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2018 | OriginalPaper | Chapter

Morphology of Composite Polymer Latexes: An Update on Synthesis and Applications, Modeling, and Characterization

Authors : Shaghayegh Hamzehlou, Jose Ramon Leiza

Published in: Polymer Reaction Engineering of Dispersed Systems

Publisher: Springer International Publishing

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Abstract

Polymer latexes are used in a wide range of technological and industrial products. Polymer–polymer and polymer–inorganic composite (hybrid) latexes have found specific applications in coatings, adhesives, impact modifiers, and medical diagnostics, among others. Control of latex particle morphology is a key factor to achieve a desired application in structured polymer latex particles. Fundamental knowledge of the effects of different synthetic routes and reaction parameters such as temperature, glass transition temperature, and functional groups is vital to obtain the required morphology of polymer–polymer and polymer–inorganic hybrids. Subsequently an unambiguous characterization of particle morphology is essential, which requires determining the shape of the particles, the surface composition, and the internal composition. In this review, we focus on the most recent developments (of the last 5 years) in the synthesis and application of composite (hybrid) latex particles, including polymer–polymer and polymer–inorganic latex systems. Furthermore, we discuss the most recent modeling efforts to simulate the development of particle morphology in composite polymer latexes synthesized by (mini)emulsion polymerization and the latest advances and improvements in characterization techniques to determine the morphology of composite polymer latexes.

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Literature
1.
go back to reference Asua JM (2007) Polymer reaction engineering. Blackwell, Oxford Asua JM (2007) Polymer reaction engineering. Blackwell, Oxford
2.
go back to reference Asua JM (ed) (1997) Polymeric dispersions: principles and applications1st edn. Springer Netherlands, Dordrecht Asua JM (ed) (1997) Polymeric dispersions: principles and applications1st edn. Springer Netherlands, Dordrecht
3.
go back to reference Urban D, Takamura K (2002) Polymer dispersions and their industrial applications. Wiley-VCH, Weinheim Urban D, Takamura K (2002) Polymer dispersions and their industrial applications. Wiley-VCH, Weinheim
4.
go back to reference Schork FJ, Tsavalas J (2004) The morphology of alkyd/acrylate latexes produced via hybrid miniemulsion polymerization: grafting mechanisms. Colloid Polym Sci 124:126–130 Schork FJ, Tsavalas J (2004) The morphology of alkyd/acrylate latexes produced via hybrid miniemulsion polymerization: grafting mechanisms. Colloid Polym Sci 124:126–130
5.
go back to reference Tsavalas JG, Schork FJ, Landfester K (2004) Particle morphology development in hybrid miniemulsion polymerization. J Coat Technol Res 1:53–63 Tsavalas JG, Schork FJ, Landfester K (2004) Particle morphology development in hybrid miniemulsion polymerization. J Coat Technol Res 1:53–63
6.
go back to reference Herrera V, Pirri R, Asua JM, Leiza JR (2007) Morphology control in polystyrene/pol(methyl methacrylate) composite latex particles. J Polym Sci A Polym Chem 45:2484–2493 Herrera V, Pirri R, Asua JM, Leiza JR (2007) Morphology control in polystyrene/pol(methyl methacrylate) composite latex particles. J Polym Sci A Polym Chem 45:2484–2493
7.
go back to reference Goikoetxea M, Minari RJ, Beristain I, Paulis M, Barandiaran MJ, Asua JM (2009) Polymerization kinetics and microstructure of waterborne acrylic/alkyde nanocomposites synthesized by miniemulsion. J Polym Sci A Polym Chem 47:4871–4885 Goikoetxea M, Minari RJ, Beristain I, Paulis M, Barandiaran MJ, Asua JM (2009) Polymerization kinetics and microstructure of waterborne acrylic/alkyde nanocomposites synthesized by miniemulsion. J Polym Sci A Polym Chem 47:4871–4885
8.
go back to reference Li CY, Chiu WY, Don TM (2007) Morphology of PU/PMMA hybrid particles from miniemulsion polymerization: thermodynamic consideration. J Polym Sci A Polym Chem 45:3359–3369 Li CY, Chiu WY, Don TM (2007) Morphology of PU/PMMA hybrid particles from miniemulsion polymerization: thermodynamic consideration. J Polym Sci A Polym Chem 45:3359–3369
9.
go back to reference Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. I. Dispersion of titanium dioxide particles in organic media using OLOA 370 as stabilizer. J Polym Sci A Polym Chem 38:4419–4430 Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. I. Dispersion of titanium dioxide particles in organic media using OLOA 370 as stabilizer. J Polym Sci A Polym Chem 38:4419–4430
10.
go back to reference Chu HH, Ou ED (2000) Emulsion polymerization of 2-hydroxyethyl methacrylate and partition of monomer between particles and water phase. Polym Bull 44:337–344 Chu HH, Ou ED (2000) Emulsion polymerization of 2-hydroxyethyl methacrylate and partition of monomer between particles and water phase. Polym Bull 44:337–344
11.
go back to reference Reyes Y, Akhmatskaya E, Leiza JR, Asua JM (2013) Particle morphology. In: van Herk AM (ed) Chemistry and technology of emulsion polymerization2nd edn. Wiley, Singapore Reyes Y, Akhmatskaya E, Leiza JR, Asua JM (2013) Particle morphology. In: van Herk AM (ed) Chemistry and technology of emulsion polymerization2nd edn. Wiley, Singapore
12.
go back to reference Sundberg DC, Durant YG (2003) Latex particle morphology, fundamental aspects: a review. Polym React Eng 11:379–432 Sundberg DC, Durant YG (2003) Latex particle morphology, fundamental aspects: a review. Polym React Eng 11:379–432
13.
go back to reference Schuler B, Baumstark R, Kirsch S, Pfau A, Sandor M, Zosel A (2000) Structure and properties of multiphase particles and their impact on the performance of architectural coatings. Prog Org Coat 40:139–150 Schuler B, Baumstark R, Kirsch S, Pfau A, Sandor M, Zosel A (2000) Structure and properties of multiphase particles and their impact on the performance of architectural coatings. Prog Org Coat 40:139–150
14.
go back to reference Goikoetxea M, Reyes Y, de las Heras Alarcón CM, Minari RJ, Beristain I, Paulis M, Barandiaran MJ, Keddie JL, Asua JM (2012) Transformation of waterborne hybrid polymer particles into films: morphology development and Modeling. Polymer 53:1098–1108 Goikoetxea M, Reyes Y, de las Heras Alarcón CM, Minari RJ, Beristain I, Paulis M, Barandiaran MJ, Keddie JL, Asua JM (2012) Transformation of waterborne hybrid polymer particles into films: morphology development and Modeling. Polymer 53:1098–1108
15.
go back to reference Paulis M, Asua JM (2016) Knowledge-based production of waterborne hybrid polymer materials. Macromol React Eng 10:8–21 Paulis M, Asua JM (2016) Knowledge-based production of waterborne hybrid polymer materials. Macromol React Eng 10:8–21
16.
go back to reference van Herk AM, Landfester K (eds) (2010) Hybrid latex particles: preparation with (mini)emulsion polymerization. Springer, Berlin van Herk AM, Landfester K (eds) (2010) Hybrid latex particles: preparation with (mini)emulsion polymerization. Springer, Berlin
17.
