Skip to main content
Top

2019 | OriginalPaper | Chapter

5. Morphology Development and Control

Authors : Roberto Pantani, Felice De Santis, Vito Speranza

Published in: Polypropylene Handbook

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

When referred to polymers, the word morphology is adopted to indicate: crystallinity, which is the relative volume occupied by each of the crystalline phases, including mesophases; dimensions, shape, distribution, and orientation of the crystallites. In this chapter, we describe the morphology of isotactic polypropylene in function of the main variables: temperature, pressure, and flow. This description is carried out not only under the phenomenological point of view but also considering the models which describe the effects of these variables. The chapter describes then the morphology development during injection molding, which is taken as an example of a complex process in which fast cooling rates, high pressures and strong flow fields are involved. A case study in which the simulation of the behavior of polypropylene during injection molding tests is eventually reported.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
5.
52.
go back to reference Fillon B, Lotz B, Thierry A et al. (1993) Self‐nucleation and enhanced nucleation of polymers. Definition of a convenient calorimetric “efficiency scale” and evaluation of nucleating additives in isotactic polypropylene (α phase). J Polym Sci Part B: Polym Phys 31 10):1395–1405. https://doi.org/10.1002/polb.1993.090311014 Fillon B, Lotz B, Thierry A et al. (1993) Self‐nucleation and enhanced nucleation of polymers. Definition of a convenient calorimetric “efficiency scale” and evaluation of nucleating additives in isotactic polypropylene (α phase). J Polym Sci Part B: Polym Phys 31 10):1395–1405. https://​doi.​org/​10.​1002/​polb.​1993.​090311014
62.
go back to reference Balzano L, Rastogi S, Peters GW (2008) Flow induced crystallization in isotactic polypropylene − 1, 3: 2, 4-bis (3, 4-dimethylbenzylidene) sorbitol blends: implications on morphology of shear and phase separation. Macromolecules 41(2):399–408. https://doi.org/10.1021/ma071460gCrossRef Balzano L, Rastogi S, Peters GW (2008) Flow induced crystallization in isotactic polypropylene − 1, 3: 2, 4-bis (3, 4-dimethylbenzylidene) sorbitol blends: implications on morphology of shear and phase separation. Macromolecules 41(2):399–408. https://​doi.​org/​10.​1021/​ma071460gCrossRef
73.
go back to reference Pantani R, Speranza V, Titomanlio G (2018) A criterion for the formation of fibrillar layers in injection molded parts. Int Polym Process. in press Pantani R, Speranza V, Titomanlio G (2018) A criterion for the formation of fibrillar layers in injection molded parts. Int Polym Process. in press
81.
go back to reference Kmetty Á, Bárány T, Karger-Kocsis J (2010) Self-reinforced polymeric materials: a review. Prog Polym Sci 35(10):1288–1310CrossRef Kmetty Á, Bárány T, Karger-Kocsis J (2010) Self-reinforced polymeric materials: a review. Prog Polym Sci 35(10):1288–1310CrossRef
82.
go back to reference Allan P, Bevis M (1987) Multiple live-feed injection moulding. Plastics and rubber processing and applications 7(1):3–10 Allan P, Bevis M (1987) Multiple live-feed injection moulding. Plastics and rubber processing and applications 7(1):3–10
85.
go back to reference Lei J, Jiang C, Shen K (2004) Biaxially self‐reinforced high‐density polyethylene prepared by dynamic packing injection molding. I. Processing parameters and mechanical properties. J Appl polym Sci 93(4):1584–1590 Lei J, Jiang C, Shen K (2004) Biaxially self‐reinforced high‐density polyethylene prepared by dynamic packing injection molding. I. Processing parameters and mechanical properties. J Appl polym Sci 93(4):1584–1590
97.
Metadata
Title
Morphology Development and Control
Authors
Roberto Pantani
Felice De Santis
Vito Speranza
Copyright Year
2019
DOI
https://doi.org/10.1007/978-3-030-12903-3_5

Premium Partners