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Published in:
Advanced Control of Photochemical Reactions Leading to Synergetic Responses in Molecules and Mesoscopic Materials Read chapter Read first chapter

2020 | OriginalPaper | Chapter

8. Modulations of Electronic States in Plasmonic Strong Coupling Systems and Their Application to Photochemical Reaction Fields

Author : Kosei Ueno

Published in: Photosynergetic Responses in Molecules and Molecular Aggregates

Publisher: Springer Singapore

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Abstract

The modulation of electronic or transition states plays an important role in improving the selectivity and reactivity of chemical reactions. In recent years, the strong coupling between an optical mode and excitons or molecular vibrational modes has received attractive attention as a physical phenomenon for controlling the activation energy of chemical reactions by modulating the electronic state or the vibrational state. In this study, we investigated the spectral properties of hybrid states formed by the strong coupling between plasmon and molecular/intermolecular vibrational modes in the infrared wavelength region. The strong coupling between plasmon and molecular excitonic states have been also studied for demonstrating how to confirm the formation of hybrid states. We developed a highly efficient photochemical reaction field by using modal strong coupling systems between plasmons and different optical modes.

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previous chapter Plasmon-Associated Control of Chemical Reaction at Nanometer Scale
next chapter Photosynergetic Effects on Triplet–Triplet Annihilation Upconversion Processes in Solid Studied by Theory and Experiments
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Metadata
Title
Modulations of Electronic States in Plasmonic Strong Coupling Systems and Their Application to Photochemical Reaction Fields
Author
Kosei Ueno
Copyright Year
2020
Publisher
Springer Singapore
Book
Photosynergetic Responses in Molecules and Molecular Aggregates

Print ISBN: 978-981-15-5450-6

Electronic ISBN: 978-981-15-5451-3

Copyright Year: 2020

DOI
https://doi.org/10.1007/978-981-15-5451-3_8

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