go back to reference Asua JM (2002) Miniemulsion polymerization. Prog Polym Sci 27:1283–1346 Asua JM (2002) Miniemulsion polymerization. Prog Polym Sci 27:1283–1346
18.
go back to reference Asua JM (2014) Challenges for industrialization of miniemulsion polymerization. Prog Polym Sci 39:1797–1826 Asua JM (2014) Challenges for industrialization of miniemulsion polymerization. Prog Polym Sci 39:1797–1826
19.
go back to reference Stubbs JM, Sundberg DC (2008) Core-shell and other multiphase latex particles-confirming their morphologies and relating those to synthesis variables. J Coat Technol Res 5:169–180 Stubbs JM, Sundberg DC (2008) Core-shell and other multiphase latex particles-confirming their morphologies and relating those to synthesis variables. J Coat Technol Res 5:169–180
20.
go back to reference Cheng Y, Wang Z (2013) Fluorinated poly(isobornyl methacrylate-co-butyl acrylate) core-shell latex nanoparticles: synthesis, morphology and wettability of films. Polymer 54:3047–3054 Cheng Y, Wang Z (2013) Fluorinated poly(isobornyl methacrylate-co-butyl acrylate) core-shell latex nanoparticles: synthesis, morphology and wettability of films. Polymer 54:3047–3054
21.
go back to reference Bonnefond, A.; González, E.; Asua, J. M.; Leiza, J. R.; Ieva, E.; Brinati, G.; Carella, S.; Marrani, A.; Veneroni, A.; Kiwi, J.; et al. Stable photocatalytic paints prepared from hybrid core-shell fluorinated/acrylic/TiO2 waterborne dispersions. Crystals 2016, 6(10), 136 doi:10.3390/cryst6100136. Bonnefond, A.; González, E.; Asua, J. M.; Leiza, J. R.; Ieva, E.; Brinati, G.; Carella, S.; Marrani, A.; Veneroni, A.; Kiwi, J.; et al. Stable photocatalytic paints prepared from hybrid core-shell fluorinated/acrylic/TiO2 waterborne dispersions. Crystals 2016, 6(10), 136 doi:10.​3390/​cryst6100136.
22.
go back to reference Tan C, Tirri T, Wilen C-E (2016) The effect of core–shell particle morphology on adhesive properties of poly(styrene-co-butyl acrylate). Int J Adhes Adhes 66:104–113 Tan C, Tirri T, Wilen C-E (2016) The effect of core–shell particle morphology on adhesive properties of poly(styrene-co-butyl acrylate). Int J Adhes Adhes 66:104–113
23.
go back to reference Lopez A, Degrandi-Contraires E, Canetta E, Creton C, Keddie JL, Asua JM (2011) Waterborne polyurethane-acrylic hybrid nanoparticles by miniemulsion polymerization: applications in pressure-sensitive adhesives. Langmuir 27:3878–3788PubMed Lopez A, Degrandi-Contraires E, Canetta E, Creton C, Keddie JL, Asua JM (2011) Waterborne polyurethane-acrylic hybrid nanoparticles by miniemulsion polymerization: applications in pressure-sensitive adhesives. Langmuir 27:3878–3788PubMed
24.
go back to reference Lopez A, Degrandi E, Canetta E, Keddie JL, Creton C, Asua JM (2011) Simultaneous free radical and addition miniemulsion polymerization: effect of the diol on the microstructure of polyurethane-acrylic pressure-sensitive adhesives. Polymer 52:3021–3030 Lopez A, Degrandi E, Canetta E, Keddie JL, Creton C, Asua JM (2011) Simultaneous free radical and addition miniemulsion polymerization: effect of the diol on the microstructure of polyurethane-acrylic pressure-sensitive adhesives. Polymer 52:3021–3030
25.
go back to reference Lopez A, Reyes Y, Degrandi-Contraires E, Canetta E, Creton C, Asua JM (2013) Waterborne hybrid polymer particles: tuning of the adhesive performance by controlling the hybrid microstructure. Eur Polym J 49:1541–1552 Lopez A, Reyes Y, Degrandi-Contraires E, Canetta E, Creton C, Asua JM (2013) Waterborne hybrid polymer particles: tuning of the adhesive performance by controlling the hybrid microstructure. Eur Polym J 49:1541–1552
26.
go back to reference Hamzehlou S, Ballard N, Carretero P, Paulis M, Asua JM, Reyes Y, Leiza JR (2014) Mechanistic investigation of the simultaneous addition and free-radical polymerization in batch miniemulsion droplets: Monte Carlo simulation versus experimental data in polyurethane/acrylic systems. Polymer 55:4801–4811 Hamzehlou S, Ballard N, Carretero P, Paulis M, Asua JM, Reyes Y, Leiza JR (2014) Mechanistic investigation of the simultaneous addition and free-radical polymerization in batch miniemulsion droplets: Monte Carlo simulation versus experimental data in polyurethane/acrylic systems. Polymer 55:4801–4811
27.
go back to reference Degrandi-Contraires E, Udagama R, McKenna T, Bourgeat-Lami E, Plummer CJG, Creton C (2014) Influence of composition on the morphology of polyurethane/acrylic latex particles and adhesive films. Int J Adhes Adhes 50:176–182 Degrandi-Contraires E, Udagama R, McKenna T, Bourgeat-Lami E, Plummer CJG, Creton C (2014) Influence of composition on the morphology of polyurethane/acrylic latex particles and adhesive films. Int J Adhes Adhes 50:176–182
28.
go back to reference Bourgeat-Lami E (2003) Hollow particles: synthetic pathways and potential applications. In: Elaissari A (ed) Colloidal polymers. Surfactant science series. Marcel Dekker, New York, pp 189–223 Bourgeat-Lami E (2003) Hollow particles: synthetic pathways and potential applications. In: Elaissari A (ed) Colloidal polymers. Surfactant science series. Marcel Dekker, New York, pp 189–223
29.
go back to reference Pan TY, Lee CF, Chu CH (2013) Synthesis and characteristics of poly(methacrylic acid-co-N-isopropylacrylamide) thermosensitive composite hollow latex particles and their application as drug carriers. J Polym Sci A Polym Chem 51:5203–5214 Pan TY, Lee CF, Chu CH (2013) Synthesis and characteristics of poly(methacrylic acid-co-N-isopropylacrylamide) thermosensitive composite hollow latex particles and their application as drug carriers. J Polym Sci A Polym Chem 51:5203–5214
30.
go back to reference Jiang YM, Li BT, Wang WJ, Xu M, Kan CY (2014) Effect of the shell crosslinking level and core/shell ratio on the morphology of latex particles in the preparation of hollow latexes. Chin J Polym Sci 32:177–186 Jiang YM, Li BT, Wang WJ, Xu M, Kan CY (2014) Effect of the shell crosslinking level and core/shell ratio on the morphology of latex particles in the preparation of hollow latexes. Chin J Polym Sci 32:177–186
31.
