3529CrossRef

Title: Microencapsulated self-healing polymers via controlled, surface initiated atom transfer radical polymerization from the surface of graphene oxide
Authors: Junali Handique
Swapan Kumar Dolui
Publication date: 01-10-2018
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 10/2018
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-018-1603-6

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 10/2018

Preparation and characterization of modified ultrafiltration nylon 6 membrane modified by poly (acrylamide-co-maleic anhydride)

Calcium phosphate and calcium carbonate mineralization of bioinspired hydrogels based on β-chitin isolated from biomineral of the common cuttlefish (Sepia officinalis, L.)

Covalent hybrid of graphene and silicon dioxide and reinforcing effect in rubber composites

Preparation of TiO2 incorporated polyacrylonitrile electrospun nanofibers for adsorption of heavy metal ions

Influence of end-group modification on interaction of amphiphilic poly(oxyethylene)-b-poly(oxybutylene) block copolymers with ionic surfactants

Investigation of thermal-oil environmental ageing effect on mechanical and thermal behaviours of E-glass fibre/epoxy composites

Premium Partners