go back to reference Deng W, Ji W, Jiang Y, Kan C (2013) Influence of unsaturated acid monomer on the morphology of latex particles in the preparation of hollow latex via the alkali post-treatment. J Appl Polym Sci 127:651–658 Deng W, Ji W, Jiang Y, Kan C (2013) Influence of unsaturated acid monomer on the morphology of latex particles in the preparation of hollow latex via the alkali post-treatment. J Appl Polym Sci 127:651–658
32.
go back to reference Yuan T, Shao Q, Hu J, Wang F, Tu W (2015) Effect of the intermediate layer-core ratio on the morphology and opacity ability of hollow latex particles. J Appl Polym Sci 132:1–7 Yuan T, Shao Q, Hu J, Wang F, Tu W (2015) Effect of the intermediate layer-core ratio on the morphology and opacity ability of hollow latex particles. J Appl Polym Sci 132:1–7
33.
go back to reference Blenner D, Stubbs J, Sundberg D (2017) Multi-lobed composite polymer nanoparticles prepared by conventional emulsion polymerization. Polymer 114:54–63 Blenner D, Stubbs J, Sundberg D (2017) Multi-lobed composite polymer nanoparticles prepared by conventional emulsion polymerization. Polymer 114:54–63
34.
go back to reference Niu Q, Pan M, Yuan J, Liu X, Wang X, Yu H (2013) Anisotropic nanoparticles with controllable morphologies from non-cross-linked seeded emulsion polymerization. Macromol Rapid Commun 34:1363–1367PubMed Niu Q, Pan M, Yuan J, Liu X, Wang X, Yu H (2013) Anisotropic nanoparticles with controllable morphologies from non-cross-linked seeded emulsion polymerization. Macromol Rapid Commun 34:1363–1367PubMed
35.
go back to reference Li K, Zeng X, Li H, Lai X (2015) Role of acrylic acid in the synthesis of core-shell fluorine-containing polyacrylate latex with spherical and plum blossom-like morphology. J Appl Polym Sci 132:42527–42534 Li K, Zeng X, Li H, Lai X (2015) Role of acrylic acid in the synthesis of core-shell fluorine-containing polyacrylate latex with spherical and plum blossom-like morphology. J Appl Polym Sci 132:42527–42534
36.
go back to reference Chang Y, Pan M, Yuan J, Liu Y, Wang X, Jiang P, Wang Y, Zhong G-J, Li Z-M (2015) Morphology and film performance of phthalate-free plasticized poly(vinyl chloride) composite particles via the graft copolymerization of acrylate swelling flower-like latex particles. RSC Adv 5:40076–40087 Chang Y, Pan M, Yuan J, Liu Y, Wang X, Jiang P, Wang Y, Zhong G-J, Li Z-M (2015) Morphology and film performance of phthalate-free plasticized poly(vinyl chloride) composite particles via the graft copolymerization of acrylate swelling flower-like latex particles. RSC Adv 5:40076–40087
37.
go back to reference Paulis M, Leiza JR (2010) Polymer/clay nanocomposites through emulsion and suspension polymerization. In: Mittal V (ed) Advances in polymer nanocomposite technology. Nova Science, New York, pp 53–101 Paulis M, Leiza JR (2010) Polymer/clay nanocomposites through emulsion and suspension polymerization. In: Mittal V (ed) Advances in polymer nanocomposite technology. Nova Science, New York, pp 53–101
38.
go back to reference Mičušík M, Reyes Y, Paulis M, Leiza JR (2010) Polymer–clay nanocomposites by miniemulsion polymerization. In: Mittal V (ed) Polymer nanocomposites by emulsion and suspension polymerization. Royal Society of Chemistry, London Mičušík M, Reyes Y, Paulis M, Leiza JR (2010) Polymer–clay nanocomposites by miniemulsion polymerization. In: Mittal V (ed) Polymer nanocomposites by emulsion and suspension polymerization. Royal Society of Chemistry, London
39.
go back to reference Weiss CK, Landfester K (2010) Miniemulsion polymerization as a means to encapsulate organic and inorganic materials. Adv Polym Sci 233:185–236 Weiss CK, Landfester K (2010) Miniemulsion polymerization as a means to encapsulate organic and inorganic materials. Adv Polym Sci 233:185–236
40.
go back to reference Bourgeat-Lami E, Lansalot M (2010) Organic/inorganic composite latexes: the marriage of emulsion polymerization and inorganic chemistry. Adv Polym Sci 233:53–123 Bourgeat-Lami E, Lansalot M (2010) Organic/inorganic composite latexes: the marriage of emulsion polymerization and inorganic chemistry. Adv Polym Sci 233:53–123
41.
go back to reference Faucheu J, Gauthier C, Chazeau L, Cavaillé JY, Mellon V, Lami EB (2010) Miniemulsion polymerization for synthesis of structured clay/polymer nanocomposites: short review and recent advances. Polymer 51:6–17 Faucheu J, Gauthier C, Chazeau L, Cavaillé JY, Mellon V, Lami EB (2010) Miniemulsion polymerization for synthesis of structured clay/polymer nanocomposites: short review and recent advances. Polymer 51:6–17
42.
go back to reference Diaconu G, Micusik M, Bonnefond A, Paulis M, Leiza JR (2009) Macroinitiator and macromonomer modified montmorillonite for the synthesis of acrylic/MMT nanocomposite latexes. Macromolecules 42:3316–3325 Diaconu G, Micusik M, Bonnefond A, Paulis M, Leiza JR (2009) Macroinitiator and macromonomer modified montmorillonite for the synthesis of acrylic/MMT nanocomposite latexes. Macromolecules 42:3316–3325
43.
go back to reference Mičušík M, Bonnefond A, Reyes Y, Bogner A, Chazeau L, Plummer C, Paulis M, Leiza JR (2010) Morphology of polymer/clay latex particles synthesized by miniemulsion polymerization: modeling and experimental results. Macromol React Eng 4:432–444 Mičušík M, Bonnefond A, Reyes Y, Bogner A, Chazeau L, Plummer C, Paulis M, Leiza JR (2010) Morphology of polymer/clay latex particles synthesized by miniemulsion polymerization: modeling and experimental results. Macromol React Eng 4:432–444
44.
go back to reference Mballa MAM, Heuts JPA, Van Herk AM (2013) Encapsulation of non-chemically modified montmorillonite clay platelets via emulsion polymerization. Colloid Polym Sci 291:501–513 Mballa MAM, Heuts JPA, Van Herk AM (2013) Encapsulation of non-chemically modified montmorillonite clay platelets via emulsion polymerization. Colloid Polym Sci 291:501–513
45.
go back to reference Greesh N, Ray SS (2016) Impact of non-ionic surfactant chemical structure on morphology and stability of polystyrene nanocomposite latex. Colloid Polym Sci 294:157–170 Greesh N, Ray SS (2016) Impact of non-ionic surfactant chemical structure on morphology and stability of polystyrene nanocomposite latex. Colloid Polym Sci 294:157–170
46.
go back to reference Wang S, Tian X, Sun J, Liu J, Duan J (2016) Morphology and mechanical properties of natural rubber latex films modified by exfoliated Na-montmorillonite/polyethyleneimine-G-poly (methyl methacrylate) nanocomposites. J Appl Polym Sci 133:1–8 Wang S, Tian X, Sun J, Liu J, Duan J (2016) Morphology and mechanical properties of natural rubber latex films modified by exfoliated Na-montmorillonite/polyethyleneimine-G-poly (methyl methacrylate) nanocomposites. J Appl Polym Sci 133:1–8
47.
go back to reference Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. II. Preparation and characterization of styrene miniemulsion droplets containing TiO2 particles. J Polym Sci A Polym Chem 38:4431–4440 Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. II. Preparation and characterization of styrene miniemulsion droplets containing TiO2 particles. J Polym Sci A Polym Chem 38:4431–4440
48.
go back to reference Aguirre M, Johansson Salazar-Sandoval E, Johansson M, Ahniyaz A, Paulis M, Leiza JR (2014) Hybrid acrylic/CeO2 nanocomposites using hydrophilic, spherical and high aspect ratio CeO2 nanoparticles. J Mater Chem A 2:20280–20287 Aguirre M, Johansson Salazar-Sandoval E, Johansson M, Ahniyaz A, Paulis M, Leiza JR (2014) Hybrid acrylic/CeO2 nanocomposites using hydrophilic, spherical and high aspect ratio CeO2 nanoparticles. J Mater Chem A 2:20280–20287
49.
go back to reference Aguirre M, Barrado M, Iturrondobeitia M, Okariz A, Guraya T, Paulis M, Leiza JR (2015) Film forming hybrid acrylic/ZnO latexes with excellent UV absorption capacity. Chem Eng J 270:300–308 Aguirre M, Barrado M, Iturrondobeitia M, Okariz A, Guraya T, Paulis M, Leiza JR (2015) Film forming hybrid acrylic/ZnO latexes with excellent UV absorption capacity. Chem Eng J 270:300–308
50.
go back to reference Nguyen D, Zondanos HS, Farrugia JM, Serelis AK, Such CH, Hawkett BS (2008) Pigment encapsulation by emulsion polymerization using macro-RAFT copolymers. Langmuir 24:2140–2150PubMed Nguyen D, Zondanos HS, Farrugia JM, Serelis AK, Such CH, Hawkett BS (2008) Pigment encapsulation by emulsion polymerization using macro-RAFT copolymers. Langmuir 24:2140–2150PubMed
51.
go back to reference Aguirre M, Paulis M, Leiza JR (2013) UV screening clear coats based on encapsulated CeO2 hybrid latexes. J Mater Chem A 1:3155–3162 Aguirre M, Paulis M, Leiza JR (2013) UV screening clear coats based on encapsulated CeO2 hybrid latexes. J Mater Chem A 1:3155–3162
52.
go back to reference Bourgeat-Lami E, Duguet E (2006) Polymer encapsulation of inorganic particles. In: Ghosh SK (ed) Functional coatings: by polymer microencapsulation. Wiley-VCH, Weinheim, pp 85–152 Bourgeat-Lami E, Duguet E (2006) Polymer encapsulation of inorganic particles. In: Ghosh SK (ed) Functional coatings: by polymer microencapsulation. Wiley-VCH, Weinheim, pp 85–152
53.
go back to reference Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. III. Characterization of encapsulation. J Polym Sci A Polym Chem 38:4441–4450 Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization. III. Characterization of encapsulation. J Polym Sci A Polym Chem 38:4441–4450
54.
go back to reference De San Luis A, Bonnefond A, Barrado M, Guraya T, Iturrondobeitia M, Okariz A, Paulis M, Leiza JR (2017) Toward the minimization of fluorescence loss in hybrid cross-linked core-shell PS/QD/PMMA nanoparticles: effect of the shell thickness. Chem Eng J 313:261–269 De San Luis A, Bonnefond A, Barrado M, Guraya T, Iturrondobeitia M, Okariz A, Paulis M, Leiza JR (2017) Toward the minimization of fluorescence loss in hybrid cross-linked core-shell PS/QD/PMMA nanoparticles: effect of the shell thickness. Chem Eng J 313:261–269
55.
go back to reference Fleischhaker F, Zentel R (2005) Photonic crystals from core-shell colloids with incorporated highly fluorescent quantum dots. Chem Mater 17:1346–1351 Fleischhaker F, Zentel R (2005) Photonic crystals from core-shell colloids with incorporated highly fluorescent quantum dots. Chem Mater 17:1346–1351
56.
go back to reference Joumaa N, Lansalot M, Théretz A, Elaissari A, Sukhanova A, Artemyev M, Nabiev I, Cohen JHM (2006) Synthesis of quantum dot-tagged submicrometer polystyrene particles by miniemulsion polymerization. Langmuir 22:1810–1816PubMed Joumaa N, Lansalot M, Théretz A, Elaissari A, Sukhanova A, Artemyev M, Nabiev I, Cohen JHM (2006) Synthesis of quantum dot-tagged submicrometer polystyrene particles by miniemulsion polymerization. Langmuir 22:1810–1816PubMed
57.
go back to reference González E, Bonnefond A, Barrado M, Casado Barrasa AM, Asua JM, Leiza JR (2015) Photoactive self-cleaning polymer coatings by TiO2 nanoparticle Pickering miniemulsion polymerization. Chem Eng J 281:209–217 González E, Bonnefond A, Barrado M, Casado Barrasa AM, Asua JM, Leiza JR (2015) Photoactive self-cleaning polymer coatings by TiO2 nanoparticle Pickering miniemulsion polymerization. Chem Eng J 281:209–217
58.
go back to reference Bonnefond A, Gonzalez E, Asua JM, Leiza JR, Kiwi J, Pulgarin C, Rtimi S (2015) New evidence for hybrid acrylic/TiO2 films inducing bacterial inactivation under low intensity simulated sunlight. Colloids Surf B Biointerfaces 135:1–7PubMed Bonnefond A, Gonzalez E, Asua JM, Leiza JR, Kiwi J, Pulgarin C, Rtimi S (2015) New evidence for hybrid acrylic/TiO2 films inducing bacterial inactivation under low intensity simulated sunlight. Colloids Surf B Biointerfaces 135:1–7PubMed
59.
go back to reference Landfester K, Weiss CK (2010) Encapsulation by miniemulsion polymerization. Adv Polym Sci 229:1–49 Landfester K, Weiss CK (2010) Encapsulation by miniemulsion polymerization. Adv Polym Sci 229:1–49
60.
go back to reference Kobayashi S, Mullen K (eds) (2014) Encyclopedia of polymeric nanomaterials. Springer-Verlag, Berlin Kobayashi S, Mullen K (eds) (2014) Encyclopedia of polymeric nanomaterials. Springer-Verlag, Berlin
61.
go back to reference Ali SI, Heuts JPA, Hawkett BS, Van Herk AM (2009) Polymer encapsulated Gibbsite nanoparticles: efficient preparation of anisotropic composite latex particles by RAFT-based starved feed emulsion polymerization. Langmuir 25:10523–10533PubMed Ali SI, Heuts JPA, Hawkett BS, Van Herk AM (2009) Polymer encapsulated Gibbsite nanoparticles: efficient preparation of anisotropic composite latex particles by RAFT-based starved feed emulsion polymerization. Langmuir 25:10523–10533PubMed
62.
go back to reference Costoyas A, Ramos J, Forcada J (2009) Encapsulation of silica nanoparticles by miniemulsion polymerization. J Polym Sci A Polym Chem 47:935–939 Costoyas A, Ramos J, Forcada J (2009) Encapsulation of silica nanoparticles by miniemulsion polymerization. J Polym Sci A Polym Chem 47:935–939
63.
go back to reference Reyes Y, Peruzzo PJ, Ferna M, Paulis M, Leiza JR (2013) Encapsulation of clay within polymer particles in a high-solid content aqueous dispersion. Langmuir 29:9849–9856PubMed Reyes Y, Peruzzo PJ, Ferna M, Paulis M, Leiza JR (2013) Encapsulation of clay within polymer particles in a high-solid content aqueous dispersion. Langmuir 29:9849–9856PubMed
64.
go back to reference Mballa Mballa MA, Heuts JPA, Van Herk AM (2013) The effect of clay on the morphology of multiphase latex particles. Colloid Polym Sci 291:1419–1427 Mballa Mballa MA, Heuts JPA, Van Herk AM (2013) The effect of clay on the morphology of multiphase latex particles. Colloid Polym Sci 291:1419–1427
65.
go back to reference Nguyen D, Such CH, Hawkett BS (2013) Polymer coating of carboxylic acid functionalized multiwalled carbon nanotubes via reversible addition-fragmentation chain transfer mediated emulsion polymerization. J Polym Sci A Polym Chem 51:250–257 Nguyen D, Such CH, Hawkett BS (2013) Polymer coating of carboxylic acid functionalized multiwalled carbon nanotubes via reversible addition-fragmentation chain transfer mediated emulsion polymerization. J Polym Sci A Polym Chem 51:250–257
66.
go back to reference Huynh VT, Nguyen D, Such CH, Hawkett BS (2015) Polymer coating of graphene oxide via reversible addition-fragmentation chain transfer mediated emulsion polymerization. J Polym Sci A Polym Chem 53:1413–1421 Huynh VT, Nguyen D, Such CH, Hawkett BS (2015) Polymer coating of graphene oxide via reversible addition-fragmentation chain transfer mediated emulsion polymerization. J Polym Sci A Polym Chem 53:1413–1421
67.
go back to reference Loiko OP, Spoelstra AB, van Herk AM, Meuldijk J, Heuts JPA (2016) An ATRP-based approach towards water-borne anisotropic polymer–Gibbsite nanocomposites. Polym Chem 7:3383–3391 Loiko OP, Spoelstra AB, van Herk AM, Meuldijk J, Heuts JPA (2016) An ATRP-based approach towards water-borne anisotropic polymer–Gibbsite nanocomposites. Polym Chem 7:3383–3391
68.
go back to reference Loiko OP, Spoelstra AB, van Herk AM, Meuldijk J, Heuts JPA (2016) Encapsulation of unmodified Gibbsite via conventional emulsion polymerisation using charged co-oligomers. RSC Adv 6:80748–80755 Loiko OP, Spoelstra AB, van Herk AM, Meuldijk J, Heuts JPA (2016) Encapsulation of unmodified Gibbsite via conventional emulsion polymerisation using charged co-oligomers. RSC Adv 6:80748–80755
69.
go back to reference Cenacchi A, Pearson S, Kostadinova D, Leroux F, D’Agosto F, Lansalot M, Bourgeat-Lami E, Prevot V (2017) Nanocomposite latexes containing layered double hydroxides via RAFT-assisted encapsulating emulsion polymerization. Polym Chem 8:1233–1243 Cenacchi A, Pearson S, Kostadinova D, Leroux F, D’Agosto F, Lansalot M, Bourgeat-Lami E, Prevot V (2017) Nanocomposite latexes containing layered double hydroxides via RAFT-assisted encapsulating emulsion polymerization. Polym Chem 8:1233–1243
70.
go back to reference Aguirre M, Paulis M, Leiza JR, Guraya T, Iturrondobeitia M, Okariz A, Ibarretxe J (2013) High-solids-content hybrid acrylic/CeO2 latexes with encapsulated morphology assessed by 3D-TEM. Macromol Chem Phys 214:2157–2164 Aguirre M, Paulis M, Leiza JR, Guraya T, Iturrondobeitia M, Okariz A, Ibarretxe J (2013) High-solids-content hybrid acrylic/CeO2 latexes with encapsulated morphology assessed by 3D-TEM. Macromol Chem Phys 214:2157–2164
71.
go back to reference Aguirre M, Paulis M, Barrado M, Iturrondobeitia M, Okariz A, Guraya T, Ibarretxe J, Leiza JR (2014) Evolution of particle morphology during the synthesis of hybrid acrylic/CeO2 nanocomposites by miniemulsion polymerization. J Polym Sci A Polym Chem 53:792–799 Aguirre M, Paulis M, Barrado M, Iturrondobeitia M, Okariz A, Guraya T, Ibarretxe J, Leiza JR (2014) Evolution of particle morphology during the synthesis of hybrid acrylic/CeO2 nanocomposites by miniemulsion polymerization. J Polym Sci A Polym Chem 53:792–799
72.
go back to reference Aguirrre M, Paulis M, Leiza JR (2014) Particle nucleation and growth in seeded semibatch miniemulsion polymerization of hybrid CeO2/acrylic latexes. Polymer 55:752–761 Aguirrre M, Paulis M, Leiza JR (2014) Particle nucleation and growth in seeded semibatch miniemulsion polymerization of hybrid CeO2/acrylic latexes. Polymer 55:752–761
73.
go back to reference Garnier J, Warnant J, Lacroix-Desmazes P, Dufils PE, Vinas J, van Herk A (2013) Sulfonated macro-RAFT agents for the surfactant-free synthesis of cerium oxide-based hybrid latexes. J Colloid Interface Sci 407:273–281PubMed Garnier J, Warnant J, Lacroix-Desmazes P, Dufils PE, Vinas J, van Herk A (2013) Sulfonated macro-RAFT agents for the surfactant-free synthesis of cerium oxide-based hybrid latexes. J Colloid Interface Sci 407:273–281PubMed
74.
go back to reference Warnant J, Garnier J, van Herk A, Dufils P-E, Vinas J, Lacroix-Desmazes P (2013) A CeO2/PVDC hybrid latex mediated by a phosphonated macro-RAFT agent. Polym Chem 4:5656 Warnant J, Garnier J, van Herk A, Dufils P-E, Vinas J, Lacroix-Desmazes P (2013) A CeO2/PVDC hybrid latex mediated by a phosphonated macro-RAFT agent. Polym Chem 4:5656
75.
go back to reference Désert A, Morele J, Taveau J-C, Lambert O, Lansalot M, Bourgeat-Lami E, Thill A, Spalla O, Belloni L, Ravaine S, et al. (2016) Multipod-like silica/polystyrene clusters. Nanoscale 8:5454–5469PubMed Désert A, Morele J, Taveau J-C, Lambert O, Lansalot M, Bourgeat-Lami E, Thill A, Spalla O, Belloni L, Ravaine S, et al. (2016) Multipod-like silica/polystyrene clusters. Nanoscale 8:5454–5469PubMed
76.
go back to reference Chomette C, Duguet E, Mornet S, Yammine E, Manoharan VN, Schade NB, Hubert C, Ravaine S, Perro A, Tréguer-Delapierre M (2016) Templated growth of gold satellites on dimpled silica cores. Faraday Discuss 191:105–116PubMed Chomette C, Duguet E, Mornet S, Yammine E, Manoharan VN, Schade NB, Hubert C, Ravaine S, Perro A, Tréguer-Delapierre M (2016) Templated growth of gold satellites on dimpled silica cores. Faraday Discuss 191:105–116PubMed
77.
go back to reference Negrete-Herrera N, Putaux JL, David L, Bourgeat-Lami E (2006) Polymer/laponite composite colloids through emulsion polymerization: influence of the clay modification level on particle morphology. Macromolecules 39:9177–9184 Negrete-Herrera N, Putaux JL, David L, Bourgeat-Lami E (2006) Polymer/laponite composite colloids through emulsion polymerization: influence of the clay modification level on particle morphology. Macromolecules 39:9177–9184
78.
go back to reference Bon SAF, Colver PJ (2007) Pickering miniemulsion polymerization using Laponite clay as a stabilizer. Langmuir 23:8316–8322PubMed Bon SAF, Colver PJ (2007) Pickering miniemulsion polymerization using Laponite clay as a stabilizer. Langmuir 23:8316–8322PubMed
79.
go back to reference Sheibat-Othman N, Bourgeat-Lami E (2009) Use of silica particles for the formation of organic-inorganic particles by surfactant-free emulsion polymerization. Langmuir 25:10121–10133PubMed Sheibat-Othman N, Bourgeat-Lami E (2009) Use of silica particles for the formation of organic-inorganic particles by surfactant-free emulsion polymerization. Langmuir 25:10121–10133PubMed
80.
go back to reference Colver PJ, Colard CAL, Bon SAF (2008) Multilayered nanocomposite polymer colloids using emulsion polymerization stabilized by solid particles. J Am Chem Soc 130:16850–16851PubMed Colver PJ, Colard CAL, Bon SAF (2008) Multilayered nanocomposite polymer colloids using emulsion polymerization stabilized by solid particles. J Am Chem Soc 130:16850–16851PubMed
81.
go back to reference Xu Z, Xia A, Wang C, Yang W, Fu S (2007) Synthesis of raspberry-like magnetic polystyrene microspheres. Mater Chem Phys 103:494–499 Xu Z, Xia A, Wang C, Yang W, Fu S (2007) Synthesis of raspberry-like magnetic polystyrene microspheres. Mater Chem Phys 103:494–499
82.
go back to reference Zgheib N, Putaux J-L, Thill A, D’Agosto F, Lansalot M, Bourgeat-Lam E (2012) Stabilization of miniemulsion droplets by cerium oxide nanoparticles: a step toward the elaboration of armored composite. Langmuir 28:6163–6174PubMed Zgheib N, Putaux J-L, Thill A, D’Agosto F, Lansalot M, Bourgeat-Lam E (2012) Stabilization of miniemulsion droplets by cerium oxide nanoparticles: a step toward the elaboration of armored composite. Langmuir 28:6163–6174PubMed
83.
go back to reference Liu Y, Chen X, Wang R, Xin JH (2006) Polymer microspheres stabilized by Titania nanoparticles. Mater Lett 60:3731–3734 Liu Y, Chen X, Wang R, Xin JH (2006) Polymer microspheres stabilized by Titania nanoparticles. Mater Lett 60:3731–3734
84.
go back to reference Chen JH, Cheng CY, Chiu WY, Lee CF, Liang NY (2008) Synthesis of ZnO/polystyrene composites particles by Pickering emulsion polymerization. Eur Polym J 44:3271–3279 Chen JH, Cheng CY, Chiu WY, Lee CF, Liang NY (2008) Synthesis of ZnO/polystyrene composites particles by Pickering emulsion polymerization. Eur Polym J 44:3271–3279
85.
go back to reference Bonnefond A, Mičušík M, Paulis M, Leiza JR, Teixeira RFA, Bon SAF (2013) Morphology and properties of waterborne adhesives made from hybrid polyacrylic/montmorillonite clay colloidal dispersions showing improved tack and shear resistance. Colloid Polym Sci 291:167–180 Bonnefond A, Mičušík M, Paulis M, Leiza JR, Teixeira RFA, Bon SAF (2013) Morphology and properties of waterborne adhesives made from hybrid polyacrylic/montmorillonite clay colloidal dispersions showing improved tack and shear resistance. Colloid Polym Sci 291:167–180
86.
go back to reference González-Matheus K, Leal GP, Asua JM (2014) Pickering-stabilized latexes with high silica incorporation and improved salt stability. Part Part Syst Charact 31:94–100 González-Matheus K, Leal GP, Asua JM (2014) Pickering-stabilized latexes with high silica incorporation and improved salt stability. Part Part Syst Charact 31:94–100
87.
go back to reference Fischer V, Bannwarth MB, Jakob G, Landfester K, Muñoz-Espí R (2013) Luminescent and magnetoresponsive multifunctional chalcogenide/polymer hybrid nanoparticles. J Phys Chem C 117:5999–6005 Fischer V, Bannwarth MB, Jakob G, Landfester K, Muñoz-Espí R (2013) Luminescent and magnetoresponsive multifunctional chalcogenide/polymer hybrid nanoparticles. J Phys Chem C 117:5999–6005
88.
go back to reference Bonnefond A, Ibarra M, Gonzalez E, Barrado M, Chuvilin A, Maria Asua J, Ramon Leiza J (2016) Photocatalytic and magnetic titanium dioxide/polystyrene/magnetite composite hybrid polymer particles. J Polym Sci A Polym Chem 54:3350–3356 Bonnefond A, Ibarra M, Gonzalez E, Barrado M, Chuvilin A, Maria Asua J, Ramon Leiza J (2016) Photocatalytic and magnetic titanium dioxide/polystyrene/magnetite composite hybrid polymer particles. J Polym Sci A Polym Chem 54:3350–3356
89.
go back to reference Gonzalez-Ortiz LJ, Asua JM (1995) Development of particle morphology in emulsion polymerization. 1. Cluster dynamics. Macromolecules 28:3135–3145 Gonzalez-Ortiz LJ, Asua JM (1995) Development of particle morphology in emulsion polymerization. 1. Cluster dynamics. Macromolecules 28:3135–3145
90.
go back to reference Gonzalez-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 2. Cluster dynamics in reacting systems. Macromolecules 29:383–389 Gonzalez-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 2. Cluster dynamics in reacting systems. Macromolecules 29:383–389
91.
go back to reference Gonzalez-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 3. Cluster nucleation and dynamics in polymerizing systems. Macromolecules 29:4520–4527 Gonzalez-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 3. Cluster nucleation and dynamics in polymerizing systems. Macromolecules 29:4520–4527
92.
go back to reference Asua JM (2014) Mapping the morphology of polymer-inorganic nanocomposites synthesized by miniemulsion polymerization. Macromol Chem Phys 215:458–464 Asua JM (2014) Mapping the morphology of polymer-inorganic nanocomposites synthesized by miniemulsion polymerization. Macromol Chem Phys 215:458–464
93.
go back to reference Reyes Y, Asua JM (2010) Modeling multiphase latex particle equilibrium morphology. J Polym Sci A Polym Chem 48:2579–2583 Reyes Y, Asua JM (2010) Modeling multiphase latex particle equilibrium morphology. J Polym Sci A Polym Chem 48:2579–2583
94.
go back to reference Stubbs J, Carrier R, Sundberg DC (2008) Monte Carlo simulation of emulsion polymerization kinetics and the evolution of latex particle morphology and polymer chain architecture. Macromol Theory Simul 17:147–162 Stubbs J, Carrier R, Sundberg DC (2008) Monte Carlo simulation of emulsion polymerization kinetics and the evolution of latex particle morphology and polymer chain architecture. Macromol Theory Simul 17:147–162
95.
go back to reference Akhmatskaya E, Asua JM (2012) Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer. J Polym Sci A Polym Chem 50:1383–1393 Akhmatskaya E, Asua JM (2012) Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer. J Polym Sci A Polym Chem 50:1383–1393
96.
go back to reference Akhmatskaya E, Asua JM (2013) Dynamic modeling of the morphology of multiphase waterborne polymer particles. Colloid Polym Sci 291:87–98 Akhmatskaya E, Asua JM (2013) Dynamic modeling of the morphology of multiphase waterborne polymer particles. Colloid Polym Sci 291:87–98
97.
go back to reference Hamzehlou S, Leiza JR, Asua JM (2016) A new approach for mathematical modeling of the dynamic development of particle morphology. Chem Eng J 304:655–666 Hamzehlou S, Leiza JR, Asua JM (2016) A new approach for mathematical modeling of the dynamic development of particle morphology. Chem Eng J 304:655–666
98.
go back to reference Chen YC, Dimonie V, El-Aasser MS (1992) Role of surfactant in composite latex particle morphology. J Appl Polym Sci 45:487–499 Chen YC, Dimonie V, El-Aasser MS (1992) Role of surfactant in composite latex particle morphology. J Appl Polym Sci 45:487–499
99.
go back to reference Stubbs JM, Sundberg DC (2005) A round Robin study for the characterization of latex particle morphology – multiple analytical techniques to probe specific structural features. Polymer 46:1125–1138 Stubbs JM, Sundberg DC (2005) A round Robin study for the characterization of latex particle morphology – multiple analytical techniques to probe specific structural features. Polymer 46:1125–1138
100.
go back to reference Gonzalez E, Tollan C, Chuvilin A, Barandiaran MJ, Paulis M (2012) Determination of the coalescence temperature of latexes by environmental scanning electron microscopy. ACS Appl Mater Interfaces 4:4276–4282PubMed Gonzalez E, Tollan C, Chuvilin A, Barandiaran MJ, Paulis M (2012) Determination of the coalescence temperature of latexes by environmental scanning electron microscopy. ACS Appl Mater Interfaces 4:4276–4282PubMed
101.
go back to reference Nzudie DT (1992) Contribution a L’etude de L’interphase Des Lates “core- Shell” Par Lat RMN Du Solide a Haute Resolution. Universite de Haute-Alsace, Mulhouse Nzudie DT (1992) Contribution a L’etude de L’interphase Des Lates “core- Shell” Par Lat RMN Du Solide a Haute Resolution. Universite de Haute-Alsace, Mulhouse
102.
go back to reference Song M, Hourston DJ, Reading M, Pollock HM, Hammiche A (1999) Modulated differential scanning Calorimetry. Analysis of interphases in multi-component polymer materials. J Therm Anal Calorim 56:991–1004 Song M, Hourston DJ, Reading M, Pollock HM, Hammiche A (1999) Modulated differential scanning Calorimetry. Analysis of interphases in multi-component polymer materials. J Therm Anal Calorim 56:991–1004
103.
go back to reference Hourston DJ, Song M, Hammiche A, Pollock HM, Reading M (1997) Modulated differential scanning calorimetry: 6. Thermal characterization of multicomponent polymers and interfaces. Polymer 38:1–7 Hourston DJ, Song M, Hammiche A, Pollock HM, Reading M (1997) Modulated differential scanning calorimetry: 6. Thermal characterization of multicomponent polymers and interfaces. Polymer 38:1–7
104.
go back to reference Tripathi AK, Tsavalas JG, Sundberg DC (2013) Thermochimica acta quantitative measurements of the extent of phase separation during and after polymerization in polymer composites using DSC. Thermochim Acta 568:20–30 Tripathi AK, Tsavalas JG, Sundberg DC (2013) Thermochimica acta quantitative measurements of the extent of phase separation during and after polymerization in polymer composites using DSC. Thermochim Acta 568:20–30
105.
go back to reference Luo H, Scriven LE, Francis LF (2007) Cryo-SEM studies of latex/ceramic nanoparticle coating microstructure development. J Colloid Interface Sci 316:500–509PubMed Luo H, Scriven LE, Francis LF (2007) Cryo-SEM studies of latex/ceramic nanoparticle coating microstructure development. J Colloid Interface Sci 316:500–509PubMed
106.
go back to reference Crassous JJ, Ballauff M, Drechsler M, Schmidt U, Talmon Y (2006) Imaging the volume transition in thermosensitive core-shell particles by cryo-transmission electron microscopy. Langmuir 22:2403–2406PubMed Crassous JJ, Ballauff M, Drechsler M, Schmidt U, Talmon Y (2006) Imaging the volume transition in thermosensitive core-shell particles by cryo-transmission electron microscopy. Langmuir 22:2403–2406PubMed
107.
go back to reference Geng X, Zhai MX, Sun T, Meyers G (2013) Morphology observation of latex particles with scanning transmission electron microscopy by a hydroxyethyl cellulose embedding combined with RuO4 staining method. Microsc Microanal 19:319–326PubMed Geng X, Zhai MX, Sun T, Meyers G (2013) Morphology observation of latex particles with scanning transmission electron microscopy by a hydroxyethyl cellulose embedding combined with RuO4 staining method. Microsc Microanal 19:319–326PubMed
108.
go back to reference Libera MR, Egerton RF (2010) Advances in the transmission electron microscopy of polymers. Polym Rev 50:321–339 Libera MR, Egerton RF (2010) Advances in the transmission electron microscopy of polymers. Polym Rev 50:321–339
109.
go back to reference Sawyer LC, Grubb DT, Meyers GF (2008) Polymer microscopy3rd edn. Springer, New York Sawyer LC, Grubb DT, Meyers GF (2008) Polymer microscopy3rd edn. Springer, New York
110.
go back to reference Smith RW, Bryg V (2006) Staining polymers for microscopical examination. Rubber Chem Technol 79:520–540 Smith RW, Bryg V (2006) Staining polymers for microscopical examination. Rubber Chem Technol 79:520–540
111.
go back to reference Midgley PA, Weyland M (2003) 3D electron microscopy in the physical sciences: the development of Z-contrast and EFTEM tomography. Ultramicroscopy 96:413–431PubMed Midgley PA, Weyland M (2003) 3D electron microscopy in the physical sciences: the development of Z-contrast and EFTEM tomography. Ultramicroscopy 96:413–431PubMed
112.
go back to reference Tosaka M, Danev R, Nagayama K (2005) Application of phase contrast transmission microscopic methods to polymer materials. Macromolecules 38:7884–7886 Tosaka M, Danev R, Nagayama K (2005) Application of phase contrast transmission microscopic methods to polymer materials. Macromolecules 38:7884–7886
113.
go back to reference Horiuchi S, Hanada T, Yase K, Ougizawa T (1999) Analysis of an interface between an immiscible polymer pair by electron spectroscopic imaging. Macromolecules 32:1312–1314 Horiuchi S, Hanada T, Yase K, Ougizawa T (1999) Analysis of an interface between an immiscible polymer pair by electron spectroscopic imaging. Macromolecules 32:1312–1314
114.
go back to reference Hoiruchi S, Kiyoshi Y, Kitano T, Higashida N, Ougizawa T (1997) EFTEM for the characterization of polymer blend morphologies. Polym J 29:380–383 Hoiruchi S, Kiyoshi Y, Kitano T, Higashida N, Ougizawa T (1997) EFTEM for the characterization of polymer blend morphologies. Polym J 29:380–383
115.
go back to reference Lieser G, Schmid SC, Wegner G (1996) Electrically conducting polymers: preparation and investigation of oxidized poly(acetylene) by EFTEM. J Microsc 183:53–59 Lieser G, Schmid SC, Wegner G (1996) Electrically conducting polymers: preparation and investigation of oxidized poly(acetylene) by EFTEM. J Microsc 183:53–59
116.
go back to reference Garcia-Meitin E, Bar G, Blackson J, Reuschle D (2008) High resolution polymer imaging using scanning transmission electron microscopy. Microsc Microanal 14:1380–1381 Garcia-Meitin E, Bar G, Blackson J, Reuschle D (2008) High resolution polymer imaging using scanning transmission electron microscopy. Microsc Microanal 14:1380–1381
117.
go back to reference Horiuchi S, Yin D, Ougizawa T (2005) Nanoscale analysis of polymer interfaces by energy-filtering transmission electron microscopy. Macromol Chem Phys 206:725–731 Horiuchi S, Yin D, Ougizawa T (2005) Nanoscale analysis of polymer interfaces by energy-filtering transmission electron microscopy. Macromol Chem Phys 206:725–731
118.
go back to reference Linares EM, Leite CAP, Valadares LF, Silva CA, Rezende CA, Galembeck F (2009) Molecular mapping by low-energy-loss energy-filtered transmission electron microscopy imaging. Anal Chem 81:2317–2324PubMed Linares EM, Leite CAP, Valadares LF, Silva CA, Rezende CA, Galembeck F (2009) Molecular mapping by low-energy-loss energy-filtered transmission electron microscopy imaging. Anal Chem 81:2317–2324PubMed
119.
go back to reference Hofer F, Warbichler P (2005) Elemental mapping using energy fiktered imaging. Transmission electron energy loss spectrometry in materials science and the EELS atlas. Wiley-VCH, Weinheim Hofer F, Warbichler P (2005) Elemental mapping using energy fiktered imaging. Transmission electron energy loss spectrometry in materials science and the EELS atlas. Wiley-VCH, Weinheim
120.
go back to reference Jeanguillaume C, Colliex C (1989) Spectrum-image: the next step in EELS digital acquisition and processing. Ultramicroscopy 28:252–257 Jeanguillaume C, Colliex C (1989) Spectrum-image: the next step in EELS digital acquisition and processing. Ultramicroscopy 28:252–257
121.
go back to reference Hunt JA, Williams DB (1991) Electron energy-loss spectrum-imaging. Ultramicroscopy 38:47–73 Hunt JA, Williams DB (1991) Electron energy-loss spectrum-imaging. Ultramicroscopy 38:47–73
122.
go back to reference Kim G, Sousa A, Meyers D, Shope M, Libera M (2006) Diffuse polymer interfaces in lobed nanoemulsions preserved in aqueous media. J Am Chem Soc 128:6570–6571PubMed Kim G, Sousa A, Meyers D, Shope M, Libera M (2006) Diffuse polymer interfaces in lobed nanoemulsions preserved in aqueous media. J Am Chem Soc 128:6570–6571PubMed
123.
go back to reference Kim G, Sousa A, Meyers D, Libera M (2008) Nanoscale composition of biphasic polymer nanocolloids in aqueous suspension. Microsc Microanal 14:459–468PubMed Kim G, Sousa A, Meyers D, Libera M (2008) Nanoscale composition of biphasic polymer nanocolloids in aqueous suspension. Microsc Microanal 14:459–468PubMed
124.
go back to reference Yakovlev S, Libera M (2008) Dose-limited spectroscopic imaging of soft materials by low-loss EELS in the scanning transmission electron microscope. Micron 39:734–740PubMed Yakovlev S, Libera M (2008) Dose-limited spectroscopic imaging of soft materials by low-loss EELS in the scanning transmission electron microscope. Micron 39:734–740PubMed
125.
go back to reference Drummy LF, Wang YC, Schoenmakers R, May K, Jackson M, Koerner H, Farmer BL, Mauryama B, Vaia RA (2008) Morphology of layered silicate-(NanoClay-) polymer nanocomposites by electron tomography and small-angle X-ray scattering. Macromolecules 41:2135–2143 Drummy LF, Wang YC, Schoenmakers R, May K, Jackson M, Koerner H, Farmer BL, Mauryama B, Vaia RA (2008) Morphology of layered silicate-(NanoClay-) polymer nanocomposites by electron tomography and small-angle X-ray scattering. Macromolecules 41:2135–2143
126.
go back to reference Voorn DJ, Ming W, van Herk AM (2006) Clay platelets encapsulated inside latex particles. Macromolecules 39:4654–4656 Voorn DJ, Ming W, van Herk AM (2006) Clay platelets encapsulated inside latex particles. Macromolecules 39:4654–4656
127.
go back to reference Midgley PA, Weyland M, Yates TJV, Arslan I, Dunin-Borkowski RE, Thomas JM (2006) Nanoscale scanning transmission electron tomography. J Microsc 223:185–190PubMed Midgley PA, Weyland M, Yates TJV, Arslan I, Dunin-Borkowski RE, Thomas JM (2006) Nanoscale scanning transmission electron tomography. J Microsc 223:185–190PubMed
128.
go back to reference Ziese U, De Jong KP, Koster AJ (2004) Electron tomography: a tool for 3D structural probing of heterogeneous catalysts at the nanometer scale. Appl Catal A Gen 260:71–74 Ziese U, De Jong KP, Koster AJ (2004) Electron tomography: a tool for 3D structural probing of heterogeneous catalysts at the nanometer scale. Appl Catal A Gen 260:71–74
129.
go back to reference Mori Y, Kawaguchi H (2007) Impact of initiators in preparing magnetic polymer particles by miniemulsion polymerization. Colloids Surf B Biointerfaces 56:246–254PubMed Mori Y, Kawaguchi H (2007) Impact of initiators in preparing magnetic polymer particles by miniemulsion polymerization. Colloids Surf B Biointerfaces 56:246–254PubMed
Metadata
Title
Morphology of Composite Polymer Latexes: An Update on Synthesis and Applications, Modeling, and Characterization
Authors
Shaghayegh Hamzehlou
Jose Ramon Leiza
Copyright Year
2018
DOI
https://doi.org/10.1007/12_2017_25

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